TY  - JOUR
AU  - Sentić, Milica
AU  - Arbault, Stephane
AU  - Bouffier, Laurent
AU  - Manojlović, Dragan
AU  - Kuhn, Alexander
AU  - Šojić, Nešo
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7494
AB  - Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.
PB  - Royal Soc Chemistry, Cambridge
T2  - Chemical Science
T1  - 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission
VL  - 6
IS  - 8
SP  - 4433
EP  - 4437
DO  - 10.1039/c5sc01530h
ER  - 

@article{
author = "Sentić, Milica and Arbault, Stephane and Bouffier, Laurent and Manojlović, Dragan and Kuhn, Alexander and Šojić, Nešo",
year = "2015",
abstract = "Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Chemical Science",
title = "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission",
volume = "6",
number = "8",
pages = "4433-4437",
doi = "10.1039/c5sc01530h"
}

Sentić, M., Arbault, S., Bouffier, L., Manojlović, D., Kuhn, A.,& Šojić, N.. (2015). 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science
Royal Soc Chemistry, Cambridge., 6(8), 4433-4437.
https://doi.org/10.1039/c5sc01530h

Sentić M, Arbault S, Bouffier L, Manojlović D, Kuhn A, Šojić N. 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science. 2015;6(8):4433-4437.
doi:10.1039/c5sc01530h .

Sentić, Milica, Arbault, Stephane, Bouffier, Laurent, Manojlović, Dragan, Kuhn, Alexander, Šojić, Nešo, "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission" in Chemical Science, 6, no. 8 (2015):4433-4437,
https://doi.org/10.1039/c5sc01530h . .