Kovačević, Tihomir M.

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orcid::0000-0001-7386-6831
  • Kovačević, Tihomir M. (3)
  • Kovačević, Tihomir (2)
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Author's Bibliography

Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources

Alil, Ana; Lazarević, Miloš; Bajić, Danica; Nada, Ilić; Kovačević, Tihomir M.; Nedić, Bogdan

(Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), 2023)

TY  - CONF
AU  - Alil, Ana
AU  - Lazarević, Miloš
AU  - Bajić, Danica
AU  - Nada, Ilić
AU  - Kovačević, Tihomir M.
AU  - Nedić, Bogdan
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6861
AB  - Explosively welded metal plates of large surfaces or specific geometries are used in equipment for 
the production of electricity from renewable sources. In explosive welding, the energy of a 
controlled detonation is used to create a joint, when one metal part collides with another at high 
speed forming a weavy bonded interface. Explosive welding is used in the production of specialized 
components for renewable energy sources, such as parts of wind farms or turbines, because enables 
strong and secure connections between different types of metal or material. This technique can also 
be applied in the production of specific components for solar industry, such as solar panel supports 
that require strong and reliable connections, often between dissimilar materials that are difficult to 
weld with conventional methods. In addition, explosive welding can be useful in the production of 
batteries for renewable energy storage, where it is crucial to ensure that the connections are 
mechanical and electrically reliable. For such structures it is important to be able to perform in situ 
monitoring using nondestructive techniques to check the success of the performed welding on the 
whole pieces or products made this way. This work considers the application of non-destructive and 
destructive techniques to examine the quality of explosively welded joints of two different sets of 
metal plates: aluminum alloy-steel and carbon steel- highly wear resistant alloy steel, with two 
explosives, Amonex and Demex. Inspection of the joints was carried out using surface methods and 
non-destructive volumetric methods. The following techniques were applied: visual method, liquid 
penetrant testing, X-ray and ultrasound defectoscopy. To confirm the results of non-destructive 
techniques, a microstructural analysis of the cross-section of the welded joint was performed. The 
application of non-destructive testing techniques in testing the quality of explosively welded joints 
contributes to the reduction of costs that would be caused by destructive tests, since these 
techniques can be used to monitor the success of the process itself and thus improve the 
technological process of producing bimetallic joints by explosive welding.
AB  - Eksplozivno zavarene metalne ploče velikih površina ili specifične geometrije nalaze primenu u 
opremi za proizvodnju električne energije iz obnovljivih izvora. U eksplozivnom zavarivanju koristi 
se energija kontrolisane detonacije da bi se ostvario spoj, kada se jedan metalni deo sudara sa 
drugim velikom brzinom formirajući spoj talasastog profila. Eksplozivno zavarivanje se koristi u 
proizvodnji specijalnih komponenti za obnovljive izvore energije, kao što su delovi vetroelektrana 
ili turbina, jer omogućava čvrste i sigurne spojeve između različitih vrsta metala. Ova tehnika se 
može primeniti i u izradi specifičnih komponenti za solarnu industriju, kao što su nosači solarnih 
panela koji zahtevaju snažne i pouzdane veze, neretko između raznorodnih materijala koje je teško 
zavariti konvencionalnim postupcima. Osim toga, eksplozivno zavarivanje može biti korisno u 
