Mitrić, Miodrag

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Authority KeyName Variants
orcid::0000-0002-1709-9890
  • Mitrić, Miodrag (29)
Projects
Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions
Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites Directed synthesis, structure and properties of multifunctional materials
Synthesis, processing and applications of nanostructured multifunctional materials with defined properties Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion
Investigation of intermetallics and semiconductors and possible application in renewable energy sources Development of Methods of Monitoring and Removal of Biologically Actives Substances Aimed at Improving the Quality of the Environment
New approach in designing materials for energy conversion and energy storage systems Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them
Lithium-ion batteries and fuel cells - research and development Magnetic and radionuclide labeled nanostructured materials for medical applications
NASA - NNX09AV07A NSF CREST - HRD-0833184
Serbian Academy of Science and Arts - F/198 STSM Grant from COST Action [BM1403]
CMST COST Action CM 1304 ‘‘Emergence and Evolution of Complex Chemical Systems’’ CMST COST Action Emergence and Evolution of Complex Chemical Systems - CM1304
The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences Chemical and structural designing of nanomaterials for application in medicine and tissue engineering
Biomarkers in neurodegenerative and malignant processes Functional, Functionalized and Advanced Nanomaterials
Sinteza, karakterizacija i testiranje katalitičkih svojstava specijalno dizajniranih materijala Kompozitni materijali na bazi ugljenika, metala i oksida metala u elektrokatalizi i procesima skladištenja energije
Elektrohemijske karakteristike oksidnih i polimernih prevlaka na modifikovanim površinama metala Ministry and DAAD, Germany, Project No.:57334757
NASA - NNX09AVO7A NSF - HRD0833184

Author's Bibliography

Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells

Eraković, Sanja; Pavlović, Miroslav; Stopić, Srećko; Mitrić, Miodrag; Varničić, Miroslava; Stevanović, Jasmina; Panić, Vladimir; Friedrich, Bernd

(International Association of Physical Chemists, 2019)

TY  - CONF
AU  - Eraković, Sanja
AU  - Pavlović, Miroslav
AU  - Stopić, Srećko
AU  - Mitrić, Miodrag
AU  - Varničić, Miroslava
AU  - Stevanović, Jasmina
AU  - Panić, Vladimir
AU  - Friedrich, Bernd
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/6656
AB  - Perovskite have emerged as promising materials in newly invented energy storage and conversion devices due to their exceptional thermal stability, electronic structure, ionic conductivity, electron mobility, and redox behaviour [1]. Among perovskite that are suitable as catalyst for electrode in supercapacitors and solid oxide fuel cells, lanthanum strontium cobalt oxides have shown promising catalytic activity and relatively high stability [1]. Also, Co-based lanthanum manganite (LMCO) has been used as cathode material with a high electro-chemical catalytic activity for oxygen reduction[2].Ultrasonic spray pyrolysis (USP) was used to successfully synthesize spherical sub-µm-sized of La0.6Sr0.4CoO3 (LSCO) and Mn and Sr-doped LaCoO3 powders. LSCO should be of wider voltage window than carbonaceous materials, with the possibility to adopt the pseudocapacitive oxide, such as RuO2, not only by simple surface adsorption, but over full or partial incorporation into the oxide structure. Hence, this work aims to investigate supercapacitive potentials of pure LSCO prepared by single step USP and LSCO doped with RuO2. The catalytic activity of Sr and Mn cation substitution in lanthanum cobalt oxide was also investigated. Electrochemical behaviour was investigated by EIS, CV and LSV techniques. The EIS and CV analyses showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive abilities of RuO2 itself while being hosted by LSCO. The investigated LMCO electrodes by CV and LSV techniques showed excellent catalytic activity for oxygen reduction. Our work indicated that these perovskite shows potential applications in the field of pseudocapacitance electrode materials and is worthy of further investigation.
PB  - International Association of Physical Chemists
C3  - Book of abstracts - 7th Regional Symposium on Electrochemistry – South East Europe & 8th Kurt Schwabe Symposium, May 27-30, Split, Croatia
T1  - Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells
SP  - 116
EP  - 116
UR  - https://hdl.handle.net/21.15107/rcub_cer_6656
ER  - 
@conference{
author = "Eraković, Sanja and Pavlović, Miroslav and Stopić, Srećko and Mitrić, Miodrag and Varničić, Miroslava and Stevanović, Jasmina and Panić, Vladimir and Friedrich, Bernd",
year = "2019",
abstract = "Perovskite have emerged as promising materials in newly invented energy storage and conversion devices due to their exceptional thermal stability, electronic structure, ionic conductivity, electron mobility, and redox behaviour [1]. Among perovskite that are suitable as catalyst for electrode in supercapacitors and solid oxide fuel cells, lanthanum strontium cobalt oxides have shown promising catalytic activity and relatively high stability [1]. Also, Co-based lanthanum manganite (LMCO) has been used as cathode material with a high electro-chemical catalytic activity for oxygen reduction[2].Ultrasonic spray pyrolysis (USP) was used to successfully synthesize spherical sub-µm-sized of La0.6Sr0.4CoO3 (LSCO) and Mn and Sr-doped LaCoO3 powders. LSCO should be of wider voltage window than carbonaceous materials, with the possibility to adopt the pseudocapacitive oxide, such as RuO2, not only by simple surface adsorption, but over full or partial incorporation into the oxide structure. Hence, this work aims to investigate supercapacitive potentials of pure LSCO prepared by single step USP and LSCO doped with RuO2. The catalytic activity of Sr and Mn cation substitution in lanthanum cobalt oxide was also investigated. Electrochemical behaviour was investigated by EIS, CV and LSV techniques. The EIS and CV analyses showed that RuO2 catalyzes the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive abilities of RuO2 itself while being hosted by LSCO. The investigated LMCO electrodes by CV and LSV techniques showed excellent catalytic activity for oxygen reduction. Our work indicated that these perovskite shows potential applications in the field of pseudocapacitance electrode materials and is worthy of further investigation.",
publisher = "International Association of Physical Chemists",
journal = "Book of abstracts - 7th Regional Symposium on Electrochemistry – South East Europe & 8th Kurt Schwabe Symposium, May 27-30, Split, Croatia",
title = "Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells",
pages = "116-116",
url = "https://hdl.handle.net/21.15107/rcub_cer_6656"
}
Eraković, S., Pavlović, M., Stopić, S., Mitrić, M., Varničić, M., Stevanović, J., Panić, V.,& Friedrich, B.. (2019). Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells. in Book of abstracts - 7th Regional Symposium on Electrochemistry – South East Europe & 8th Kurt Schwabe Symposium, May 27-30, Split, Croatia
International Association of Physical Chemists., 116-116.
https://hdl.handle.net/21.15107/rcub_cer_6656
Eraković S, Pavlović M, Stopić S, Mitrić M, Varničić M, Stevanović J, Panić V, Friedrich B. Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells. in Book of abstracts - 7th Regional Symposium on Electrochemistry – South East Europe & 8th Kurt Schwabe Symposium, May 27-30, Split, Croatia. 2019;:116-116.
https://hdl.handle.net/21.15107/rcub_cer_6656 .
Eraković, Sanja, Pavlović, Miroslav, Stopić, Srećko, Mitrić, Miodrag, Varničić, Miroslava, Stevanović, Jasmina, Panić, Vladimir, Friedrich, Bernd, "Electrochemical performances of rare earth Co-based mixed oxides and their application as supercapacitors and fuel cells" in Book of abstracts - 7th Regional Symposium on Electrochemistry – South East Europe & 8th Kurt Schwabe Symposium, May 27-30, Split, Croatia (2019):116-116,
https://hdl.handle.net/21.15107/rcub_cer_6656 .

Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function

Mojović, Zorica; Novaković, Tatjana; Mojović, Miloš; Barudžija, Tanja; Mitrić, Miodrag

(International Institute for the Science of Sintering, Beograd, 2019)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Novaković, Tatjana
AU  - Mojović, Miloš
AU  - Barudžija, Tanja
AU  - Mitrić, Miodrag
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3248
AB  - Alumina powders, pure and doped with nickel, were synthetized by sol-gel method and calcined at 500, 900 and 1100°C in order to obtain mesoporous structures with a high specific surface area, well adapTab. to catalytic application. The characterization of samples was performed by XRD, EPR spectroscopy and electrochemical impedance spectroscopy (EIS). XRD analysis showed that the addition of Ni2+, as well as the annealing temperature, affects the structural properties of the obtained composites. EPR analysis revealed the traces of Fe3+ impurities, the presence of oxy defects in alumina and Ni2+ in tetrahedral position for samples calcined at 1100°C. The impedance of the Nafion/alumina modified GCE depended on combined effect of porous structure and surface properties of alumina samples. The electrochemical behavior of a glassy carbon electrode modified with Ni (II)-doped aluminas was studied in 0.5 M NaOH solution, with and without methanol. The electrochemical activity of nickel-doped alumina composites was dictated by the amount of present NiO impurity.
AB  - Прахови алумине, без додатка и са додатком никла, синтетисани су сол-гел методом и жарени на 500, 900 и 1100 oC с циљем да се добију мезопорозне структуре са високом специфичном површином, применљиве у каталитичке сврхе. Карактеризација узорака вршена је са XRD, EPR и EIS спектроскопијом. XRD анализа показала је да и додатак Ni2+-јона, као и температура жарења, утичу на структурне особине добијених композита. EPR анализом утврђено је присуство Fe3+-јона у траговима, окси-дефеката у алумини и Ni2+-јона у тетраедарским позицијама у узорцима жареним на 1100 oC. Импеданса стакло-карбон електроде модификоване нафион/алумином, зависила је од комбинованог ефекта порозне структуре и површинских карактеристика узорака алумине. Електрохемијско понашање модификоване стакло-карбон електроде испитивано је у 0.5M раствору NaOH, без и са метанолом. Електрохемијска активност никл-алумина композита диктирана је присуством NiO фазе.
PB  - International Institute for the Science of Sintering, Beograd
T2  - Science of Sintering
T1  - Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function
VL  - 51
IS  - 3
SP  - 339
EP  - 351
DO  - 10.2298/SOS1903339M
ER  - 
@article{
author = "Mojović, Zorica and Novaković, Tatjana and Mojović, Miloš and Barudžija, Tanja and Mitrić, Miodrag",
year = "2019",
abstract = "Alumina powders, pure and doped with nickel, were synthetized by sol-gel method and calcined at 500, 900 and 1100°C in order to obtain mesoporous structures with a high specific surface area, well adapTab. to catalytic application. The characterization of samples was performed by XRD, EPR spectroscopy and electrochemical impedance spectroscopy (EIS). XRD analysis showed that the addition of Ni2+, as well as the annealing temperature, affects the structural properties of the obtained composites. EPR analysis revealed the traces of Fe3+ impurities, the presence of oxy defects in alumina and Ni2+ in tetrahedral position for samples calcined at 1100°C. The impedance of the Nafion/alumina modified GCE depended on combined effect of porous structure and surface properties of alumina samples. The electrochemical behavior of a glassy carbon electrode modified with Ni (II)-doped aluminas was studied in 0.5 M NaOH solution, with and without methanol. The electrochemical activity of nickel-doped alumina composites was dictated by the amount of present NiO impurity., Прахови алумине, без додатка и са додатком никла, синтетисани су сол-гел методом и жарени на 500, 900 и 1100 oC с циљем да се добију мезопорозне структуре са високом специфичном површином, применљиве у каталитичке сврхе. Карактеризација узорака вршена је са XRD, EPR и EIS спектроскопијом. XRD анализа показала је да и додатак Ni2+-јона, као и температура жарења, утичу на структурне особине добијених композита. EPR анализом утврђено је присуство Fe3+-јона у траговима, окси-дефеката у алумини и Ni2+-јона у тетраедарским позицијама у узорцима жареним на 1100 oC. Импеданса стакло-карбон електроде модификоване нафион/алумином, зависила је од комбинованог ефекта порозне структуре и површинских карактеристика узорака алумине. Електрохемијско понашање модификоване стакло-карбон електроде испитивано је у 0.5M раствору NaOH, без и са метанолом. Електрохемијска активност никл-алумина композита диктирана је присуством NiO фазе.",
publisher = "International Institute for the Science of Sintering, Beograd",
journal = "Science of Sintering",
title = "Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function",
volume = "51",
number = "3",
pages = "339-351",
doi = "10.2298/SOS1903339M"
}
Mojović, Z., Novaković, T., Mojović, M., Barudžija, T.,& Mitrić, M.. (2019). Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function. in Science of Sintering
International Institute for the Science of Sintering, Beograd., 51(3), 339-351.
https://doi.org/10.2298/SOS1903339M
Mojović Z, Novaković T, Mojović M, Barudžija T, Mitrić M. Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function. in Science of Sintering. 2019;51(3):339-351.
doi:10.2298/SOS1903339M .
Mojović, Zorica, Novaković, Tatjana, Mojović, Miloš, Barudžija, Tanja, Mitrić, Miodrag, "Electrochemical and structural properties of Ni(II)-alumina composites as an annealing temperature function" in Science of Sintering, 51, no. 3 (2019):339-351,
https://doi.org/10.2298/SOS1903339M . .
3
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Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide

Eraković, Sanja; Pavlović, Miroslav M.; Stopić, Srećko; Stevanović, Jasmina; Mitrić, Miodrag; Friedrich, Bernd; Panić, Vladimir

(Elsevier, 2019)

TY  - JOUR
AU  - Eraković, Sanja
AU  - Pavlović, Miroslav M.
AU  - Stopić, Srećko
AU  - Stevanović, Jasmina
AU  - Mitrić, Miodrag
AU  - Friedrich, Bernd
AU  - Panić, Vladimir
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3207
AB  - Considerable promotion of RuO2 hosted by perovskite-like structure of rare eartheCoO3 composite and
vice versa supercapacitive performances is reported. Spherical, sub-mm-sized, regular spheres of
La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently
hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their
supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied
by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate
partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry
(CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly
revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of
RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the
promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes
the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2
abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite
as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability
with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide
VL  - 321
SP  - 134721
DO  - 10.1016/j.electacta.2019.134721
ER  - 
@article{
author = "Eraković, Sanja and Pavlović, Miroslav M. and Stopić, Srećko and Stevanović, Jasmina and Mitrić, Miodrag and Friedrich, Bernd and Panić, Vladimir",
year = "2019",
abstract = "Considerable promotion of RuO2 hosted by perovskite-like structure of rare eartheCoO3 composite and
vice versa supercapacitive performances is reported. Spherical, sub-mm-sized, regular spheres of
La0.6Sr0.4CoO3 (LSCO), were synthesized by ultrasonic spray pyrolysis. The sphere surface was subsequently
hydrothermally doped by RuO2. LSCO and LSCO/RuO2 composites were investigated for their
supercapacitive performances in alkaline solution. Microstructure and surface morphology were studied
by SEM and XRD. It was found that amorphous Ru species decorate LSCO surface, and possibly incorporate
partially into B-site of the LSCO lattice. Electrochemical characterization by cyclic voltammetry
(CV), galvanostatic charge-discharge (G-C/DC) and electrochemical impedance spectroscopy (EIS) clearly
revealed that capacitive performances of LSCO are considerably improved by addition of 20 mass. % of
RuO2. The registered capacitance for LSCO/RuO2 reaches the values of pure RuO2, which reveals the
promoting influence of LSCO on RuO2 pseudocapacitance. The EIS analysis showed that RuO2 catalyzes
the redox transition of Co species, with simultaneous proportional increase in pseudocapacitive RuO2
abilities while being hosted by LSCO. This intrinsic interactive promotion introduces LSCO/RuO2 composite
as unique supercapacitive material. G-C/DC curves showed that LSCO/RuO2 is of modest cyclability
with respect to pure LSCO and RuO2, although the capacitance losses with cycling are acceptably low.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide",
volume = "321",
pages = "134721",
doi = "10.1016/j.electacta.2019.134721"
}
Eraković, S., Pavlović, M. M., Stopić, S., Stevanović, J., Mitrić, M., Friedrich, B.,& Panić, V.. (2019). Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta
Elsevier., 321, 134721.
https://doi.org/10.1016/j.electacta.2019.134721
Eraković S, Pavlović MM, Stopić S, Stevanović J, Mitrić M, Friedrich B, Panić V. Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide. in Electrochimica Acta. 2019;321:134721.
doi:10.1016/j.electacta.2019.134721 .
Eraković, Sanja, Pavlović, Miroslav M., Stopić, Srećko, Stevanović, Jasmina, Mitrić, Miodrag, Friedrich, Bernd, Panić, Vladimir, "Interactive promotion of supercapacitance of rare earth/CoO3-based spray pyrolytic perovskite microspheres hosting the hydrothermal ruthenium oxide" in Electrochimica Acta, 321 (2019):134721,
https://doi.org/10.1016/j.electacta.2019.134721 . .
4
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Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Ivanovski, Valentin N.; Škapin, Srečo Davor; Dojčinović, Biljana; Uskoković, Dragan

(Elsevier, 2019)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Dojčinović, Biljana
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4938
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3330
AB  - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
VL  - 786
SP  - 912
EP  - 919
DO  - 10.1016/j.jallcom.2019.01.392
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan",
year = "2019",
abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose",
volume = "786",
pages = "912-919",
doi = "10.1016/j.jallcom.2019.01.392"
}
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds
Elsevier., 786, 912-919.
https://doi.org/10.1016/j.jallcom.2019.01.392
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919.
doi:10.1016/j.jallcom.2019.01.392 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919,
https://doi.org/10.1016/j.jallcom.2019.01.392 . .
4
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6

Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose

Jugović, Dragana; Mitrić, Miodrag; Milović, Miloš; Ivanovski, Valentin N.; Škapin, Srečo Davor; Dojčinović, Biljana; Uskoković, Dragan

(Elsevier, 2019)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Milović, Miloš
AU  - Ivanovski, Valentin N.
AU  - Škapin, Srečo Davor
AU  - Dojčinović, Biljana
AU  - Uskoković, Dragan
PY  - 2019
UR  - http://dais.sanu.ac.rs/123456789/4937
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2649
AB  - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
VL  - 786
SP  - 912
EP  - 919
DO  - 10.1016/j.jallcom.2019.01.392
ER  - 
@article{
author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan",
year = "2019",
abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose",
volume = "786",
pages = "912-919",
doi = "10.1016/j.jallcom.2019.01.392"
}
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds
Elsevier., 786, 912-919.
https://doi.org/10.1016/j.jallcom.2019.01.392
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919.
doi:10.1016/j.jallcom.2019.01.392 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919,
https://doi.org/10.1016/j.jallcom.2019.01.392 . .
4
3
6

Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation

Banić, Nemanja; Abramović, Biljana F.; Krstić, Jugoslav; Šojić, Merkulov D.V.; Finčur, Nina L.; Mitrić, Miodrag

(Korean Society of Industrial Engineering Chemistry, 2019)

TY  - JOUR
AU  - Banić, Nemanja
AU  - Abramović, Biljana F.
AU  - Krstić, Jugoslav
AU  - Šojić, Merkulov D.V.
AU  - Finčur, Nina L.
AU  - Mitrić, Miodrag
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2502
AB  - This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.
PB  - Korean Society of Industrial Engineering Chemistry
T2  - Journal of Industrial and Engineering Chemistry
T1  - Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
VL  - 70
SP  - 264
EP  - 275
DO  - 10.1016/j.jiec.2018.10.025
ER  - 
@article{
author = "Banić, Nemanja and Abramović, Biljana F. and Krstić, Jugoslav and Šojić, Merkulov D.V. and Finčur, Nina L. and Mitrić, Miodrag",
year = "2019",
abstract = "This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.",
publisher = "Korean Society of Industrial Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation",
volume = "70",
pages = "264-275",
doi = "10.1016/j.jiec.2018.10.025"
}
Banić, N., Abramović, B. F., Krstić, J., Šojić, M. D.V., Finčur, N. L.,& Mitrić, M.. (2019). Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry
Korean Society of Industrial Engineering Chemistry., 70, 264-275.
https://doi.org/10.1016/j.jiec.2018.10.025
Banić N, Abramović BF, Krstić J, Šojić MD, Finčur NL, Mitrić M. Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry. 2019;70:264-275.
doi:10.1016/j.jiec.2018.10.025 .
Banić, Nemanja, Abramović, Biljana F., Krstić, Jugoslav, Šojić, Merkulov D.V., Finčur, Nina L., Mitrić, Miodrag, "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation" in Journal of Industrial and Engineering Chemistry, 70 (2019):264-275,
https://doi.org/10.1016/j.jiec.2018.10.025 . .
34
16
32

Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation

Banić, Nemanja; Abramović, Biljana F.; Krstić, Jugoslav; Šojić, Merkulov D.V.; Finčur, Nina L.; Mitrić, Miodrag

(Korean Society of Industrial Engineering Chemistry, 2019)

TY  - JOUR
AU  - Banić, Nemanja
AU  - Abramović, Biljana F.
AU  - Krstić, Jugoslav
AU  - Šojić, Merkulov D.V.
AU  - Finčur, Nina L.
AU  - Mitrić, Miodrag
PY  - 2019
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2901
AB  - This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.
PB  - Korean Society of Industrial Engineering Chemistry
T2  - Journal of Industrial and Engineering Chemistry
T1  - Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
VL  - 70
SP  - 264
EP  - 275
DO  - 10.1016/j.jiec.2018.10.025
ER  - 
@article{
author = "Banić, Nemanja and Abramović, Biljana F. and Krstić, Jugoslav and Šojić, Merkulov D.V. and Finčur, Nina L. and Mitrić, Miodrag",
year = "2019",
abstract = "This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed.",
publisher = "Korean Society of Industrial Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation",
volume = "70",
pages = "264-275",
doi = "10.1016/j.jiec.2018.10.025"
}
Banić, N., Abramović, B. F., Krstić, J., Šojić, M. D.V., Finčur, N. L.,& Mitrić, M.. (2019). Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry
Korean Society of Industrial Engineering Chemistry., 70, 264-275.
https://doi.org/10.1016/j.jiec.2018.10.025
Banić N, Abramović BF, Krstić J, Šojić MD, Finčur NL, Mitrić M. Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry. 2019;70:264-275.
doi:10.1016/j.jiec.2018.10.025 .
Banić, Nemanja, Abramović, Biljana F., Krstić, Jugoslav, Šojić, Merkulov D.V., Finčur, Nina L., Mitrić, Miodrag, "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation" in Journal of Industrial and Engineering Chemistry, 70 (2019):264-275,
https://doi.org/10.1016/j.jiec.2018.10.025 . .
34
16
32

Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions

Stanić, Vojislav Dj.; Adnađević, Borivoj K.; Dimitrijević, Suzana I.; Dimović, Slavko; Mitrić, Miodrag; Zmejkovski, Bojana; Smiljanić, Slavko

(Belgrade : Vinča Institute of Nuclear Sciences, 2018)

TY  - JOUR
AU  - Stanić, Vojislav Dj.
AU  - Adnađević, Borivoj K.
AU  - Dimitrijević, Suzana I.
AU  - Dimović, Slavko
AU  - Mitrić, Miodrag
AU  - Zmejkovski, Bojana
AU  - Smiljanić, Slavko
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2453
AB  - Fluorapatite nanopowders with different amounts of fluoride ions were prepared using the surfactant-assisted microwave method under isothermal conditions. Microwave irradiation was applied for the rapid formation of crystals. A micellar solution of polyoxyethylene (23) lauryl ether was used as a regulator of nucleation and crystal growth. Characterization studies from X-ray diffraction, field-emission scaning electron microscopy and Fourier(-)transform infrared spectra showed that crystals have an apatite structure and particles of all samples are nano size, with an average length of 50 mn and about 15-25 nm in diameter. Antimicrobial studies have demonstrated that synthesized fluorapatite nanopowders exhibit activity against tested pathogens: Eseherichia coli, Staphylococcus aureus and Candida albicans. Activity increased with the amount of fluoride ions. The synthesized fluorapatite nanomaterials are promising as materials in environmental protection and medicine for orthopedics and dental restorations.
PB  - Belgrade : Vinča Institute of Nuclear Sciences
T2  - Nuclear Technology & Radiation Protection
T1  - Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions
VL  - 33
IS  - 2
SP  - 180
EP  - 187
DO  - 10.2298/NTRP1802180S
ER  - 
@article{
author = "Stanić, Vojislav Dj. and Adnađević, Borivoj K. and Dimitrijević, Suzana I. and Dimović, Slavko and Mitrić, Miodrag and Zmejkovski, Bojana and Smiljanić, Slavko",
year = "2018",
abstract = "Fluorapatite nanopowders with different amounts of fluoride ions were prepared using the surfactant-assisted microwave method under isothermal conditions. Microwave irradiation was applied for the rapid formation of crystals. A micellar solution of polyoxyethylene (23) lauryl ether was used as a regulator of nucleation and crystal growth. Characterization studies from X-ray diffraction, field-emission scaning electron microscopy and Fourier(-)transform infrared spectra showed that crystals have an apatite structure and particles of all samples are nano size, with an average length of 50 mn and about 15-25 nm in diameter. Antimicrobial studies have demonstrated that synthesized fluorapatite nanopowders exhibit activity against tested pathogens: Eseherichia coli, Staphylococcus aureus and Candida albicans. Activity increased with the amount of fluoride ions. The synthesized fluorapatite nanomaterials are promising as materials in environmental protection and medicine for orthopedics and dental restorations.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences",
journal = "Nuclear Technology & Radiation Protection",
title = "Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions",
volume = "33",
number = "2",
pages = "180-187",
doi = "10.2298/NTRP1802180S"
}
Stanić, V. Dj., Adnađević, B. K., Dimitrijević, S. I., Dimović, S., Mitrić, M., Zmejkovski, B.,& Smiljanić, S.. (2018). Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions. in Nuclear Technology & Radiation Protection
Belgrade : Vinča Institute of Nuclear Sciences., 33(2), 180-187.
https://doi.org/10.2298/NTRP1802180S
Stanić VD, Adnađević BK, Dimitrijević SI, Dimović S, Mitrić M, Zmejkovski B, Smiljanić S. Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions. in Nuclear Technology & Radiation Protection. 2018;33(2):180-187.
doi:10.2298/NTRP1802180S .
Stanić, Vojislav Dj., Adnađević, Borivoj K., Dimitrijević, Suzana I., Dimović, Slavko, Mitrić, Miodrag, Zmejkovski, Bojana, Smiljanić, Slavko, "Synthesis of fluorapatite nanopowders by a surfactant-assisted microwave method under isothermal conditions" in Nuclear Technology & Radiation Protection, 33, no. 2 (2018):180-187,
https://doi.org/10.2298/NTRP1802180S . .
1
1
2

Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites

Radoicic, Marija; Ciric-Marjanovic, Gordana; Spasojevic, Vuk; Ahrenkiel, Scott Phillip; Mitrić, Miodrag; Novaković, Tatjana; Šaponjić, Zoran

(Elsevier, 2017)

TY  - JOUR
AU  - Radoicic, Marija
AU  - Ciric-Marjanovic, Gordana
AU  - Spasojevic, Vuk
AU  - Ahrenkiel, Scott Phillip
AU  - Mitrić, Miodrag
AU  - Novaković, Tatjana
AU  - Šaponjić, Zoran
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2238
AB  - A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites
VL  - 213
SP  - 155
EP  - 166
DO  - 10.1016/j.apcatb.2017.05.023
ER  - 
@article{
author = "Radoicic, Marija and Ciric-Marjanovic, Gordana and Spasojevic, Vuk and Ahrenkiel, Scott Phillip and Mitrić, Miodrag and Novaković, Tatjana and Šaponjić, Zoran",
year = "2017",
abstract = "A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites",
volume = "213",
pages = "155-166",
doi = "10.1016/j.apcatb.2017.05.023"
}
Radoicic, M., Ciric-Marjanovic, G., Spasojevic, V., Ahrenkiel, S. P., Mitrić, M., Novaković, T.,& Šaponjić, Z.. (2017). Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental
Elsevier., 213, 155-166.
https://doi.org/10.1016/j.apcatb.2017.05.023
Radoicic M, Ciric-Marjanovic G, Spasojevic V, Ahrenkiel SP, Mitrić M, Novaković T, Šaponjić Z. Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental. 2017;213:155-166.
doi:10.1016/j.apcatb.2017.05.023 .
Radoicic, Marija, Ciric-Marjanovic, Gordana, Spasojevic, Vuk, Ahrenkiel, Scott Phillip, Mitrić, Miodrag, Novaković, Tatjana, Šaponjić, Zoran, "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites" in Applied Catalysis B-Environmental, 213 (2017):155-166,
https://doi.org/10.1016/j.apcatb.2017.05.023 . .
64
35
61

Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites

Radoicic, Marija; Ciric-Marjanovic, Gordana; Spasojevic, Vuk; Ahrenkiel, Scott Phillip; Mitrić, Miodrag; Novaković, Tatjana; Šaponjić, Zoran

(Elsevier, 2017)

TY  - JOUR
AU  - Radoicic, Marija
AU  - Ciric-Marjanovic, Gordana
AU  - Spasojevic, Vuk
AU  - Ahrenkiel, Scott Phillip
AU  - Mitrić, Miodrag
AU  - Novaković, Tatjana
AU  - Šaponjić, Zoran
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3018
AB  - A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.
PB  - Elsevier
T2  - Applied Catalysis B-Environmental
T1  - Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites
VL  - 213
SP  - 155
EP  - 166
DO  - 10.1016/j.apcatb.2017.05.023
ER  - 
@article{
author = "Radoicic, Marija and Ciric-Marjanovic, Gordana and Spasojevic, Vuk and Ahrenkiel, Scott Phillip and Mitrić, Miodrag and Novaković, Tatjana and Šaponjić, Zoran",
year = "2017",
abstract = "A simple bottom-up method for the preparation of novel and very efficient photocatalytic nanocomposite system based on carbonized form of polyaniline (PANI) and colloidal TiO2 nanocrystals has been developed. The carbonized PANI/TiO2 nanocomposites were synthesized in a two-step procedure. Firstly, non-carbonized PANI/TiO2 nanocomposites were synthesized by the chemical oxidative polymerization of aniline (ANI) with ammonium peroxydisulfate, in the presence of colloidal TiO2 nanoparticles (TiO2 NPs) (d 4.5 nm). Initial [TiO2 NANI] mole ratios were 20, 50, and 80. In the second step, following the polymerization process, the carbonization of PANI/TiO2 nanocomposites was performed by thermal treatment in an inert atmosphere at 650 degrees C. The morphological and structural properties of the carbonized nanocomposites were studied using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and Raman spectroscopy. The accomplishment of complete carbonization of PANI in PANI/TiO2 nanocomposites was confirmed by Raman spectroscopy. The appearance of anatase and rutile crystal forms in TiO2 NPs upon carbonization, with mass ratio depending on the initial molar ratio of ANI and TiO2 NPs was revealed by XRD measurements, TEM, SEM and Raman spectroscopy. The photocatalytic activities of carbonized PANI/TiO2 nanocomposites were evaluated following the photocatalytic degradation processes of Rhodamine B and Methylene blue. Carbonized PANI/TiO2 nanocomposites showed higher photocatalytic efficacy compared to bare TiO2 NPs and non-carbonized PANI/TiO2 nanocomposites. The porosity and surface structure of carbonized PANI/TiO2 nanocomposites, as well as crystalline structure of TiO2, affect photocatalytic activity of nanocomposites.",
publisher = "Elsevier",
journal = "Applied Catalysis B-Environmental",
title = "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites",
volume = "213",
pages = "155-166",
doi = "10.1016/j.apcatb.2017.05.023"
}
Radoicic, M., Ciric-Marjanovic, G., Spasojevic, V., Ahrenkiel, S. P., Mitrić, M., Novaković, T.,& Šaponjić, Z.. (2017). Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental
Elsevier., 213, 155-166.
https://doi.org/10.1016/j.apcatb.2017.05.023
Radoicic M, Ciric-Marjanovic G, Spasojevic V, Ahrenkiel SP, Mitrić M, Novaković T, Šaponjić Z. Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites. in Applied Catalysis B-Environmental. 2017;213:155-166.
doi:10.1016/j.apcatb.2017.05.023 .
Radoicic, Marija, Ciric-Marjanovic, Gordana, Spasojevic, Vuk, Ahrenkiel, Scott Phillip, Mitrić, Miodrag, Novaković, Tatjana, Šaponjić, Zoran, "Superior photocatalytic properties of carbonized PANI/TiO2 nanocomposites" in Applied Catalysis B-Environmental, 213 (2017):155-166,
https://doi.org/10.1016/j.apcatb.2017.05.023 . .
64
35
62

Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity

Dolic, Maja B.; Rajakovic-Ognjanovic, Vladana N.; Štrbac, Svetlana; Dimitrijević, Suzana I.; Mitrić, Miodrag; Onjia, Antonije E.; Rajaković, Ljubinka V.

(Elsevier, 2017)

