TY  - JOUR
AU  - Janjić, Goran
AU  - Marinović, Sanja
AU  - Jadranin, Milka
AU  - Ajduković, Marija
AU  - Đorđević, Ivana
AU  - Petkovic-Benazzouz, Marija
AU  - Milutinović Nikolić, Aleksandra
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6693
AB  - The catalytic degradation of hazardous organic contaminants in industrial wastewater is a promising technology. Reactions of tartrazine, the synthetic yellow azo dye, with Oxone® in the presence of catalyst in strong acidic condition (pH 2), were detected by using UV–Vis spectroscopy. In order to extend the applicability profile of Co-supported Al-pillared montmorillonite catalyst an investigation of Oxone® induced reactions were performed in extreme acidic environment. The products of the reactions were identified by liquid chromatography–mass spectrometry (LC-MS). Along with the catalytic decomposition of tartrazine induced by radical attack (confirmed as unique reaction path under neutral and alkaline conditions), the formation of tartrazine derivatives by reaction of nucleophilic addition was also detected. The presence of derivatives under acidic conditions slowed down the hydrolysis of tartrazine diazo bond in comparison to the reactions in neutral environment. Nevertheless, the reaction in acidic conditions (pH 2) is faster than the one conducted in alkaline conditions (pH 11). Theoretical calculations were used to complete and clarify the mechanisms of tartrazine derivatization and degradation, as well as to predict the UV–Vis spectra of compounds which could serve as predictors of certain reaction phases. ECOSAR program, used to estimate toxicological profile of compounds to aquatic animals, indicated an increase in the harmfulness of the compounds identified by LC-MS as degradation products from the reaction conducted for 240min. It could be concluded that an intensification of the process parameters (higher concentration of Oxone®, higher catalyst loading, increased reaction time, etc.) is needed in order to obtain only biodegradable products.
PB  - Elsevier
T2  - Environmental Pollution
T1  - Degradation of tartrazine by Oxone® in the presence of cobalt based catalyst supported on pillared montmorillonite - Efficient technology even in extreme conditions
VL  - 331
SP  - 121863
DO  - 10.1016/j.envpol.2023.121863
ER  - 

@article{
author = "Janjić, Goran and Marinović, Sanja and Jadranin, Milka and Ajduković, Marija and Đorđević, Ivana and Petkovic-Benazzouz, Marija and Milutinović Nikolić, Aleksandra",
year = "2023",
abstract = "The catalytic degradation of hazardous organic contaminants in industrial wastewater is a promising technology. Reactions of tartrazine, the synthetic yellow azo dye, with Oxone® in the presence of catalyst in strong acidic condition (pH 2), were detected by using UV–Vis spectroscopy. In order to extend the applicability profile of Co-supported Al-pillared montmorillonite catalyst an investigation of Oxone® induced reactions were performed in extreme acidic environment. The products of the reactions were identified by liquid chromatography–mass spectrometry (LC-MS). Along with the catalytic decomposition of tartrazine induced by radical attack (confirmed as unique reaction path under neutral and alkaline conditions), the formation of tartrazine derivatives by reaction of nucleophilic addition was also detected. The presence of derivatives under acidic conditions slowed down the hydrolysis of tartrazine diazo bond in comparison to the reactions in neutral environment. Nevertheless, the reaction in acidic conditions (pH 2) is faster than the one conducted in alkaline conditions (pH 11). Theoretical calculations were used to complete and clarify the mechanisms of tartrazine derivatization and degradation, as well as to predict the UV–Vis spectra of compounds which could serve as predictors of certain reaction phases. ECOSAR program, used to estimate toxicological profile of compounds to aquatic animals, indicated an increase in the harmfulness of the compounds identified by LC-MS as degradation products from the reaction conducted for 240min. It could be concluded that an intensification of the process parameters (higher concentration of Oxone®, higher catalyst loading, increased reaction time, etc.) is needed in order to obtain only biodegradable products.",
publisher = "Elsevier",
journal = "Environmental Pollution",
title = "Degradation of tartrazine by Oxone® in the presence of cobalt based catalyst supported on pillared montmorillonite - Efficient technology even in extreme conditions",
volume = "331",
pages = "121863",
doi = "10.1016/j.envpol.2023.121863"
}

Janjić, G., Marinović, S., Jadranin, M., Ajduković, M., Đorđević, I., Petkovic-Benazzouz, M.,& Milutinović Nikolić, A.. (2023). Degradation of tartrazine by Oxone® in the presence of cobalt based catalyst supported on pillared montmorillonite - Efficient technology even in extreme conditions. in Environmental Pollution
Elsevier., 331, 121863.
https://doi.org/10.1016/j.envpol.2023.121863

Janjić G, Marinović S, Jadranin M, Ajduković M, Đorđević I, Petkovic-Benazzouz M, Milutinović Nikolić A. Degradation of tartrazine by Oxone® in the presence of cobalt based catalyst supported on pillared montmorillonite - Efficient technology even in extreme conditions. in Environmental Pollution. 2023;331:121863.
doi:10.1016/j.envpol.2023.121863 .

Janjić, Goran, Marinović, Sanja, Jadranin, Milka, Ajduković, Marija, Đorđević, Ivana, Petkovic-Benazzouz, Marija, Milutinović Nikolić, Aleksandra, "Degradation of tartrazine by Oxone® in the presence of cobalt based catalyst supported on pillared montmorillonite - Efficient technology even in extreme conditions" in Environmental Pollution, 331 (2023):121863,
https://doi.org/10.1016/j.envpol.2023.121863 . .