TY  - CHAP
AU  - Rašović, Aleksandar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5514
AB  - Advances, during the period 2008–18, in the chemistry of 1,2-dithioles as well as their applications in medicine and technology are presented. Additionally, for the better understanding of the extent of recent progress as well as a more complete overview of the topics, the chapter also includes a critical summary of the most relevant previously reported work concerning this subject. The examples of the synthesis of different 1,2-dithioles, starting from various fragments, are described herein following a systematic classification. Their reactivity is also thoroughly reviewed. The significance of lipoic acid, which has been also called a “universal antioxidant,” in the development of the multitarget profile drugs against Alzheimer's disease (AD) and its application for the preparation of functionalized nanoparticles is summarized. A survey of the literature data on the theoretical and experimental study of antioxidant properties of LA as well as its biochemistry is presented. The natural occurrence of compounds containing 1,2-dithioles is reviewed. Novel X-ray determinations of structures containing 1,2-dithiole moiety are listed. The synthesis and structure characterization of 3,3aλ4,4-trithia-1-azapentalenes is thoroughly discussed.
PB  - Elsevier
T2  - Comprehensive Heterocyclic Chemistry IV
T1  - 1,2-Dithioles
VL  - 4
SP  - 766
EP  - 833
DO  - 10.1016/B978-0-12-818655-8.00137-2
ER  - 

@inbook{
author = "Rašović, Aleksandar",
year = "2022",
abstract = "Advances, during the period 2008–18, in the chemistry of 1,2-dithioles as well as their applications in medicine and technology are presented. Additionally, for the better understanding of the extent of recent progress as well as a more complete overview of the topics, the chapter also includes a critical summary of the most relevant previously reported work concerning this subject. The examples of the synthesis of different 1,2-dithioles, starting from various fragments, are described herein following a systematic classification. Their reactivity is also thoroughly reviewed. The significance of lipoic acid, which has been also called a “universal antioxidant,” in the development of the multitarget profile drugs against Alzheimer's disease (AD) and its application for the preparation of functionalized nanoparticles is summarized. A survey of the literature data on the theoretical and experimental study of antioxidant properties of LA as well as its biochemistry is presented. The natural occurrence of compounds containing 1,2-dithioles is reviewed. Novel X-ray determinations of structures containing 1,2-dithiole moiety are listed. The synthesis and structure characterization of 3,3aλ4,4-trithia-1-azapentalenes is thoroughly discussed.",
publisher = "Elsevier",
journal = "Comprehensive Heterocyclic Chemistry IV",
booktitle = "1,2-Dithioles",
volume = "4",
pages = "766-833",
doi = "10.1016/B978-0-12-818655-8.00137-2"
}

Rašović, A.. (2022). 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry IV
Elsevier., 4, 766-833.
https://doi.org/10.1016/B978-0-12-818655-8.00137-2

Rašović A. 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry IV. 2022;4:766-833.
doi:10.1016/B978-0-12-818655-8.00137-2 .

Rašović, Aleksandar, "1,2-Dithioles" in Comprehensive Heterocyclic Chemistry IV, 4 (2022):766-833,
https://doi.org/10.1016/B978-0-12-818655-8.00137-2 . .

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Blagojević, Vladimir A.
AU  - Baranac-Stojanović, Marija
AU  - Kleinpeter, Erich
AU  - Marković, Rade
AU  - Minić, Dragica M.
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1934
AB  - Information about the strength of donor-acceptor interactions in push-pull alkenes is valuable, as this so-called "push-pull effect'' influences their chemical reactivity and dynamic behaviour. In this paper, we discuss the applicability of NMR spectral data and barriers to rotation around the CQC double bond to quantify the push-pull effect in biologically important 2-alkylidene-4-oxothiazolidines. While olefinic proton chemical shifts and differences in C-13 NMR chemical shifts of the two carbons constituting the CQC double bond fail to give the correct trend in the electron withdrawing ability of the substituents attached to the exocyclic carbon of the double bond, barriers to rotation prove to be a reliable quantity in providing information about the extent of donor-acceptor interactions in the push-pull systems studied. In particular all relevant kinetic data, that is the Arrhenius parameters ( apparent activation energy Ea and frequency factor A) and activation parameters ( Delta S-double dagger, Delta H-double dagger and Delta G(double dagger)), were determined from the data of the experimentally studied configurational isomerization of ( E)-9a. These results were compared to previously published related data for other two compounds, ( Z)-1b and ( 2E, 5Z)-7, showing that experimentally determined Delta G(double dagger) values are a good indicator of the strength of push-pull character. Theoretical calculations of the rotational barriers of eight selected derivatives excellently correlate with the calculated CQC bond lengths and corroborate the applicability of Delta G(double dagger) for estimation of the strength of the push-pull effect in these and related systems.
PB  - Royal Soc Chemistry, Cambridge
T2  - New Journal of Chemistry
T1  - Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond
VL  - 40
IS  - 7
SP  - 6364
EP  - 6373
DO  - 10.1039/c6nj00901h
ER  - 