proizvodnji baterija za skladištenje obnovljive energije, gde je ključno osigurati da su spojevi 
mehanički i električki pouzdani. Za primenu u takvim konstrukcijama važno je da se može vršiti in 
situ kontrola primenom nedestruktivnih tehnika kako bi se proverila uspešnost izvršenog 
zavarivanja celih komada ili proizvoda dobijenih na ovaj način. U ovom radu prikazana je primena 
nedestruktivnih i destruktivnih tehnika za ispitivanje kvaliteta eksplozivno zavarenih spojeva dva 
različita seta metalnih ploča: aluminijumska legura-čelik i ugljenični čelik-alatni čelik, sa dva 
eksploziva, Amonex i Demex. Ispitivanje kvaliteta ostvarenih spojeva vršeno je površinskim 
metodama i zapreminskim metodama bez razaranja i sa razaranjem. Primenjene su sledeće tehnike 
bez razaranja: vizuelna metoda, ispitivanje tečnim penetrantima, radiografija i ultrazvučno 
ispitivanje. Kako bi se rezultati nedestruktivnih tehnika potvrdili, izvšena je i mikrostrukturna 
analiza poprečnog preseka zavarenog spoja. Primena tehnika ispitivanja bez razaranja u 
ispitivanju kvaliteta eksplozivno zavarenih spojeva doprinosi smanjenju troškova kada se vrše 
destruktivna ispitivanja. Ovim tehnikama može pratiti uspešnost samog procesa i na taj način 
poboljšati tehnološki proces izrade bimetalnih spojeva eksplozivnim zavarivanjem.
PB  - Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)
C3  - Proceedings - 11th International Conference  on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia
T1  - Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources
SP  - 23
EP  - 34
UR  - https://hdl.handle.net/21.15107/rcub_cer_6861
ER  - 
@conference{
author = "Alil, Ana and Lazarević, Miloš and Bajić, Danica and Nada, Ilić and Kovačević, Tihomir M. and Nedić, Bogdan",
year = "2023",
abstract = "Explosively welded metal plates of large surfaces or specific geometries are used in equipment for 
the production of electricity from renewable sources. In explosive welding, the energy of a 
controlled detonation is used to create a joint, when one metal part collides with another at high 
speed forming a weavy bonded interface. Explosive welding is used in the production of specialized 
components for renewable energy sources, such as parts of wind farms or turbines, because enables 
strong and secure connections between different types of metal or material. This technique can also 
be applied in the production of specific components for solar industry, such as solar panel supports 
that require strong and reliable connections, often between dissimilar materials that are difficult to 
weld with conventional methods. In addition, explosive welding can be useful in the production of 
batteries for renewable energy storage, where it is crucial to ensure that the connections are 
mechanical and electrically reliable. For such structures it is important to be able to perform in situ 
monitoring using nondestructive techniques to check the success of the performed welding on the 
whole pieces or products made this way. This work considers the application of non-destructive and 
destructive techniques to examine the quality of explosively welded joints of two different sets of 
metal plates: aluminum alloy-steel and carbon steel- highly wear resistant alloy steel, with two 
explosives, Amonex and Demex. Inspection of the joints was carried out using surface methods and 
non-destructive volumetric methods. The following techniques were applied: visual method, liquid 
penetrant testing, X-ray and ultrasound defectoscopy. To confirm the results of non-destructive 
techniques, a microstructural analysis of the cross-section of the welded joint was performed. The 
application of non-destructive testing techniques in testing the quality of explosively welded joints 
contributes to the reduction of costs that would be caused by destructive tests, since these 
