TY  - JOUR
AU  - Manić, Nebojša
AU  - Janković, Bojan
AU  - Stojiljković, Dragoslava
AU  - Popović, Mina
AU  - Cvetković, Slobodan
AU  - Mikulčić, Hrvoje
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5594
AB  - The actual paper analyses the performance of different energy crop biomasses, Miscanthus x giganteus Greef et Deu (EC-1) and Arundo donax L. (EC-2) stems, during slow pyrolysis process monitored by simultaneous TG-DTG-MS techniques, through chemical exergy analysis. In addition to considering the physical and chemical characteristics of given feedstocks for their efficient thermo-chemical conversion into pyrolytic gas, in this study, a theoretical simulation for their implementation use in the gasification process was also performed. The performed thermodynamic study with detailed exergy analysis showed that the large contribution of exergy in syngas components such as CO and H2 originates primarily from cellulose pyrolysis of EC-1, while large exergy contribution in syngas component as CH4 originates from lignin pyrolysis of EC-2. It was founded that the exergy efficiency of syngas for EC-1 equals 19.04%, which is lower than the exergy efficiency of syngas for EC-2 (20.46%), as a result of higher ash content in EC-1. Also, it was reported that higher carbon (C) and hydrogen (H) contents present in the EC-2 sample generate higher gaseous energy and exergy values, i.e. the increment of exergy efficiency of syngas, by both approaches (pyrolysis and gasification exergy analysis), but results in a lower biomass chemical exergy (18.28 MJ kg−1). The methodology applied to the gasification process was shown a higher exergy efficiency for EC-2 (∼36 – 42%) than for EC-1 (∼33 – 39%), dependant on the equivalence ratio (ER).
PB  - Elsevier B.V.
T2  - Thermochimica Acta
T1  - Thermodynamic study on energy crops thermochemical conversion to increase the efficiency of energy production
VL  - 719
SP  - 179408
DO  - 10.1016/j.tca.2022.179408
ER  - 

@article{
author = "Manić, Nebojša and Janković, Bojan and Stojiljković, Dragoslava and Popović, Mina and Cvetković, Slobodan and Mikulčić, Hrvoje",
year = "2023",
abstract = "The actual paper analyses the performance of different energy crop biomasses, Miscanthus x giganteus Greef et Deu (EC-1) and Arundo donax L. (EC-2) stems, during slow pyrolysis process monitored by simultaneous TG-DTG-MS techniques, through chemical exergy analysis. In addition to considering the physical and chemical characteristics of given feedstocks for their efficient thermo-chemical conversion into pyrolytic gas, in this study, a theoretical simulation for their implementation use in the gasification process was also performed. The performed thermodynamic study with detailed exergy analysis showed that the large contribution of exergy in syngas components such as CO and H2 originates primarily from cellulose pyrolysis of EC-1, while large exergy contribution in syngas component as CH4 originates from lignin pyrolysis of EC-2. It was founded that the exergy efficiency of syngas for EC-1 equals 19.04%, which is lower than the exergy efficiency of syngas for EC-2 (20.46%), as a result of higher ash content in EC-1. Also, it was reported that higher carbon (C) and hydrogen (H) contents present in the EC-2 sample generate higher gaseous energy and exergy values, i.e. the increment of exergy efficiency of syngas, by both approaches (pyrolysis and gasification exergy analysis), but results in a lower biomass chemical exergy (18.28 MJ kg−1). The methodology applied to the gasification process was shown a higher exergy efficiency for EC-2 (∼36 – 42%) than for EC-1 (∼33 – 39%), dependant on the equivalence ratio (ER).",
publisher = "Elsevier B.V.",
journal = "Thermochimica Acta",
title = "Thermodynamic study on energy crops thermochemical conversion to increase the efficiency of energy production",
volume = "719",
pages = "179408",
doi = "10.1016/j.tca.2022.179408"
}

Manić, N., Janković, B., Stojiljković, D., Popović, M., Cvetković, S.,& Mikulčić, H.. (2023). Thermodynamic study on energy crops thermochemical conversion to increase the efficiency of energy production. in Thermochimica Acta
Elsevier B.V.., 719, 179408.
https://doi.org/10.1016/j.tca.2022.179408

Manić N, Janković B, Stojiljković D, Popović M, Cvetković S, Mikulčić H. Thermodynamic study on energy crops thermochemical conversion to increase the efficiency of energy production. in Thermochimica Acta. 2023;719:179408.
doi:10.1016/j.tca.2022.179408 .

Manić, Nebojša, Janković, Bojan, Stojiljković, Dragoslava, Popović, Mina, Cvetković, Slobodan, Mikulčić, Hrvoje, "Thermodynamic study on energy crops thermochemical conversion to increase the efficiency of energy production" in Thermochimica Acta, 719 (2023):179408,
https://doi.org/10.1016/j.tca.2022.179408 . .