@article{
author = "Rašović, Aleksandar and Blagojević, Vladimir A. and Baranac-Stojanović, Marija and Kleinpeter, Erich and Marković, Rade and Minić, Dragica M.",
year = "2016",
abstract = "Information about the strength of donor-acceptor interactions in push-pull alkenes is valuable, as this so-called "push-pull effect'' influences their chemical reactivity and dynamic behaviour. In this paper, we discuss the applicability of NMR spectral data and barriers to rotation around the CQC double bond to quantify the push-pull effect in biologically important 2-alkylidene-4-oxothiazolidines. While olefinic proton chemical shifts and differences in C-13 NMR chemical shifts of the two carbons constituting the CQC double bond fail to give the correct trend in the electron withdrawing ability of the substituents attached to the exocyclic carbon of the double bond, barriers to rotation prove to be a reliable quantity in providing information about the extent of donor-acceptor interactions in the push-pull systems studied. In particular all relevant kinetic data, that is the Arrhenius parameters ( apparent activation energy Ea and frequency factor A) and activation parameters ( Delta S-double dagger, Delta H-double dagger and Delta G(double dagger)), were determined from the data of the experimentally studied configurational isomerization of ( E)-9a. These results were compared to previously published related data for other two compounds, ( Z)-1b and ( 2E, 5Z)-7, showing that experimentally determined Delta G(double dagger) values are a good indicator of the strength of push-pull character. Theoretical calculations of the rotational barriers of eight selected derivatives excellently correlate with the calculated CQC bond lengths and corroborate the applicability of Delta G(double dagger) for estimation of the strength of the push-pull effect in these and related systems.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "New Journal of Chemistry",
title = "Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond",
volume = "40",
number = "7",
pages = "6364-6373",
doi = "10.1039/c6nj00901h"
}

Rašović, A., Blagojević, V. A., Baranac-Stojanović, M., Kleinpeter, E., Marković, R.,& Minić, D. M.. (2016). Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond. in New Journal of Chemistry
Royal Soc Chemistry, Cambridge., 40(7), 6364-6373.
https://doi.org/10.1039/c6nj00901h

Rašović A, Blagojević VA, Baranac-Stojanović M, Kleinpeter E, Marković R, Minić DM. Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond. in New Journal of Chemistry. 2016;40(7):6364-6373.
doi:10.1039/c6nj00901h .

Rašović, Aleksandar, Blagojević, Vladimir A., Baranac-Stojanović, Marija, Kleinpeter, Erich, Marković, Rade, Minić, Dragica M., "Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond" in New Journal of Chemistry, 40, no. 7 (2016):6364-6373,
https://doi.org/10.1039/c6nj00901h . .

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Koch, Andreas
AU  - Kleinpeter, Erich
AU  - Marković, Rade
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1227
AB  - Trithiaazapentalene derivatives were prepared by the reaction of 2-alkylidene-4-oxothiazolidines with Lawesson's reagent. They are classified as two structurally different trithiaazapentalene compounds that have different contributions of monocyclic 1,2-dithiole and 1,2,4-dithiazole structures and degrees of aromaticity of the bicyclic trithiaazapentalene system. The electron-donating ability of substituents at the C(5) position of the trithiaazapentalene system is recognized as the main cause for changes in pi-Celectron distribution. This is the first complete study of substituent effects on the structure of trithiapentalenes.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Tetrahedron
T1  - Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives
VL  - 69
IS  - 51
SP  - 10849
EP  - 10857
DO  - 10.1016/j.tet.2013.10.088
ER  - 