techniques can be used to monitor the success of the process itself and thus improve the 
technological process of producing bimetallic joints by explosive welding., Eksplozivno zavarene metalne ploče velikih površina ili specifične geometrije nalaze primenu u 
opremi za proizvodnju električne energije iz obnovljivih izvora. U eksplozivnom zavarivanju koristi 
se energija kontrolisane detonacije da bi se ostvario spoj, kada se jedan metalni deo sudara sa 
drugim velikom brzinom formirajući spoj talasastog profila. Eksplozivno zavarivanje se koristi u 
proizvodnji specijalnih komponenti za obnovljive izvore energije, kao što su delovi vetroelektrana 
ili turbina, jer omogućava čvrste i sigurne spojeve između različitih vrsta metala. Ova tehnika se 
može primeniti i u izradi specifičnih komponenti za solarnu industriju, kao što su nosači solarnih 
panela koji zahtevaju snažne i pouzdane veze, neretko između raznorodnih materijala koje je teško 
zavariti konvencionalnim postupcima. Osim toga, eksplozivno zavarivanje može biti korisno u 
proizvodnji baterija za skladištenje obnovljive energije, gde je ključno osigurati da su spojevi 
mehanički i električki pouzdani. Za primenu u takvim konstrukcijama važno je da se može vršiti in 
situ kontrola primenom nedestruktivnih tehnika kako bi se proverila uspešnost izvršenog 
zavarivanja celih komada ili proizvoda dobijenih na ovaj način. U ovom radu prikazana je primena 
nedestruktivnih i destruktivnih tehnika za ispitivanje kvaliteta eksplozivno zavarenih spojeva dva 
različita seta metalnih ploča: aluminijumska legura-čelik i ugljenični čelik-alatni čelik, sa dva 
eksploziva, Amonex i Demex. Ispitivanje kvaliteta ostvarenih spojeva vršeno je površinskim 
metodama i zapreminskim metodama bez razaranja i sa razaranjem. Primenjene su sledeće tehnike 
bez razaranja: vizuelna metoda, ispitivanje tečnim penetrantima, radiografija i ultrazvučno 
ispitivanje. Kako bi se rezultati nedestruktivnih tehnika potvrdili, izvšena je i mikrostrukturna 
analiza poprečnog preseka zavarenog spoja. Primena tehnika ispitivanja bez razaranja u 
ispitivanju kvaliteta eksplozivno zavarenih spojeva doprinosi smanjenju troškova kada se vrše 
destruktivna ispitivanja. Ovim tehnikama može pratiti uspešnost samog procesa i na taj način 
poboljšati tehnološki proces izrade bimetalnih spojeva eksplozivnim zavarivanjem.",
publisher = "Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)",
journal = "Proceedings - 11th International Conference  on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia",
title = "Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources",
pages = "23-34",
url = "https://hdl.handle.net/21.15107/rcub_cer_6861"
}
Alil, A., Lazarević, M., Bajić, D., Nada, I., Kovačević, T. M.,& Nedić, B.. (2023). Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources. in Proceedings - 11th International Conference  on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia
Union of Mechanical and  Electrotechnical Engineers and  Technicians of Serbia (SMEITS)., 23-34.
https://hdl.handle.net/21.15107/rcub_cer_6861
Alil A, Lazarević M, Bajić D, Nada I, Kovačević TM, Nedić B. Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources. in Proceedings - 11th International Conference  on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia. 2023;:23-34.
https://hdl.handle.net/21.15107/rcub_cer_6861 .
Alil, Ana, Lazarević, Miloš, Bajić, Danica, Nada, Ilić, Kovačević, Tihomir M., Nedić, Bogdan, "Testing the quality of explosively welded joints of dissimilar metals potentially applicable in renewable energy sources" in Proceedings - 11th International Conference  on Renewable Electrical Power Sources, Belgrade, November 2 and 3, 2023, Chamber of Commerce and Industry of Serbia (2023):23-34,
https://hdl.handle.net/21.15107/rcub_cer_6861 .

Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials

Marinković, Aleksandar D.; Milosavljević, Milutin; Kovačević, Tihomir M.; Kovačina, Jovanka; Milošević, Milena D.; Jovanović, Aleksandar; Petrović, Slobodan D.

(ООО «Центр «АЮМЭЛЬ», 2020)

TY  - CONF
AU  - Marinković, Aleksandar D.
AU  - Milosavljević, Milutin
AU  - Kovačević, Tihomir M.
AU  - Kovačina, Jovanka
AU  - Milošević, Milena D.
AU  - Jovanović, Aleksandar
AU  - Petrović, Slobodan D.
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3687
AB  - Innovative technology has been developed for the production of gelcoat and materials of reduced flammability based on unsaturated polyester resins. These materials were synthesized from raw materials obtained from waste poly(ethylene terephthalate) (PET) and bio-renewable resources. The presented technologies respect the environmental legislative as well as the principles of green and circular economy. Resulting products can be applied in various industries (construction/building, mining, polymer processing etc.).
PB  - ООО «Центр «АЮМЭЛЬ»
C3  - Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the Russian Federation, 24-26.09.2020.
T1  - Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials
SP  - 179
EP  - 180
UR  - https://hdl.handle.net/21.15107/rcub_cer_3687
ER  - 
@conference{
author = "Marinković, Aleksandar D. and Milosavljević, Milutin and Kovačević, Tihomir M. and Kovačina, Jovanka and Milošević, Milena D. and Jovanović, Aleksandar and Petrović, Slobodan D.",
year = "2020",
abstract = "Innovative technology has been developed for the production of gelcoat and materials of reduced flammability based on unsaturated polyester resins. These materials were synthesized from raw materials obtained from waste poly(ethylene terephthalate) (PET) and bio-renewable resources. The presented technologies respect the environmental legislative as well as the principles of green and circular economy. Resulting products can be applied in various industries (construction/building, mining, polymer processing etc.).",
publisher = "ООО «Центр «АЮМЭЛЬ»",
journal = "Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the Russian Federation, 24-26.09.2020.",
title = "Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials",
pages = "179-180",
url = "https://hdl.handle.net/21.15107/rcub_cer_3687"
}
Marinković, A. D., Milosavljević, M., Kovačević, T. M., Kovačina, J., Milošević, M. D., Jovanović, A.,& Petrović, S. D.. (2020). Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials. in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the Russian Federation, 24-26.09.2020.
ООО «Центр «АЮМЭЛЬ»., 179-180.
https://hdl.handle.net/21.15107/rcub_cer_3687
Marinković AD, Milosavljević M, Kovačević TM, Kovačina J, Milošević MD, Jovanović A, Petrović SD. Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials. in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the Russian Federation, 24-26.09.2020.. 2020;:179-180.
https://hdl.handle.net/21.15107/rcub_cer_3687 .
Marinković, Aleksandar D., Milosavljević, Milutin, Kovačević, Tihomir M., Kovačina, Jovanka, Milošević, Milena D., Jovanović, Aleksandar, Petrović, Slobodan D., "Eco-friendly technology for gel-coat and fireproofing material production using bio-renewable and waste materials" in Catalogue of XVI International Salon of Inventions and New Technologies "New Time", Sevastopol, the Russian Federation, 24-26.09.2020. (2020):179-180,
https://hdl.handle.net/21.15107/rcub_cer_3687 .

Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale

Marinković, Aleksandar; Milosavljević, Milutin; Kovačević, Tihomir; Kovačina, Jovanka; Milošević, Milena; Jovanović, Aleksandar; Slobodan, Petrović

(2020)