TY  - JOUR
AU  - Dolic, Maja B.
AU  - Rajakovic-Ognjanovic, Vladana N.
AU  - Štrbac, Svetlana
AU  - Dimitrijević, Suzana I.
AU  - Mitrić, Miodrag
AU  - Onjia, Antonije E.
AU  - Rajaković, Ljubinka V.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3030
AB  - The objective of this study was to investigate the modification of materials used in wastewater treatment for possible antimicrobial application(s). Granulated activated carbon (GAC) and natural clinoptilolite (CLI) were activated using Cu2+-and Zn2+-ions and the disinfection ability of the resulting materials was tested. Studies of the sorption and desorption kinetics were performed in order to determine and clarify the antimicrobial activity of the metal-activated sorbents. The exact sorption capacities of the selected sorbents, GAC and CLI, activated through use of Cu2+-ions, were 15.90 and 3.60 mg/g, respectively, while for the materials activated by Zn2+-ions, the corresponding capacities were 14.00 and 4.72 mg/g,. The desorption rates were 2 and 3 orders of magnitude lower than their sorption efficacy for the Cu2+-, and Zn2+-activated sorbents, respectively. The intermediate sorption capacity and low desorption rate indicated that the overall antimicrobial activity of the metal-modified sorbents was a result of metal ions immobilized onto surface sites. The effect of antimicrobial activity of free ions desorbed from the metal-activated surface may thus be disregarded. The antimicrobial activities of Cu/GAC, Zn/GAC, Cu/CLI and Zn/ CLI were also tested against Escherichia coli, Staphylococcus aureus, and Candida albicans. After 15 min exposure, the highest levels of cell inactivation were obtained through the Cu/CLI and the Cu/GAC against E. coli, 100.0 and 98.24%, respectively. However, for S. aureus and yeast cell inactivation, all Cu2+-and Zn2+-activated sorbents proved to be unsatisfactory. A characterization of the sorbents was performed by Xray diffraction (XRD), X-ray photo electron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). A concentration of the adsorbed and released ions was determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS). The results showed that the antimicrobial performance of the activated sorbents depended on the surface characteristics of the material, which itself designates the distribution and the bioavailability of the activating agent.
PB  - Elsevier
T2  - New Biotechnology
T1  - Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity
VL  - 39
SP  - 150
EP  - 159
DO  - 10.1016/j.nbt.2017.03.001
ER  - 
@article{
author = "Dolic, Maja B. and Rajakovic-Ognjanovic, Vladana N. and Štrbac, Svetlana and Dimitrijević, Suzana I. and Mitrić, Miodrag and Onjia, Antonije E. and Rajaković, Ljubinka V.",
year = "2017",
abstract = "The objective of this study was to investigate the modification of materials used in wastewater treatment for possible antimicrobial application(s). Granulated activated carbon (GAC) and natural clinoptilolite (CLI) were activated using Cu2+-and Zn2+-ions and the disinfection ability of the resulting materials was tested. Studies of the sorption and desorption kinetics were performed in order to determine and clarify the antimicrobial activity of the metal-activated sorbents. The exact sorption capacities of the selected sorbents, GAC and CLI, activated through use of Cu2+-ions, were 15.90 and 3.60 mg/g, respectively, while for the materials activated by Zn2+-ions, the corresponding capacities were 14.00 and 4.72 mg/g,. The desorption rates were 2 and 3 orders of magnitude lower than their sorption efficacy for the Cu2+-, and Zn2+-activated sorbents, respectively. The intermediate sorption capacity and low desorption rate indicated that the overall antimicrobial activity of the metal-modified sorbents was a result of metal ions immobilized onto surface sites. The effect of antimicrobial activity of free ions desorbed from the metal-activated surface may thus be disregarded. The antimicrobial activities of Cu/GAC, Zn/GAC, Cu/CLI and Zn/ CLI were also tested against Escherichia coli, Staphylococcus aureus, and Candida albicans. After 15 min exposure, the highest levels of cell inactivation were obtained through the Cu/CLI and the Cu/GAC against E. coli, 100.0 and 98.24%, respectively. However, for S. aureus and yeast cell inactivation, all Cu2+-and Zn2+-activated sorbents proved to be unsatisfactory. A characterization of the sorbents was performed by Xray diffraction (XRD), X-ray photo electron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). A concentration of the adsorbed and released ions was determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS). The results showed that the antimicrobial performance of the activated sorbents depended on the surface characteristics of the material, which itself designates the distribution and the bioavailability of the activating agent.",
publisher = "Elsevier",
journal = "New Biotechnology",
title = "Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity",
volume = "39",
pages = "150-159",
doi = "10.1016/j.nbt.2017.03.001"
}
Dolic, M. B., Rajakovic-Ognjanovic, V. N., Štrbac, S., Dimitrijević, S. I., Mitrić, M., Onjia, A. E.,& Rajaković, L. V.. (2017). Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity. in New Biotechnology
Elsevier., 39, 150-159.
https://doi.org/10.1016/j.nbt.2017.03.001
Dolic MB, Rajakovic-Ognjanovic VN, Štrbac S, Dimitrijević SI, Mitrić M, Onjia AE, Rajaković LV. Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity. in New Biotechnology. 2017;39:150-159.
doi:10.1016/j.nbt.2017.03.001 .
Dolic, Maja B., Rajakovic-Ognjanovic, Vladana N., Štrbac, Svetlana, Dimitrijević, Suzana I., Mitrić, Miodrag, Onjia, Antonije E., Rajaković, Ljubinka V., "Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity" in New Biotechnology, 39 (2017):150-159,
https://doi.org/10.1016/j.nbt.2017.03.001 . .
17
7
18

Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity

Dolic, Maja B.; Rajakovic-Ognjanovic, Vladana N.; Štrbac, Svetlana; Dimitrijević, Suzana I.; Mitrić, Miodrag; Onjia, Antonije E.; Rajaković, Ljubinka V.

(Elsevier, 2017)

TY  - JOUR
AU  - Dolic, Maja B.
AU  - Rajakovic-Ognjanovic, Vladana N.
AU  - Štrbac, Svetlana
AU  - Dimitrijević, Suzana I.
AU  - Mitrić, Miodrag
AU  - Onjia, Antonije E.
AU  - Rajaković, Ljubinka V.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2158
AB  - The objective of this study was to investigate the modification of materials used in wastewater treatment for possible antimicrobial application(s). Granulated activated carbon (GAC) and natural clinoptilolite (CLI) were activated using Cu2+-and Zn2+-ions and the disinfection ability of the resulting materials was tested. Studies of the sorption and desorption kinetics were performed in order to determine and clarify the antimicrobial activity of the metal-activated sorbents. The exact sorption capacities of the selected sorbents, GAC and CLI, activated through use of Cu2+-ions, were 15.90 and 3.60 mg/g, respectively, while for the materials activated by Zn2+-ions, the corresponding capacities were 14.00 and 4.72 mg/g,. The desorption rates were 2 and 3 orders of magnitude lower than their sorption efficacy for the Cu2+-, and Zn2+-activated sorbents, respectively. The intermediate sorption capacity and low desorption rate indicated that the overall antimicrobial activity of the metal-modified sorbents was a result of metal ions immobilized onto surface sites. The effect of antimicrobial activity of free ions desorbed from the metal-activated surface may thus be disregarded. The antimicrobial activities of Cu/GAC, Zn/GAC, Cu/CLI and Zn/ CLI were also tested against Escherichia coli, Staphylococcus aureus, and Candida albicans. After 15 min exposure, the highest levels of cell inactivation were obtained through the Cu/CLI and the Cu/GAC against E. coli, 100.0 and 98.24%, respectively. However, for S. aureus and yeast cell inactivation, all Cu2+-and Zn2+-activated sorbents proved to be unsatisfactory. A characterization of the sorbents was performed by Xray diffraction (XRD), X-ray photo electron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). A concentration of the adsorbed and released ions was determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS). The results showed that the antimicrobial performance of the activated sorbents depended on the surface characteristics of the material, which itself designates the distribution and the bioavailability of the activating agent.
PB  - Elsevier
T2  - New Biotechnology
T1  - Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity
VL  - 39
SP  - 150
EP  - 159
DO  - 10.1016/j.nbt.2017.03.001
ER  - 
@article{
author = "Dolic, Maja B. and Rajakovic-Ognjanovic, Vladana N. and Štrbac, Svetlana and Dimitrijević, Suzana I. and Mitrić, Miodrag and Onjia, Antonije E. and Rajaković, Ljubinka V.",
year = "2017",
abstract = "The objective of this study was to investigate the modification of materials used in wastewater treatment for possible antimicrobial application(s). Granulated activated carbon (GAC) and natural clinoptilolite (CLI) were activated using Cu2+-and Zn2+-ions and the disinfection ability of the resulting materials was tested. Studies of the sorption and desorption kinetics were performed in order to determine and clarify the antimicrobial activity of the metal-activated sorbents. The exact sorption capacities of the selected sorbents, GAC and CLI, activated through use of Cu2+-ions, were 15.90 and 3.60 mg/g, respectively, while for the materials activated by Zn2+-ions, the corresponding capacities were 14.00 and 4.72 mg/g,. The desorption rates were 2 and 3 orders of magnitude lower than their sorption efficacy for the Cu2+-, and Zn2+-activated sorbents, respectively. The intermediate sorption capacity and low desorption rate indicated that the overall antimicrobial activity of the metal-modified sorbents was a result of metal ions immobilized onto surface sites. The effect of antimicrobial activity of free ions desorbed from the metal-activated surface may thus be disregarded. The antimicrobial activities of Cu/GAC, Zn/GAC, Cu/CLI and Zn/ CLI were also tested against Escherichia coli, Staphylococcus aureus, and Candida albicans. After 15 min exposure, the highest levels of cell inactivation were obtained through the Cu/CLI and the Cu/GAC against E. coli, 100.0 and 98.24%, respectively. However, for S. aureus and yeast cell inactivation, all Cu2+-and Zn2+-activated sorbents proved to be unsatisfactory. A characterization of the sorbents was performed by Xray diffraction (XRD), X-ray photo electron spectroscopy (XPS), and field emission scanning electron microscopy (FE-SEM). A concentration of the adsorbed and released ions was determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES) and mass spectrometry (ICP-MS). The results showed that the antimicrobial performance of the activated sorbents depended on the surface characteristics of the material, which itself designates the distribution and the bioavailability of the activating agent.",
publisher = "Elsevier",
journal = "New Biotechnology",
title = "Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity",
volume = "39",
pages = "150-159",
doi = "10.1016/j.nbt.2017.03.001"
}
Dolic, M. B., Rajakovic-Ognjanovic, V. N., Štrbac, S., Dimitrijević, S. I., Mitrić, M., Onjia, A. E.,& Rajaković, L. V.. (2017). Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity. in New Biotechnology
Elsevier., 39, 150-159.
https://doi.org/10.1016/j.nbt.2017.03.001
Dolic MB, Rajakovic-Ognjanovic VN, Štrbac S, Dimitrijević SI, Mitrić M, Onjia AE, Rajaković LV. Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity. in New Biotechnology. 2017;39:150-159.
doi:10.1016/j.nbt.2017.03.001 .
Dolic, Maja B., Rajakovic-Ognjanovic, Vladana N., Štrbac, Svetlana, Dimitrijević, Suzana I., Mitrić, Miodrag, Onjia, Antonije E., Rajaković, Ljubinka V., "Natural sorbents modified by divalent Cu2+- and Zn2+- ions and their corresponding antimicrobial activity" in New Biotechnology, 39 (2017):150-159,
https://doi.org/10.1016/j.nbt.2017.03.001 . .
17
7
17

Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization

Brkovic, Danijela V.; Pavlović, Vladimir B.; Pavlović, Vera P.; Obradovic, Nina; Mitrić, Miodrag; Stevanović, Sanja; Vlahovic, Branislav; Uskoković, Petar S.; Marinković, Aleksandar D.