@article{
author = "Rašović, Aleksandar and Koch, Andreas and Kleinpeter, Erich and Marković, Rade",
year = "2013",
abstract = "Trithiaazapentalene derivatives were prepared by the reaction of 2-alkylidene-4-oxothiazolidines with Lawesson's reagent. They are classified as two structurally different trithiaazapentalene compounds that have different contributions of monocyclic 1,2-dithiole and 1,2,4-dithiazole structures and degrees of aromaticity of the bicyclic trithiaazapentalene system. The electron-donating ability of substituents at the C(5) position of the trithiaazapentalene system is recognized as the main cause for changes in pi-Celectron distribution. This is the first complete study of substituent effects on the structure of trithiapentalenes.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Tetrahedron",
title = "Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives",
volume = "69",
number = "51",
pages = "10849-10857",
doi = "10.1016/j.tet.2013.10.088"
}

Rašović, A., Koch, A., Kleinpeter, E.,& Marković, R.. (2013). Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives. in Tetrahedron
Oxford : Pergamon-Elsevier Science Ltd., 69(51), 10849-10857.
https://doi.org/10.1016/j.tet.2013.10.088

Rašović A, Koch A, Kleinpeter E, Marković R. Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives. in Tetrahedron. 2013;69(51):10849-10857.
doi:10.1016/j.tet.2013.10.088 .

Rašović, Aleksandar, Koch, Andreas, Kleinpeter, Erich, Marković, Rade, "Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives" in Tetrahedron, 69, no. 51 (2013):10849-10857,
https://doi.org/10.1016/j.tet.2013.10.088 . .

TY  - CHAP
AU  - Marković, Rade
AU  - Rašović, Aleksandar
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5513
AB  - The chemistry of 1,2-dithioles, 1,2-dithiolanes, 1,2-dithiolium salts, naphtho[1,8-cd]-1,2-dithiole, and 3,3aλ4,4-trithia-1-azapentalene is updated for the period 1995–2006. All X-ray determinations of structures containing these two nuclei are listed. New methods for the ring syntheses of 1,2-dithioles and 1,2-dithiolanes from various fragments are summarized and exemplified. The importance of through-space sulfur sulfur interactions is discussed. The relevance of lipoic acid to the synthesis of potential drugs, and self-assembled monolayers (SAMs) is described. Naturally occurring compounds containing the 1,2-dithiolane unit are exemplified. The biochemistry of lipoic acid is briefly discussed.
PB  - Elsevier
T2  - Comprehensive Heterocyclic Chemistry III
T1  - 1,2-Dithioles
VL  - 4
SP  - 893
EP  - 954
DO  - 10.1016/B978-008044992-0.00411-9
ER  - 

@inbook{
author = "Marković, Rade and Rašović, Aleksandar",
year = "2008",
abstract = "The chemistry of 1,2-dithioles, 1,2-dithiolanes, 1,2-dithiolium salts, naphtho[1,8-cd]-1,2-dithiole, and 3,3aλ4,4-trithia-1-azapentalene is updated for the period 1995–2006. All X-ray determinations of structures containing these two nuclei are listed. New methods for the ring syntheses of 1,2-dithioles and 1,2-dithiolanes from various fragments are summarized and exemplified. The importance of through-space sulfur sulfur interactions is discussed. The relevance of lipoic acid to the synthesis of potential drugs, and self-assembled monolayers (SAMs) is described. Naturally occurring compounds containing the 1,2-dithiolane unit are exemplified. The biochemistry of lipoic acid is briefly discussed.",
publisher = "Elsevier",
journal = "Comprehensive Heterocyclic Chemistry III",
booktitle = "1,2-Dithioles",
volume = "4",
pages = "893-954",
doi = "10.1016/B978-008044992-0.00411-9"
}

Marković, R.,& Rašović, A.. (2008). 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry III
Elsevier., 4, 893-954.
https://doi.org/10.1016/B978-008044992-0.00411-9

Marković R, Rašović A. 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry III. 2008;4:893-954.
doi:10.1016/B978-008044992-0.00411-9 .