TY  - CONF
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
AU  - Kovačević, Tihomir
AU  - Kovačina, Jovanka
AU  - Milošević, Milena
AU  - Jovanović, Aleksandar
AU  - Slobodan, Petrović
PY  - 2020
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6867
AB  - Razvijena je inovativna tehnologija za proizvodnju gelnih premaza i materijala koji smanjuju zapaljivost
na bazi nezasićenih poliestarskih smola (eng. Unsaturated polyester resins-UPR). Ovi materijali su
sintetisani iz sirovina dobijenih iz otpadnog poli(etilen) tereftalata (PET) i bio-obnovljivih izvora. Ovaj
proces čine tri faze: (I) sinteza hidroksilnih, karboksilnih i vinilnih termalnih monomera kao i anhidrida
maleinske kiseline na bio-osnovi iz 5-hidroksimetilfurfurala (HMF) i levulinske kiseline; proizvodi sa
termalnim hidroksilnim grupama, zasnovani su na otpadnom PET-u i karboksil, hidroksil i vinil termalnom
fosfatnom estru kraft lignina; (II) sinteza bio-UPR smola koristeći proizvode iz prve faze i vinil derivate iz
HMF-a i kraft lignina kao vezujućeg agensa za UPR smole; (III) homogenizacija UPR smola sa aditivima
(dispergatori, pigmenti, punioci i aditivi sintetisani u prvoj fazi) da bi dobili gelni premaz i sjedinili ga sa
usporivačem plamena (derivati fosfatnog estra lignina) i proizveli protiv požarni materijal. Predstavljene
tehnologije poštuju ekološke standarde kao i principe zelene i cirkularne ekonomije. Dobijeni proizvodi
mogu se primeniti u raznim industrijama (građevinarstvo, rudarstvo, prerada polimera itd.)
T1  - Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale
UR  - https://hdl.handle.net/21.15107/rcub_cer_6867
ER  - 
@conference{
author = "Marinković, Aleksandar and Milosavljević, Milutin and Kovačević, Tihomir and Kovačina, Jovanka and Milošević, Milena and Jovanović, Aleksandar and Slobodan, Petrović",
year = "2020",
abstract = "Razvijena je inovativna tehnologija za proizvodnju gelnih premaza i materijala koji smanjuju zapaljivost
na bazi nezasićenih poliestarskih smola (eng. Unsaturated polyester resins-UPR). Ovi materijali su
sintetisani iz sirovina dobijenih iz otpadnog poli(etilen) tereftalata (PET) i bio-obnovljivih izvora. Ovaj
proces čine tri faze: (I) sinteza hidroksilnih, karboksilnih i vinilnih termalnih monomera kao i anhidrida
maleinske kiseline na bio-osnovi iz 5-hidroksimetilfurfurala (HMF) i levulinske kiseline; proizvodi sa
termalnim hidroksilnim grupama, zasnovani su na otpadnom PET-u i karboksil, hidroksil i vinil termalnom
fosfatnom estru kraft lignina; (II) sinteza bio-UPR smola koristeći proizvode iz prve faze i vinil derivate iz
HMF-a i kraft lignina kao vezujućeg agensa za UPR smole; (III) homogenizacija UPR smola sa aditivima
(dispergatori, pigmenti, punioci i aditivi sintetisani u prvoj fazi) da bi dobili gelni premaz i sjedinili ga sa
usporivačem plamena (derivati fosfatnog estra lignina) i proizveli protiv požarni materijal. Predstavljene
tehnologije poštuju ekološke standarde kao i principe zelene i cirkularne ekonomije. Dobijeni proizvodi
mogu se primeniti u raznim industrijama (građevinarstvo, rudarstvo, prerada polimera itd.)",
title = "Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale",
url = "https://hdl.handle.net/21.15107/rcub_cer_6867"
}
Marinković, A., Milosavljević, M., Kovačević, T., Kovačina, J., Milošević, M., Jovanović, A.,& Slobodan, P.. (2020). Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale. .
https://hdl.handle.net/21.15107/rcub_cer_6867
Marinković A, Milosavljević M, Kovačević T, Kovačina J, Milošević M, Jovanović A, Slobodan P. Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale. 2020;.
https://hdl.handle.net/21.15107/rcub_cer_6867 .
Marinković, Aleksandar, Milosavljević, Milutin, Kovačević, Tihomir, Kovačina, Jovanka, Milošević, Milena, Jovanović, Aleksandar, Slobodan, Petrović, "Ekološki prihvatljiva tehnologija za proizvodnju gelnih premaza i protivpožarnih materijala koristeći bio-obnovljive i otpadne materijale" (2020),
https://hdl.handle.net/21.15107/rcub_cer_6867 .

Modified tannins for alkyd based anticorrosive coatings

Milošević, Milena D.; Daničić, Dunja; Kovačina, Jovanka; Bugarčić, Mladen; Rusmirović, Jelena; Kovačević, Tihomir M.; Marinković, Aleksandar D.