(Wiley, Hoboken, 2017)

TY  - JOUR
AU  - Brkovic, Danijela V.
AU  - Pavlović, Vladimir B.
AU  - Pavlović, Vera P.
AU  - Obradovic, Nina
AU  - Mitrić, Miodrag
AU  - Stevanović, Sanja
AU  - Vlahovic, Branislav
AU  - Uskoković, Petar S.
AU  - Marinković, Aleksandar D.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/2152
AB  - The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60 degrees C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30 degrees C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37 degrees C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.
PB  - Wiley, Hoboken
T2  - Polymer Composites
T1  - Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization
VL  - 38
DO  - 10.1002/pc.23996
ER  - 
@article{
author = "Brkovic, Danijela V. and Pavlović, Vladimir B. and Pavlović, Vera P. and Obradovic, Nina and Mitrić, Miodrag and Stevanović, Sanja and Vlahovic, Branislav and Uskoković, Petar S. and Marinković, Aleksandar D.",
year = "2017",
abstract = "The structural characteristics of polymer nanocomposites with functionalized multiwall carbon nanotubes (MWCNTs) in poly(methyl methacrylate) matrix have been studied in relation to nanofiller loading and surface functionality. Different functional groups have been covalently attached on the MWCNTs sidewalls in order to induce interfacial interactions at nanofiller/polymer interface, which resulted in an improved nanomechanical features. Structural properties of nanocomposites, studied with XRD and Raman analysis, indicated the most pronounced decrease in a degree of amorphousness for samples containing 0.5 and 1 wt% of MWCNTs functionalized with dapsone (dapson-MWCNT) and diethyl malonate (dem-MWCNT). SEM and TEM micrographs confirmed improved dispersibility of the MWCNTs modified with aromatic structure of dapsone inside PMMA matrix. A significant increase in a glass transition temperature of over 60 degrees C has been found for the 1 wt% dapson-MWCNT nanocomposite. Additional modification of dapson-MWCNT by further increasing aromaticity and voluminosity of attached moiety (fid-MWCNT), showed 30 degrees C increases in a glass transition temperature at 4 wt% of nanofiller loading, which is similar to shift of 37 degrees C with loading of MWCNTs modified with ester terminal group. A maximum increase of 56% of reduced modulus and 86% of hardness was obtained for 1 wt% loading of dapson-MWCNT nanofiller.",
publisher = "Wiley, Hoboken",
journal = "Polymer Composites",
title = "Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization",
volume = "38",
doi = "10.1002/pc.23996"
}
Brkovic, D. V., Pavlović, V. B., Pavlović, V. P., Obradovic, N., Mitrić, M., Stevanović, S., Vlahovic, B., Uskoković, P. S.,& Marinković, A. D.. (2017). Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization. in Polymer Composites
Wiley, Hoboken., 38.
https://doi.org/10.1002/pc.23996
Brkovic DV, Pavlović VB, Pavlović VP, Obradovic N, Mitrić M, Stevanović S, Vlahovic B, Uskoković PS, Marinković AD. Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization. in Polymer Composites. 2017;38.
doi:10.1002/pc.23996 .
Brkovic, Danijela V., Pavlović, Vladimir B., Pavlović, Vera P., Obradovic, Nina, Mitrić, Miodrag, Stevanović, Sanja, Vlahovic, Branislav, Uskoković, Petar S., Marinković, Aleksandar D., "Structural Properties of the Multiwall Carbon Nanotubes/Poly(Methyl Methacrylate) Nanocomposites: Effect of the Multiwall Carbon Nanotubes Covalent Functionalization" in Polymer Composites, 38 (2017),
https://doi.org/10.1002/pc.23996 . .
11
6
11

Structural investigation of mechanically activated ZnO powder

Peleš, Adriana; Pavlović, Vera P.; Filipović, Suzana; Obradovic, Nina; Mančić, Lidija; Krstić, Jugoslav; Mitrić, Miodrag; Vlahović, Branislav; Rašić, Goran; Kosanović, Darko; Pavlović, Vladimir B.

(Elsevier, 2015)

TY  - JOUR
AU  - Peleš, Adriana
AU  - Pavlović, Vera P.
AU  - Filipović, Suzana
AU  - Obradovic, Nina
AU  - Mančić, Lidija
AU  - Krstić, Jugoslav
AU  - Mitrić, Miodrag
AU  - Vlahović, Branislav
AU  - Rašić, Goran
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3208
AB  - Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural investigation of mechanically activated ZnO powder
VL  - 648
SP  - 971
EP  - 979
DO  - 10.1016/j.jallcom.2015.06.247
ER  - 
@article{
author = "Peleš, Adriana and Pavlović, Vera P. and Filipović, Suzana and Obradovic, Nina and Mančić, Lidija and Krstić, Jugoslav and Mitrić, Miodrag and Vlahović, Branislav and Rašić, Goran and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2015",
abstract = "Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural investigation of mechanically activated ZnO powder",
volume = "648",
pages = "971-979",
doi = "10.1016/j.jallcom.2015.06.247"
}
Peleš, A., Pavlović, V. P., Filipović, S., Obradovic, N., Mančić, L., Krstić, J., Mitrić, M., Vlahović, B., Rašić, G., Kosanović, D.,& Pavlović, V. B.. (2015). Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds
Elsevier., 648, 971-979.
https://doi.org/10.1016/j.jallcom.2015.06.247
Peleš A, Pavlović VP, Filipović S, Obradovic N, Mančić L, Krstić J, Mitrić M, Vlahović B, Rašić G, Kosanović D, Pavlović VB. Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds. 2015;648:971-979.
doi:10.1016/j.jallcom.2015.06.247 .
Peleš, Adriana, Pavlović, Vera P., Filipović, Suzana, Obradovic, Nina, Mančić, Lidija, Krstić, Jugoslav, Mitrić, Miodrag, Vlahović, Branislav, Rašić, Goran, Kosanović, Darko, Pavlović, Vladimir B., "Structural investigation of mechanically activated ZnO powder" in Journal of Alloys and Compounds, 648 (2015):971-979,
https://doi.org/10.1016/j.jallcom.2015.06.247 . .
12
10
14

Structural investigation of mechanically activated ZnO powder

Peleš, Adriana; Pavlović, Vera P.; Filipović, Suzana; Obradovic, Nina; Mančić, Lidija; Krstić, Jugoslav; Mitrić, Miodrag; Vlahović, Branislav; Rašić, Goran; Kosanović, Darko; Pavlović, Vladimir B.