Marković, Rade, Rašović, Aleksandar, "1,2-Dithioles" in Comprehensive Heterocyclic Chemistry III, 4 (2008):893-954,
https://doi.org/10.1016/B978-008044992-0.00411-9 . .

TY  - DATA
AU  - Marković, Rade
AU  - Rašović, Aleksandar
AU  - Steel, Peter
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4592
AB  - GISGAR : Ethyl 3-(6-phenyl-4λ4[1,2]dithiolo[1,5-b][1,2,4]dithiazol-2-yl)propanoate Space Group: P 21/c (14), Cell: a 4.5830(8)Å b 15.550(3)Å c 21.858(4)Å, α 90° β 91.579(2)° γ 90°
PB  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 271489: Experimental Crystal Structure Determination. Crystallographic data for "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate, Acta Crystallographica Section E: Structure Reports Online, 2008, 64, 1"
DO  - 10.5517/cc93hql
ER  - 

@misc{
author = "Marković, Rade and Rašović, Aleksandar and Steel, Peter",
year = "2008",
abstract = "GISGAR : Ethyl 3-(6-phenyl-4λ4[1,2]dithiolo[1,5-b][1,2,4]dithiazol-2-yl)propanoate Space Group: P 21/c (14), Cell: a 4.5830(8)Å b 15.550(3)Å c 21.858(4)Å, α 90° β 91.579(2)° γ 90°",
publisher = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 271489: Experimental Crystal Structure Determination. Crystallographic data for "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate, Acta Crystallographica Section E: Structure Reports Online, 2008, 64, 1"",
doi = "10.5517/cc93hql"
}

Marković, R., Rašović, A.,& Steel, P.. (2008). CCDC 271489: Experimental Crystal Structure Determination. Crystallographic data for "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate, Acta Crystallographica Section E: Structure Reports Online, 2008, 64, 1". 
The Cambridge Crystallographic Data Centre (CCDC)..
https://doi.org/10.5517/cc93hql

Marković R, Rašović A, Steel P. CCDC 271489: Experimental Crystal Structure Determination. Crystallographic data for "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate, Acta Crystallographica Section E: Structure Reports Online, 2008, 64, 1". 2008;.
doi:10.5517/cc93hql .

Marković, Rade, Rašović, Aleksandar, Steel, Peter, "CCDC 271489: Experimental Crystal Structure Determination. Crystallographic data for "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate, Acta Crystallographica Section E: Structure Reports Online, 2008, 64, 1"" (2008),
https://doi.org/10.5517/cc93hql . .

TY  - JOUR
AU  - Marković, Rade
AU  - Rašović, Aleksandar
AU  - Steel, Peter
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/470
AB  - The title compound, C15H15NO2S3, exists in a bicyclic form, with resonance contributions from two monocyclic forms, each without a second S - S bond. The trithiapentalene heterocyclic ring system is planar, with a mean deviation of 0.014 (2) Å from the mean plane, and is inclined to the plane of the attached phenyl ring at an angle of 17.24 (7)°.
PB  - International Union of Crystallography
T2  - Acta Crystallographica Section E: Structure Reports Online
T1  - Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate
VL  - 64
IS  - 1
DO  - 10.1107/S1600536807063209
ER  - 

@article{
author = "Marković, Rade and Rašović, Aleksandar and Steel, Peter",
year = "2008",
abstract = "The title compound, C15H15NO2S3, exists in a bicyclic form, with resonance contributions from two monocyclic forms, each without a second S - S bond. The trithiapentalene heterocyclic ring system is planar, with a mean deviation of 0.014 (2) Å from the mean plane, and is inclined to the plane of the attached phenyl ring at an angle of 17.24 (7)°.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section E: Structure Reports Online",
title = "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate",
volume = "64",
number = "1",
doi = "10.1107/S1600536807063209"
}

Marković, R., Rašović, A.,& Steel, P.. (2008). Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate. in Acta Crystallographica Section E: Structure Reports Online
International Union of Crystallography., 64(1).
https://doi.org/10.1107/S1600536807063209

Marković R, Rašović A, Steel P. Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate. in Acta Crystallographica Section E: Structure Reports Online. 2008;64(1).
doi:10.1107/S1600536807063209 .