(Belgrade : Engineering Society for Corrosion, 2019)

TY  - JOUR
AU  - Milošević, Milena D.
AU  - Daničić, Dunja
AU  - Kovačina, Jovanka
AU  - Bugarčić, Mladen
AU  - Rusmirović, Jelena
AU  - Kovačević, Tihomir M.
AU  - Marinković, Aleksandar D.
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3461
AB  - The study of the synthesis of anticorrosive inhibitors, based on chemically modified tannins, and
their use in alkyd based coatings to improve anticorrosive properties is presented in this work.
Two methods of tannin modification were applied: direct method using ammonium hydroxide,
ammonium hydroxide/ammonium chloride buffer or diethylenetriamine (DETA); and a two-step
method including tannin modification with epichlorohydrin (ECH) in first step to produce epoxy
modified tannin, ET, and further modification with heteroaromatic amines or linseed oil fatty acids
(LFA) in second step. The obtained anticorrosive additives were characterized using ATR-FTIR,
1H and 13C NMR spectroscopies and elemental analysis. Epoxy, amino, hydroxyl, acid and iodine
values of the synthesized inhibitors were determined according to standard methods. The
prepared alkyd coating with tannin inhibitors was tested according to standard SRPS EN ISO
4628 method. Anticorrosive coating containing modified tannin based additive showed increased
anticorrosive properties, good adhesion and coverage comparing to the coating with zinc
phosphate additive. The alkyd coating films based on ET-LFA and ET modified with 2-amino-5-
mercapto-1,3,4-thiadiazole showed best anticorrosive results.
AB  - U ovom radu prikazana je sinteza antikorozionih aditiva na bazi hemijski modifikovanog tanina i njihova primena u alkidnim premazima u cilju poboljšanja antikorozionih svojstava. Prikazane su dve metode modifikacije tanina: direktna modifikacija tanina primenom amonijum-hidroksida, amonijum-hidroksid/amonijum-hlorid pufera ili dietilentriamina (DETA); i dvostepena modifikacija tanina koja u prvom stupnju uključuje modifikaciju epihlorhidrinom sa ciljem da se dobije tannin sa epoksi terminiranim funkcionalnim grupama, ET, i modifikaciju ET tanina sa heteroaromatičnim aminima ili masnim kiselinama izolovanim iz lanenog ulja (LFA) u drugom stupnju. Sintetisani antikorozioni aditivi su okarakterisani primenom ATR-FTIR, 1H i 13C NMR spektroskopija, i elementalnom analizom. Sadržaj epoksi, amino, hidroksilnih i karboksilnih grupa i vrednost jodnog broja sintetisanih aditiva određen je prema standardnim metodama. Alkidni premazi koji sadrže antikorozione aditive na bazi modifikovanog tanina ispitani su prema standardnoj SRPS EN ISO 4628 metodi. Antikorozivni alkidni premazi na bazi modfikovanih tanina pokazali su poboljšane antikorozione karakteristike i adheziju u poređenju sa alkidnim premazom na bazi cink-fosfata. Alkidni premazi koji sadrže dvostepeno modifikovani tanin sa LFA i 2-amino-5-merkapto-1,3,4-tiadiazolom pokazali su najbolje antikorozione karakteristike.
PB  - Belgrade : Engineering Society for Corrosion
T2  - Zastita materijala
T1  - Modified tannins for alkyd based anticorrosive coatings
T1  - Primena modifikovanih tanina u antikorozionim alkidnim premazima
VL  - 60
IS  - 1
SP  - 81
EP  - 95
DO  - 10.5937/zasmat1901081M
ER  - 
@article{
author = "Milošević, Milena D. and Daničić, Dunja and Kovačina, Jovanka and Bugarčić, Mladen and Rusmirović, Jelena and Kovačević, Tihomir M. and Marinković, Aleksandar D.",
year = "2019",
abstract = "The study of the synthesis of anticorrosive inhibitors, based on chemically modified tannins, and
their use in alkyd based coatings to improve anticorrosive properties is presented in this work.