(Elsevier, 2015)

TY  - JOUR
AU  - Peleš, Adriana
AU  - Pavlović, Vera P.
AU  - Filipović, Suzana
AU  - Obradovic, Nina
AU  - Mančić, Lidija
AU  - Krstić, Jugoslav
AU  - Mitrić, Miodrag
AU  - Vlahović, Branislav
AU  - Rašić, Goran
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir B.
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1715
AB  - Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.
PB  - Elsevier
T2  - Journal of Alloys and Compounds
T1  - Structural investigation of mechanically activated ZnO powder
VL  - 648
SP  - 971
EP  - 979
DO  - 10.1016/j.jallcom.2015.06.247
ER  - 
@article{
author = "Peleš, Adriana and Pavlović, Vera P. and Filipović, Suzana and Obradovic, Nina and Mančić, Lidija and Krstić, Jugoslav and Mitrić, Miodrag and Vlahović, Branislav and Rašić, Goran and Kosanović, Darko and Pavlović, Vladimir B.",
year = "2015",
abstract = "Commercially available ZnO powder was mechanically activated in a planetary ball mill. In order to investigate the specific surface area, pore volume and microstructure of non-activated and mechanically activated ZnO powders the authors performed N-2 physisorption, SEM and TEM. Crystallite size and lattice microstrain were analyzed by X-ray diffraction method. XRD patterns indicate that peak intensities are getting lower and expend with activation time. The reduction in crystallite size and increasing of lattice microstrain with prolonged milling time were determined applying the Rietveld's method. The difference between non-activated and the activated powder has been also observed by X-ray photoelectron spectroscopy (XPS). XPS is used for investigating the chemical bonding of ZnO powder by analyzing the energy of photoelectrons. The lattice vibration spectra were obtained using Raman spectroscopy. In Raman spectra some changes along with atypical resonant scattering were noticed, which were caused by mechanical activation.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Structural investigation of mechanically activated ZnO powder",
volume = "648",
pages = "971-979",
doi = "10.1016/j.jallcom.2015.06.247"
}
Peleš, A., Pavlović, V. P., Filipović, S., Obradovic, N., Mančić, L., Krstić, J., Mitrić, M., Vlahović, B., Rašić, G., Kosanović, D.,& Pavlović, V. B.. (2015). Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds
Elsevier., 648, 971-979.
https://doi.org/10.1016/j.jallcom.2015.06.247
Peleš A, Pavlović VP, Filipović S, Obradovic N, Mančić L, Krstić J, Mitrić M, Vlahović B, Rašić G, Kosanović D, Pavlović VB. Structural investigation of mechanically activated ZnO powder. in Journal of Alloys and Compounds. 2015;648:971-979.
doi:10.1016/j.jallcom.2015.06.247 .
Peleš, Adriana, Pavlović, Vera P., Filipović, Suzana, Obradovic, Nina, Mančić, Lidija, Krstić, Jugoslav, Mitrić, Miodrag, Vlahović, Branislav, Rašić, Goran, Kosanović, Darko, Pavlović, Vladimir B., "Structural investigation of mechanically activated ZnO powder" in Journal of Alloys and Compounds, 648 (2015):971-979,
https://doi.org/10.1016/j.jallcom.2015.06.247 . .
12
10
14

Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design

Novaković, Tatjana; Rožić, Ljiljana; Petrović, Srđan; Vuković, Zorica; Mitrić, Miodrag

(Serbian Chemical Society, 2015)

TY  - JOUR
AU  - Novaković, Tatjana
AU  - Rožić, Ljiljana
AU  - Petrović, Srđan
AU  - Vuković, Zorica
AU  - Mitrić, Miodrag
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1799
AB  - A statistical design was used to investigate the effect of various processing conditions on the structure of sol-gel derived Mg(II) doped alumina. Six process variables were selected based on the Plackett-Burman design: concentration of magnesium nitrate, time and temperature of alcohol evaporation, temperature and time of annealing and heating rate were changed at two levels. For every set of conditions, samples with different specific surface area and degree of crystallinity were obtained. Analysis of the results showed that the annealing temperature, heating rate and concentration of magnesium nitrate were the main factors affecting the average crystallite size of the predominant alumina phase. In the case of the specific surface area, two of selected six variables had pronounced effects; however, the temperature of annealing was more effective than others. The present results showed that the proposed model that uses crystallite size as a response variable is preferable to other research.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design
VL  - 80
IS  - 12
SP  - 1529
EP  - 1540
DO  - 10.2298/JSC141113056N
ER  - 
@article{
author = "Novaković, Tatjana and Rožić, Ljiljana and Petrović, Srđan and Vuković, Zorica and Mitrić, Miodrag",
year = "2015",
abstract = "A statistical design was used to investigate the effect of various processing conditions on the structure of sol-gel derived Mg(II) doped alumina. Six process variables were selected based on the Plackett-Burman design: concentration of magnesium nitrate, time and temperature of alcohol evaporation, temperature and time of annealing and heating rate were changed at two levels. For every set of conditions, samples with different specific surface area and degree of crystallinity were obtained. Analysis of the results showed that the annealing temperature, heating rate and concentration of magnesium nitrate were the main factors affecting the average crystallite size of the predominant alumina phase. In the case of the specific surface area, two of selected six variables had pronounced effects; however, the temperature of annealing was more effective than others. The present results showed that the proposed model that uses crystallite size as a response variable is preferable to other research.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design",
volume = "80",
number = "12",
pages = "1529-1540",
doi = "10.2298/JSC141113056N"
}
Novaković, T., Rožić, L., Petrović, S., Vuković, Z.,& Mitrić, M.. (2015). Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 80(12), 1529-1540.
https://doi.org/10.2298/JSC141113056N
Novaković T, Rožić L, Petrović S, Vuković Z, Mitrić M. Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design. in Journal of the Serbian Chemical Society. 2015;80(12):1529-1540.
doi:10.2298/JSC141113056N .
Novaković, Tatjana, Rožić, Ljiljana, Petrović, Srđan, Vuković, Zorica, Mitrić, Miodrag, "Study of the effect of Mg(II) addition and the annealing conditions on the structure of mesoporous aluminum oxide using Plackett-Burman design" in Journal of the Serbian Chemical Society, 80, no. 12 (2015):1529-1540,
https://doi.org/10.2298/JSC141113056N . .
3
3
2

Evaluation of the effects of treatment factors on the properties of bio-apatite materials

Sljivic-Ivanovic, M; Smiciklas, I; Milenkovic, A; Dojčinović, Biljana; Babić, Biljana M.; Mitrić, Miodrag

(Springer, New York, 2015)

TY  - JOUR
AU  - Sljivic-Ivanovic, M
AU  - Smiciklas, I
AU  - Milenkovic, A
AU  - Dojčinović, Biljana
AU  - Babić, Biljana M.
AU  - Mitrić, Miodrag
PY  - 2015
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1741
AB  - Animal bones have been studied as a resource of low-crystalline apatite for immobilization of toxic heavy metals. Chemical and thermal treatments can be applied for selective removal of bone organic constituents. In this study, the impact of different treatment factors was determined by experimental design methodology, and comparison of the estimated effects was performed in order to optimize the treatment conditions. Fractional factorial design with five variables at two levels was applied for factors screening. The type of chemical reagent (H2O2 or NaOH), its concentration (0.1 or 2 mol/L), reaction temperature (20 or 60 degrees C), contact time (1 or 3 h) and sample annealing (without or at 400 degrees C) were considered as process variables. Structural properties of bone sorbents, loss of ignition, point of zero charge, surface functional groups, specific surface area, chemical composition, and Cd2+ sorption efficiency, were selected as system responses. Samples significantly differed in respect to the organic phase content and composition, thus mechanisms of Cd2+ sorption were complex. Statistical analysis has revealed that, between all studied factors, temperature treatment was the most important for sorbents increased specific surface area, porosity and cation sorption. Furthermore, NaOH was more effective than H2O2, while the effects produced by variation of other factors were less pronounced. The highest proportion of bio-apatite with desired low crystallinity and high specific surface area was achieved by synergetic effects of chemical treatment with NaOH and thermal treatment at 400 degrees C.
PB  - Springer, New York
T2  - Journal of Materials Science
T1  - Evaluation of the effects of treatment factors on the properties of bio-apatite materials
VL  - 50
IS  - 1
SP  - 354
EP  - 365
DO  - 10.1007/s10853-014-8594-4
ER  - 
@article{
author = "Sljivic-Ivanovic, M and Smiciklas, I and Milenkovic, A and Dojčinović, Biljana and Babić, Biljana M. and Mitrić, Miodrag",
year = "2015",
abstract = "Animal bones have been studied as a resource of low-crystalline apatite for immobilization of toxic heavy metals. Chemical and thermal treatments can be applied for selective removal of bone organic constituents. In this study, the impact of different treatment factors was determined by experimental design methodology, and comparison of the estimated effects was performed in order to optimize the treatment conditions. Fractional factorial design with five variables at two levels was applied for factors screening. The type of chemical reagent (H2O2 or NaOH), its concentration (0.1 or 2 mol/L), reaction temperature (20 or 60 degrees C), contact time (1 or 3 h) and sample annealing (without or at 400 degrees C) were considered as process variables. Structural properties of bone sorbents, loss of ignition, point of zero charge, surface functional groups, specific surface area, chemical composition, and Cd2+ sorption efficiency, were selected as system responses. Samples significantly differed in respect to the organic phase content and composition, thus mechanisms of Cd2+ sorption were complex. Statistical analysis has revealed that, between all studied factors, temperature treatment was the most important for sorbents increased specific surface area, porosity and cation sorption. Furthermore, NaOH was more effective than H2O2, while the effects produced by variation of other factors were less pronounced. The highest proportion of bio-apatite with desired low crystallinity and high specific surface area was achieved by synergetic effects of chemical treatment with NaOH and thermal treatment at 400 degrees C.",
publisher = "Springer, New York",
journal = "Journal of Materials Science",
title = "Evaluation of the effects of treatment factors on the properties of bio-apatite materials",
volume = "50",
number = "1",
pages = "354-365",
doi = "10.1007/s10853-014-8594-4"
}
Sljivic-Ivanovic, M., Smiciklas, I., Milenkovic, A., Dojčinović, B., Babić, B. M.,& Mitrić, M.. (2015). Evaluation of the effects of treatment factors on the properties of bio-apatite materials. in Journal of Materials Science
Springer, New York., 50(1), 354-365.
https://doi.org/10.1007/s10853-014-8594-4
Sljivic-Ivanovic M, Smiciklas I, Milenkovic A, Dojčinović B, Babić BM, Mitrić M. Evaluation of the effects of treatment factors on the properties of bio-apatite materials. in Journal of Materials Science. 2015;50(1):354-365.
doi:10.1007/s10853-014-8594-4 .
Sljivic-Ivanovic, M, Smiciklas, I, Milenkovic, A, Dojčinović, Biljana, Babić, Biljana M., Mitrić, Miodrag, "Evaluation of the effects of treatment factors on the properties of bio-apatite materials" in Journal of Materials Science, 50, no. 1 (2015):354-365,
https://doi.org/10.1007/s10853-014-8594-4 . .
10
10
12

Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites

Vodnik, Vesna; Šaponjić, Zoran; Džunuzović, Jasna; Bogdanovic, Una; Mitrić, Miodrag; Nedeljković, Jovan M.