Marković, Rade, Rašović, Aleksandar, Steel, Peter, "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate" in Acta Crystallographica Section E: Structure Reports Online, 64, no. 1 (2008),
https://doi.org/10.1107/S1600536807063209 . .

TY  - DATA
AU  - Rašović, Aleksandar
AU  - Steel, Peter J.
AU  - Kleinpeter, Erich
AU  - Marković, Rade
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4589
AB  - JEYHUR : 2-ethyl-6-phenyl-2,3-dihydro-4H-1,3-thiazine-4-thione Space Group: P 1 (2), Cell: a 5.6687(8)Å b 11.0149(15)Å c 11.056(2)Å, α 116.540(9)° β 94.285(10)° γ 102.679(7)°
PB  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 607824: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"
DO  - 10.5517/ccndh7r
ER  - 

@misc{
author = "Rašović, Aleksandar and Steel, Peter J. and Kleinpeter, Erich and Marković, Rade",
year = "2007",
abstract = "JEYHUR : 2-ethyl-6-phenyl-2,3-dihydro-4H-1,3-thiazine-4-thione Space Group: P 1 (2), Cell: a 5.6687(8)Å b 11.0149(15)Å c 11.056(2)Å, α 116.540(9)° β 94.285(10)° γ 102.679(7)°",
publisher = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 607824: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"",
doi = "10.5517/ccndh7r"
}

Rašović, A., Steel, P. J., Kleinpeter, E.,& Marković, R.. (2007). CCDC 607824: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions". 
The Cambridge Crystallographic Data Centre (CCDC)..
https://doi.org/10.5517/ccndh7r

Rašović A, Steel PJ, Kleinpeter E, Marković R. CCDC 607824: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions". 2007;.
doi:10.5517/ccndh7r .

Rašović, Aleksandar, Steel, Peter J., Kleinpeter, Erich, Marković, Rade, "CCDC 607824: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"" (2007),
https://doi.org/10.5517/ccndh7r . .

TY  - DATA
AU  - Rašović, Aleksandar
AU  - Steel, Peter J.
AU  - Kleinpeter, Erich
AU  - Marković, Rade
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4588
AB  - JEYHOL : 2-methyl-6-phenyl-4λ4-[1,2]dithiolo[1,5-b][1,2,4]dithiazole Space Group: P 21/c (14), Cell: a 13.4197(7)Å b 7.2797(4)Å c 11.8980(6)Å, α 90° β 108.161(2)° γ 90°
PB  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"
DO  - 10.5517/ccndh6q
ER  - 

@misc{
author = "Rašović, Aleksandar and Steel, Peter J. and Kleinpeter, Erich and Marković, Rade",
year = "2007",
abstract = "JEYHOL : 2-methyl-6-phenyl-4λ4-[1,2]dithiolo[1,5-b][1,2,4]dithiazole Space Group: P 21/c (14), Cell: a 13.4197(7)Å b 7.2797(4)Å c 11.8980(6)Å, α 90° β 108.161(2)° γ 90°",
publisher = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"",
doi = "10.5517/ccndh6q"
}

Rašović, A., Steel, P. J., Kleinpeter, E.,& Marković, R.. (2007). CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions". 
The Cambridge Crystallographic Data Centre (CCDC)..
https://doi.org/10.5517/ccndh6q

Rašović A, Steel PJ, Kleinpeter E, Marković R. CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions". 2007;.
doi:10.5517/ccndh6q .

Rašović, Aleksandar, Steel, Peter J., Kleinpeter, Erich, Marković, Rade, "CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"" (2007),
https://doi.org/10.5517/ccndh6q . .