TY  - JOUR
AU  - Janković, Bojan
AU  - Manić, Nebojša
AU  - Popović, Mina
AU  - Cvetković, Slobodan
AU  - Dželetović, Željko
AU  - Stojiljković, Dragoslava
PY  - 2023
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5647
AB  - This work provides insight into possibilities of maximum utilization of C3-C4 energy crops for thermo-chemical conversion (slow pyrolysis) into high value biochemicals, platform chemicals, drop-in fuels and combustible gases, using coupled kinetic and thermodynamic analyses. In order to examine the kinetics of decomposition of lignocellulosic components, model-free and model-based methods faded from thermal analysis data were used. Thermodynamic compensation was used for explicatory of entropy controlled process, where conformational changes and chemical exchange directly affect the type and distribution of obtained pyrolytic products. It was shown that external variable (i.e. the heating rate/temperature) does not change either an entire reaction mechanism (mechanistic nature of MG and AD pyrolyses) or transition state, but it changes activation enthalpy and activation entropy which lead to differences in terms of heat energy consumption, pyrolysis favorability and thus rates of generation of activated complex among feedstocks. To investigate the interplay of catalysts (present in feedstocks as minerals) and reactants, selective energy transfer (SET) model was applied. The model showed an activity of catalyst with different outputs towards two reactants, lignin part of the structure in MG and 1,8-cineole in AD. It was shown that AD is more convenient for thermal conversion than MG, regarding to lower transformation energy requirement, higher reactivity, as well as much faster accumulation of products.
PB  - Elsevier B.V.
T2  - Industrial Crops and Products
T1  - Kinetic and thermodynamic compensation phenomena in C3 and C4 energy crops pyrolysis: Implications on reaction mechanisms and product distributions
VL  - 194
SP  - 116275
DO  - 10.1016/j.indcrop.2023.116275
ER  - 

@article{
author = "Janković, Bojan and Manić, Nebojša and Popović, Mina and Cvetković, Slobodan and Dželetović, Željko and Stojiljković, Dragoslava",
year = "2023",
abstract = "This work provides insight into possibilities of maximum utilization of C3-C4 energy crops for thermo-chemical conversion (slow pyrolysis) into high value biochemicals, platform chemicals, drop-in fuels and combustible gases, using coupled kinetic and thermodynamic analyses. In order to examine the kinetics of decomposition of lignocellulosic components, model-free and model-based methods faded from thermal analysis data were used. Thermodynamic compensation was used for explicatory of entropy controlled process, where conformational changes and chemical exchange directly affect the type and distribution of obtained pyrolytic products. It was shown that external variable (i.e. the heating rate/temperature) does not change either an entire reaction mechanism (mechanistic nature of MG and AD pyrolyses) or transition state, but it changes activation enthalpy and activation entropy which lead to differences in terms of heat energy consumption, pyrolysis favorability and thus rates of generation of activated complex among feedstocks. To investigate the interplay of catalysts (present in feedstocks as minerals) and reactants, selective energy transfer (SET) model was applied. The model showed an activity of catalyst with different outputs towards two reactants, lignin part of the structure in MG and 1,8-cineole in AD. It was shown that AD is more convenient for thermal conversion than MG, regarding to lower transformation energy requirement, higher reactivity, as well as much faster accumulation of products.",
publisher = "Elsevier B.V.",
journal = "Industrial Crops and Products",
title = "Kinetic and thermodynamic compensation phenomena in C3 and C4 energy crops pyrolysis: Implications on reaction mechanisms and product distributions",
volume = "194",
pages = "116275",
doi = "10.1016/j.indcrop.2023.116275"
}

Janković, B., Manić, N., Popović, M., Cvetković, S., Dželetović, Ž.,& Stojiljković, D.. (2023). Kinetic and thermodynamic compensation phenomena in C3 and C4 energy crops pyrolysis: Implications on reaction mechanisms and product distributions. in Industrial Crops and Products
Elsevier B.V.., 194, 116275.
https://doi.org/10.1016/j.indcrop.2023.116275

Janković B, Manić N, Popović M, Cvetković S, Dželetović Ž, Stojiljković D. Kinetic and thermodynamic compensation phenomena in C3 and C4 energy crops pyrolysis: Implications on reaction mechanisms and product distributions. in Industrial Crops and Products. 2023;194:116275.
doi:10.1016/j.indcrop.2023.116275 .

Janković, Bojan, Manić, Nebojša, Popović, Mina, Cvetković, Slobodan, Dželetović, Željko, Stojiljković, Dragoslava, "Kinetic and thermodynamic compensation phenomena in C3 and C4 energy crops pyrolysis: Implications on reaction mechanisms and product distributions" in Industrial Crops and Products, 194 (2023):116275,
https://doi.org/10.1016/j.indcrop.2023.116275 . .