Two methods of tannin modification were applied: direct method using ammonium hydroxide,
ammonium hydroxide/ammonium chloride buffer or diethylenetriamine (DETA); and a two-step
method including tannin modification with epichlorohydrin (ECH) in first step to produce epoxy
modified tannin, ET, and further modification with heteroaromatic amines or linseed oil fatty acids
(LFA) in second step. The obtained anticorrosive additives were characterized using ATR-FTIR,
1H and 13C NMR spectroscopies and elemental analysis. Epoxy, amino, hydroxyl, acid and iodine
values of the synthesized inhibitors were determined according to standard methods. The
prepared alkyd coating with tannin inhibitors was tested according to standard SRPS EN ISO
4628 method. Anticorrosive coating containing modified tannin based additive showed increased
anticorrosive properties, good adhesion and coverage comparing to the coating with zinc
phosphate additive. The alkyd coating films based on ET-LFA and ET modified with 2-amino-5-
mercapto-1,3,4-thiadiazole showed best anticorrosive results., U ovom radu prikazana je sinteza antikorozionih aditiva na bazi hemijski modifikovanog tanina i njihova primena u alkidnim premazima u cilju poboljšanja antikorozionih svojstava. Prikazane su dve metode modifikacije tanina: direktna modifikacija tanina primenom amonijum-hidroksida, amonijum-hidroksid/amonijum-hlorid pufera ili dietilentriamina (DETA); i dvostepena modifikacija tanina koja u prvom stupnju uključuje modifikaciju epihlorhidrinom sa ciljem da se dobije tannin sa epoksi terminiranim funkcionalnim grupama, ET, i modifikaciju ET tanina sa heteroaromatičnim aminima ili masnim kiselinama izolovanim iz lanenog ulja (LFA) u drugom stupnju. Sintetisani antikorozioni aditivi su okarakterisani primenom ATR-FTIR, 1H i 13C NMR spektroskopija, i elementalnom analizom. Sadržaj epoksi, amino, hidroksilnih i karboksilnih grupa i vrednost jodnog broja sintetisanih aditiva određen je prema standardnim metodama. Alkidni premazi koji sadrže antikorozione aditive na bazi modifikovanog tanina ispitani su prema standardnoj SRPS EN ISO 4628 metodi. Antikorozivni alkidni premazi na bazi modfikovanih tanina pokazali su poboljšane antikorozione karakteristike i adheziju u poređenju sa alkidnim premazom na bazi cink-fosfata. Alkidni premazi koji sadrže dvostepeno modifikovani tanin sa LFA i 2-amino-5-merkapto-1,3,4-tiadiazolom pokazali su najbolje antikorozione karakteristike.",
publisher = "Belgrade : Engineering Society for Corrosion",
journal = "Zastita materijala",
title = "Modified tannins for alkyd based anticorrosive coatings, Primena modifikovanih tanina u antikorozionim alkidnim premazima",
volume = "60",
number = "1",
pages = "81-95",
doi = "10.5937/zasmat1901081M"
}
Milošević, M. D., Daničić, D., Kovačina, J., Bugarčić, M., Rusmirović, J., Kovačević, T. M.,& Marinković, A. D.. (2019). Modified tannins for alkyd based anticorrosive coatings. in Zastita materijala
Belgrade : Engineering Society for Corrosion., 60(1), 81-95.
https://doi.org/10.5937/zasmat1901081M
Milošević MD, Daničić D, Kovačina J, Bugarčić M, Rusmirović J, Kovačević TM, Marinković AD. Modified tannins for alkyd based anticorrosive coatings. in Zastita materijala. 2019;60(1):81-95.
doi:10.5937/zasmat1901081M .
Milošević, Milena D., Daničić, Dunja, Kovačina, Jovanka, Bugarčić, Mladen, Rusmirović, Jelena, Kovačević, Tihomir M., Marinković, Aleksandar D., "Modified tannins for alkyd based anticorrosive coatings" in Zastita materijala, 60, no. 1 (2019):81-95,
https://doi.org/10.5937/zasmat1901081M . .
2

Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester

Rusmirović, Jelena; Daničić, Dunja; Kovačević, Tihomir; Bogosavljević, Marica; Brzić, Saša; Marinković, Aleksandar; Stevanović, Tatjana

(Belgrade : Military Technical Institute, 2018)

TY  - CONF
AU  - Rusmirović, Jelena
AU  - Daničić, Dunja
AU  - Kovačević, Tihomir
AU  - Bogosavljević, Marica
AU  - Brzić, Saša
AU  - Marinković, Aleksandar
AU  - Stevanović, Tatjana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6869
AB  - In this paper, the potential application of phosphorylated industrial kraft lignin (KLP) in improving flame 
retardant properties of unsaturated polyester/KLP composites (UPe/KLP) was studied. KLP mass contents in UPe based 
composites varied from 0.5 wt.% to 5.0 wt.%. The successfulness of the performed phosphorylation method, direct grafting 
of phosphorus chloride on KLP surface hydroxyl groups, and formation of phosphoric acid ester were confirmed via Fourier 
Transform-Infrared Spectroscopy (FT-IR). The effects of KLP surface functionalization and KLP mass contents on the UPe 
tensile properties were studied. Tensile strength (σ), elongation (ε) and Young’s modulus of elasticity (E) of the UPe/KLP 
composites were analyzed in relation to the structure of KLP modification. The obtained composites were tested on fire 
retardant properties according to the standard test method UL-94V.
PB  - Belgrade : Military Technical Institute
C3  - 8th International Scientific Conference on Defensive Technologies OTEH 2018, 11-12 October, 2018, Belgrade, Serbia
T1  - Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester
SP  - 538
EP  - 543
UR  - https://hdl.handle.net/21.15107/rcub_cer_6869
ER  - 
@conference{
author = "Rusmirović, Jelena and Daničić, Dunja and Kovačević, Tihomir and Bogosavljević, Marica and Brzić, Saša and Marinković, Aleksandar and Stevanović, Tatjana",
year = "2018",
abstract = "In this paper, the potential application of phosphorylated industrial kraft lignin (KLP) in improving flame 
retardant properties of unsaturated polyester/KLP composites (UPe/KLP) was studied. KLP mass contents in UPe based 
composites varied from 0.5 wt.% to 5.0 wt.%. The successfulness of the performed phosphorylation method, direct grafting 
of phosphorus chloride on KLP surface hydroxyl groups, and formation of phosphoric acid ester were confirmed via Fourier 
Transform-Infrared Spectroscopy (FT-IR). The effects of KLP surface functionalization and KLP mass contents on the UPe 
tensile properties were studied. Tensile strength (σ), elongation (ε) and Young’s modulus of elasticity (E) of the UPe/KLP 
composites were analyzed in relation to the structure of KLP modification. The obtained composites were tested on fire 
retardant properties according to the standard test method UL-94V.",
publisher = "Belgrade : Military Technical Institute",
journal = "8th International Scientific Conference on Defensive Technologies OTEH 2018, 11-12 October, 2018, Belgrade, Serbia",
title = "Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester",
pages = "538-543",
url = "https://hdl.handle.net/21.15107/rcub_cer_6869"
}
Rusmirović, J., Daničić, D., Kovačević, T., Bogosavljević, M., Brzić, S., Marinković, A.,& Stevanović, T.. (2018). Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester. in 8th International Scientific Conference on Defensive Technologies OTEH 2018, 11-12 October, 2018, Belgrade, Serbia
Belgrade : Military Technical Institute., 538-543.
https://hdl.handle.net/21.15107/rcub_cer_6869
Rusmirović J, Daničić D, Kovačević T, Bogosavljević M, Brzić S, Marinković A, Stevanović T. Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester. in 8th International Scientific Conference on Defensive Technologies OTEH 2018, 11-12 October, 2018, Belgrade, Serbia. 2018;:538-543.
https://hdl.handle.net/21.15107/rcub_cer_6869 .
Rusmirović, Jelena, Daničić, Dunja, Kovačević, Tihomir, Bogosavljević, Marica, Brzić, Saša, Marinković, Aleksandar, Stevanović, Tatjana, "Phosphorylated kraft lignin based flame retardant: efficient method for improvement of lignin flame retardancy and mechanical action in polyester" in 8th International Scientific Conference on Defensive Technologies OTEH 2018, 11-12 October, 2018, Belgrade, Serbia (2018):538-543,
https://hdl.handle.net/21.15107/rcub_cer_6869 .