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Steel, Peter J.
AU  - Kleinpeter, Erich
AU  - Marković, Rade
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4587
AB  - A new synthetic approach to 2,3-dihydro-4H-1,3-thiazine derivatives based upon reductive rearrangement of 1,2-dithiole-3-ylidene thiones has been developed. In turn, the 1,2-dithiole derivatives were prepared by an efficient ring-opening-closing process of 2-alkylidene-4-oxothiazolidines, induced in the presence of Lawesson's reagent by intramolecular non-bonded 1,5-type S⋯O interactions in the 4-oxothiazolidine precursors.
PB  - Elsevier
T2  - Tetrahedron
T1  - Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions
VL  - 63
IS  - 9
SP  - 1937
EP  - 1945
DO  - 10.1016/j.tet.2006.12.075
ER  - 

@article{
author = "Rašović, Aleksandar and Steel, Peter J. and Kleinpeter, Erich and Marković, Rade",
year = "2007",
abstract = "A new synthetic approach to 2,3-dihydro-4H-1,3-thiazine derivatives based upon reductive rearrangement of 1,2-dithiole-3-ylidene thiones has been developed. In turn, the 1,2-dithiole derivatives were prepared by an efficient ring-opening-closing process of 2-alkylidene-4-oxothiazolidines, induced in the presence of Lawesson's reagent by intramolecular non-bonded 1,5-type S⋯O interactions in the 4-oxothiazolidine precursors.",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions",
volume = "63",
number = "9",
pages = "1937-1945",
doi = "10.1016/j.tet.2006.12.075"
}

Rašović, A., Steel, P. J., Kleinpeter, E.,& Marković, R.. (2007). Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions. in Tetrahedron
Elsevier., 63(9), 1937-1945.
https://doi.org/10.1016/j.tet.2006.12.075

Rašović A, Steel PJ, Kleinpeter E, Marković R. Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions. in Tetrahedron. 2007;63(9):1937-1945.
doi:10.1016/j.tet.2006.12.075 .

Rašović, Aleksandar, Steel, Peter J., Kleinpeter, Erich, Marković, Rade, "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions" in Tetrahedron, 63, no. 9 (2007):1937-1945,
https://doi.org/10.1016/j.tet.2006.12.075 . .

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Steel, Peter J.
AU  - Kleinpeter, Erich
AU  - Marković, Rade
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4255
AB  - A new synthetic approach to 2,3-dihydro-4H-1,3-thiazine derivatives based upon reductive rearrangement of 1,2-dithiole-3-ylidene thiones has been developed. In turn, the 1,2-dithiole derivatives were prepared by an efficient ring-opening-closing process of 2-alkylidene-4-oxothiazolidines, induced in the presence of Lawesson's reagent by intramolecular non-bonded 1,5-type S⋯O interactions in the 4-oxothiazolidine precursors.
PB  - Elsevier
T2  - Tetrahedron
T1  - Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions
VL  - 63
IS  - 9
SP  - 1937
EP  - 1945
DO  - 10.1016/j.tet.2006.12.075
ER  - 

@article{
author = "Rašović, Aleksandar and Steel, Peter J. and Kleinpeter, Erich and Marković, Rade",
year = "2007",
abstract = "A new synthetic approach to 2,3-dihydro-4H-1,3-thiazine derivatives based upon reductive rearrangement of 1,2-dithiole-3-ylidene thiones has been developed. In turn, the 1,2-dithiole derivatives were prepared by an efficient ring-opening-closing process of 2-alkylidene-4-oxothiazolidines, induced in the presence of Lawesson's reagent by intramolecular non-bonded 1,5-type S⋯O interactions in the 4-oxothiazolidine precursors.",
publisher = "Elsevier",
journal = "Tetrahedron",
title = "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions",
volume = "63",
number = "9",
pages = "1937-1945",
doi = "10.1016/j.tet.2006.12.075"
}

Rašović, A., Steel, P. J., Kleinpeter, E.,& Marković, R.. (2007). Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions. in Tetrahedron
Elsevier., 63(9), 1937-1945.
https://doi.org/10.1016/j.tet.2006.12.075

Rašović A, Steel PJ, Kleinpeter E, Marković R. Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions. in Tetrahedron. 2007;63(9):1937-1945.
doi:10.1016/j.tet.2006.12.075 .

Rašović, Aleksandar, Steel, Peter J., Kleinpeter, Erich, Marković, Rade, "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions" in Tetrahedron, 63, no. 9 (2007):1937-1945,
https://doi.org/10.1016/j.tet.2006.12.075 . .

