TY  - CONF
AU  - Milentijević, Goran
AU  - Marinković, Tijana
AU  - Rančić, Milica
AU  - Milošević, Milena
AU  - Đuričković, Ivan
AU  - Marinković, Aleksandar D.
AU  - Milosavljević, Milutin M.
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6936
AB  - This work presents an optimized laboratory procedure for the synthesis of zinc dimethyldithiocarbamate (Ziram) by the reaction of the sodium salt of dimethyl dithiocarbamic acid and zinc sulfate. The reaction of synthesis of the sodium salt of dimethyl-dithiocarbamic acid takes place starting from dimethylamine, carbon disulfide and sodium hydroxide solution. To the prepared acidified aqueous solution of zinc sulphate, a solution of the sodium salt of dimethyl dithiocarbamic acid was added, whereby zinc dimethyldithiocarbamate is formed in the form of a suspension. The suspension is filtered, the filter cake is washed with water to remove the sulfate ion and dried. The structure of the obtained Ziram was confirmed by IR, 1H and 13C NMR and MS instrumental methods, and the purity was determined by the classical analytical method. The obtained product zinc dimethyldithiocarbamate was ground, formulated and used in pomiculture as fungicide under the trade name Ziram.
PB  - University of Belgrade, Technical Faculty in Bor
C3  - 29th International Conference Ecological Truth and Environmental Research - EcoTER'22, 21-24 June 2022, Sokobanja, Serbia
T1  - Optimization of zinc dimethyldithiocarbamate synthesis process (ziram)
SP  - 343
EP  - 349
UR  - https://hdl.handle.net/21.15107/rcub_cer_6936
ER  - 

@conference{
author = "Milentijević, Goran and Marinković, Tijana and Rančić, Milica and Milošević, Milena and Đuričković, Ivan and Marinković, Aleksandar D. and Milosavljević, Milutin M.",
year = "2022",
abstract = "This work presents an optimized laboratory procedure for the synthesis of zinc dimethyldithiocarbamate (Ziram) by the reaction of the sodium salt of dimethyl dithiocarbamic acid and zinc sulfate. The reaction of synthesis of the sodium salt of dimethyl-dithiocarbamic acid takes place starting from dimethylamine, carbon disulfide and sodium hydroxide solution. To the prepared acidified aqueous solution of zinc sulphate, a solution of the sodium salt of dimethyl dithiocarbamic acid was added, whereby zinc dimethyldithiocarbamate is formed in the form of a suspension. The suspension is filtered, the filter cake is washed with water to remove the sulfate ion and dried. The structure of the obtained Ziram was confirmed by IR, 1H and 13C NMR and MS instrumental methods, and the purity was determined by the classical analytical method. The obtained product zinc dimethyldithiocarbamate was ground, formulated and used in pomiculture as fungicide under the trade name Ziram.",
publisher = "University of Belgrade, Technical Faculty in Bor",
journal = "29th International Conference Ecological Truth and Environmental Research - EcoTER'22, 21-24 June 2022, Sokobanja, Serbia",
title = "Optimization of zinc dimethyldithiocarbamate synthesis process (ziram)",
pages = "343-349",
url = "https://hdl.handle.net/21.15107/rcub_cer_6936"
}

Milentijević, G., Marinković, T., Rančić, M., Milošević, M., Đuričković, I., Marinković, A. D.,& Milosavljević, M. M.. (2022). Optimization of zinc dimethyldithiocarbamate synthesis process (ziram). in 29th International Conference Ecological Truth and Environmental Research - EcoTER'22, 21-24 June 2022, Sokobanja, Serbia
University of Belgrade, Technical Faculty in Bor., 343-349.
https://hdl.handle.net/21.15107/rcub_cer_6936

Milentijević G, Marinković T, Rančić M, Milošević M, Đuričković I, Marinković AD, Milosavljević MM. Optimization of zinc dimethyldithiocarbamate synthesis process (ziram). in 29th International Conference Ecological Truth and Environmental Research - EcoTER'22, 21-24 June 2022, Sokobanja, Serbia. 2022;:343-349.
https://hdl.handle.net/21.15107/rcub_cer_6936 .

Milentijević, Goran, Marinković, Tijana, Rančić, Milica, Milošević, Milena, Đuričković, Ivan, Marinković, Aleksandar D., Milosavljević, Milutin M., "Optimization of zinc dimethyldithiocarbamate synthesis process (ziram)" in 29th International Conference Ecological Truth and Environmental Research - EcoTER'22, 21-24 June 2022, Sokobanja, Serbia (2022):343-349,
https://hdl.handle.net/21.15107/rcub_cer_6936 .

TY  - JOUR
AU  - Perendija, Jovana
AU  - Veličković, Zlate S.
AU  - Dražević, Ljubinka
AU  - Stojiljković, Ivana
AU  - Milčić, Miloš
AU  - Milosavljević, Milutin M.
AU  - Marinković, Aleksandar D.
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4830
AB  - Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced.
PB  - Belgrade : International Institute for the Science of Sintering (IISS)
T2  - Science of Sintering
T1  - Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using cell-MG hybrid adsorbent
VL  - 53
IS  - 3
SP  - 355
EP  - 378
DO  - 10.2298/SOS2103355P
ER  - 

@article{
author = "Perendija, Jovana and Veličković, Zlate S. and Dražević, Ljubinka and Stojiljković, Ivana and Milčić, Miloš and Milosavljević, Milutin M. and Marinković, Aleksandar D. and Pavlović, Vladimir B.",
year = "2021",
abstract = "Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced.",
publisher = "Belgrade : International Institute for the Science of Sintering (IISS)",
journal = "Science of Sintering",
title = "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using cell-MG hybrid adsorbent",
volume = "53",
number = "3",
pages = "355-378",
doi = "10.2298/SOS2103355P"
}

Perendija, J., Veličković, Z. S., Dražević, L., Stojiljković, I., Milčić, M., Milosavljević, M. M., Marinković, A. D.,& Pavlović, V. B.. (2021). Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using cell-MG hybrid adsorbent. in Science of Sintering
Belgrade : International Institute for the Science of Sintering (IISS)., 53(3), 355-378.
https://doi.org/10.2298/SOS2103355P

Perendija J, Veličković ZS, Dražević L, Stojiljković I, Milčić M, Milosavljević MM, Marinković AD, Pavlović VB. Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using cell-MG hybrid adsorbent. in Science of Sintering. 2021;53(3):355-378.
doi:10.2298/SOS2103355P .

Perendija, Jovana, Veličković, Zlate S., Dražević, Ljubinka, Stojiljković, Ivana, Milčić, Miloš, Milosavljević, Milutin M., Marinković, Aleksandar D., Pavlović, Vladimir B., "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using cell-MG hybrid adsorbent" in Science of Sintering, 53, no. 3 (2021):355-378,
https://doi.org/10.2298/SOS2103355P . .