TY  - JOUR
AU  - Marković, Rade
AU  - Rašović, Aleksandar
AU  - Baranac, Marija M.
AU  - Stojanović, Milovan
AU  - Steel, Peter
AU  - Jovetić, Stanka L.
PY  - 2004
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/139
AB  - The potential of directional non-bonded 1,5-type S···O interactions to initiate the incipient stage of an in situ rearrangement of N-unsubstituted thiazolidine enaminones to functionalized 1,2-dithioles has been demonstrated. The spectral characteristics, as well as X-ray structural analysis of a selected rearranged product, indicate that a dynamic interconversion occurs in solution between the 1,2-dithiole and the 3,3aλ4,4-trithia-1-azapentalene bicylic form. The lack of the rearrangement in the case of a N-methyl substituted enaminone precursor is attributed to an unfavorable methyl migration in the last reaction step.
AB  - Pokazan je potencijal usmerenih nevezivnih interakcija 1,5-tipa S···O da iniciraju početnu fazu in situ premeštanja N-nesupstituisanih tiazolidinonskih enaminona u funkcionalizovane 1,2-ditiole. Spektralne karakteristike, kao i kristalografska strukturna analiza izabranog premeštenog proizvoda, ukazuju na brzu interkonverziju između 1,2-ditiola i 3, 3aλ4,4-tritija-1-azapentalenskog bicikličnog oblika. Odsustvo premeštanja u slučaju N-metil-supstituisanog enaminomskog prekursora pripisano je nefavorizovanom premeštanju metil-grupe u završnoj fazi reakcije.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones
T1  - Tionovanje n-metil- i n-nesupstituisanih tiazolidinonskih enaminona
VL  - 69
IS  - 11
SP  - 909
EP  - 918
DO  - 10.2298/JSC0411909M
ER  - 

@article{
author = "Marković, Rade and Rašović, Aleksandar and Baranac, Marija M. and Stojanović, Milovan and Steel, Peter and Jovetić, Stanka L.",
year = "2004",
abstract = "The potential of directional non-bonded 1,5-type S···O interactions to initiate the incipient stage of an in situ rearrangement of N-unsubstituted thiazolidine enaminones to functionalized 1,2-dithioles has been demonstrated. The spectral characteristics, as well as X-ray structural analysis of a selected rearranged product, indicate that a dynamic interconversion occurs in solution between the 1,2-dithiole and the 3,3aλ4,4-trithia-1-azapentalene bicylic form. The lack of the rearrangement in the case of a N-methyl substituted enaminone precursor is attributed to an unfavorable methyl migration in the last reaction step., Pokazan je potencijal usmerenih nevezivnih interakcija 1,5-tipa S···O da iniciraju početnu fazu in situ premeštanja N-nesupstituisanih tiazolidinonskih enaminona u funkcionalizovane 1,2-ditiole. Spektralne karakteristike, kao i kristalografska strukturna analiza izabranog premeštenog proizvoda, ukazuju na brzu interkonverziju između 1,2-ditiola i 3, 3aλ4,4-tritija-1-azapentalenskog bicikličnog oblika. Odsustvo premeštanja u slučaju N-metil-supstituisanog enaminomskog prekursora pripisano je nefavorizovanom premeštanju metil-grupe u završnoj fazi reakcije.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones, Tionovanje n-metil- i n-nesupstituisanih tiazolidinonskih enaminona",
volume = "69",
number = "11",
pages = "909-918",
doi = "10.2298/JSC0411909M"
}

Marković, R., Rašović, A., Baranac, M. M., Stojanović, M., Steel, P.,& Jovetić, S. L.. (2004). Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 69(11), 909-918.
https://doi.org/10.2298/JSC0411909M

Marković R, Rašović A, Baranac MM, Stojanović M, Steel P, Jovetić SL. Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones. in Journal of the Serbian Chemical Society. 2004;69(11):909-918.
doi:10.2298/JSC0411909M .

Marković, Rade, Rašović, Aleksandar, Baranac, Marija M., Stojanović, Milovan, Steel, Peter, Jovetić, Stanka L., "Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones" in Journal of the Serbian Chemical Society, 69, no. 11 (2004):909-918,
https://doi.org/10.2298/JSC0411909M . .