(Oxford : Pergamon-Elsevier Science Ltd, 2013)

TY  - JOUR
AU  - Vodnik, Vesna
AU  - Šaponjić, Zoran
AU  - Džunuzović, Jasna
AU  - Bogdanovic, Una
AU  - Mitrić, Miodrag
AU  - Nedeljković, Jovan M.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1316
AB  - Prismatic and plate-like silver nanoparticles (Ag NPs) were synthesized according to the seed-mediated method. These particles were used as precursors for preparation of homogenous, transparent and colored Ag/poly(vinyl alcohol) (PVA) nanocomposite films with different concentrations of Ag by solution-casting technique. Optical and structural characterization of these nanocomposites includes UV-visible spectroscopy, X-ray diffraction (XRD), FTIR spectroscopy and SEM measurements. Further, the effect of embedded nanoparticles on the thermal properties of the PVA matrix was studied. The value of the glass transition temperature of polymer is found to increase after embedding Ag NPs. Comparison of thermal properties of pure PVA and nanocomposite films showed that the thermo-oxidative stability of polymer slightly increased in the presence of Ag NPs. Furthermore, the effect of the Ag NPs on the crystallinity of polymer was also observed.
PB  - Oxford : Pergamon-Elsevier Science Ltd
T2  - Materials Research Bulletin
T1  - Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites
VL  - 48
IS  - 1
SP  - 52
EP  - 57
DO  - 10.1016/j.materresbull.2012.09.059
ER  - 
@article{
author = "Vodnik, Vesna and Šaponjić, Zoran and Džunuzović, Jasna and Bogdanovic, Una and Mitrić, Miodrag and Nedeljković, Jovan M.",
year = "2013",
abstract = "Prismatic and plate-like silver nanoparticles (Ag NPs) were synthesized according to the seed-mediated method. These particles were used as precursors for preparation of homogenous, transparent and colored Ag/poly(vinyl alcohol) (PVA) nanocomposite films with different concentrations of Ag by solution-casting technique. Optical and structural characterization of these nanocomposites includes UV-visible spectroscopy, X-ray diffraction (XRD), FTIR spectroscopy and SEM measurements. Further, the effect of embedded nanoparticles on the thermal properties of the PVA matrix was studied. The value of the glass transition temperature of polymer is found to increase after embedding Ag NPs. Comparison of thermal properties of pure PVA and nanocomposite films showed that the thermo-oxidative stability of polymer slightly increased in the presence of Ag NPs. Furthermore, the effect of the Ag NPs on the crystallinity of polymer was also observed.",
publisher = "Oxford : Pergamon-Elsevier Science Ltd",
journal = "Materials Research Bulletin",
title = "Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites",
volume = "48",
number = "1",
pages = "52-57",
doi = "10.1016/j.materresbull.2012.09.059"
}
Vodnik, V., Šaponjić, Z., Džunuzović, J., Bogdanovic, U., Mitrić, M.,& Nedeljković, J. M.. (2013). Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites. in Materials Research Bulletin
Oxford : Pergamon-Elsevier Science Ltd., 48(1), 52-57.
https://doi.org/10.1016/j.materresbull.2012.09.059
Vodnik V, Šaponjić Z, Džunuzović J, Bogdanovic U, Mitrić M, Nedeljković JM. Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites. in Materials Research Bulletin. 2013;48(1):52-57.
doi:10.1016/j.materresbull.2012.09.059 .
Vodnik, Vesna, Šaponjić, Zoran, Džunuzović, Jasna, Bogdanovic, Una, Mitrić, Miodrag, Nedeljković, Jovan M., "Anisotropic silver nanoparticles as filler for the formation of hybrid nanocomposites" in Materials Research Bulletin, 48, no. 1 (2013):52-57,
https://doi.org/10.1016/j.materresbull.2012.09.059 . .
25
19
25

Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique

Popić, Jovan P.; Jegdić, Bore; Bajat, Jelena; Mitrić, Miodrag; Mišković-Stanković, Vesna

(Serbian Chemical Society, 2013)

TY  - JOUR
AU  - Popić, Jovan P.
AU  - Jegdić, Bore
AU  - Bajat, Jelena
AU  - Mitrić, Miodrag
AU  - Mišković-Stanković, Vesna
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1310
AB  - In this study, the effect of deposition time and concentration of NaNO2 in the phosphate bath on the surface morphology of iron-phosphate coatings on low carbon steel was investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The composition of ironphosphate coatings was determined using energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), while surface coverage was evaluated by the voltammetric anodic dissolution (VAD) technique in the borate solution. The addition of NaNO2 to the phosphate bath significantly increased the surface coverage since better packed crystals of smaller size, which favour the phosphate nucleation, were obtained. It was also shown that prolonged deposition time increased the surface coverage, coating roughness and crystal size in the lateral direction, altering also the crystal shape from large platelets non-uniformly distributed on the steel surface during the initial time to better packed laminated and needle-like structures during prolonged exposure.
AB  - U ovom radu je, primenom skenirajuće elektronske mikroskopije (SEM) i mikro- skopije međuatomskih sila (AFM), ispitivan uticaj vremena taloženja i koncentracije NaNO2 u rastvoru za fosfatiranje na morfologiju gvožđe-fosfatnih prevlaka na nisko-ugljeničnom čeliku. Sastav gvožđe–fosfatnih prevlaka je određen primenom energetske disperzione atomske analize (EDS) i difrakcijom H-zraka (XRD), dok je pokrivenost površine određivana anodnim rastvaranjem u boratnom rastvoru primenom linearne voltametrije (VAD). Pokazano je da dodatak NaNO2 u rastvoru za fosfatiranje značajno povećava pokrivenost površine čelika, jer se formiraju bolje pakovani kristali, manje veličine. Duže vreme taloženja takođe povećava pokrivenost površine, kao i hrapavost prevlake i širinu kristala. Oblik kristala se tokom dužeg vremena taloženja menja od kristala u obliku većih ploča neuniformno raspoređenih na površini čelika, ka bolje pakovanim laminarnim i igličastim kristalima.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique
T1  - Određivanje pokrivenosti površine čelika gvožđe-fosfatnim prevlakama anodnim rastvaranjem primenom linearne voltametrije
VL  - 78
IS  - 1
SP  - 101
EP  - 114
DO  - 10.2298/JSC120706096P
ER  - 
@article{
author = "Popić, Jovan P. and Jegdić, Bore and Bajat, Jelena and Mitrić, Miodrag and Mišković-Stanković, Vesna",
year = "2013",
abstract = "In this study, the effect of deposition time and concentration of NaNO2 in the phosphate bath on the surface morphology of iron-phosphate coatings on low carbon steel was investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The composition of ironphosphate coatings was determined using energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), while surface coverage was evaluated by the voltammetric anodic dissolution (VAD) technique in the borate solution. The addition of NaNO2 to the phosphate bath significantly increased the surface coverage since better packed crystals of smaller size, which favour the phosphate nucleation, were obtained. It was also shown that prolonged deposition time increased the surface coverage, coating roughness and crystal size in the lateral direction, altering also the crystal shape from large platelets non-uniformly distributed on the steel surface during the initial time to better packed laminated and needle-like structures during prolonged exposure., U ovom radu je, primenom skenirajuće elektronske mikroskopije (SEM) i mikro- skopije međuatomskih sila (AFM), ispitivan uticaj vremena taloženja i koncentracije NaNO2 u rastvoru za fosfatiranje na morfologiju gvožđe-fosfatnih prevlaka na nisko-ugljeničnom čeliku. Sastav gvožđe–fosfatnih prevlaka je određen primenom energetske disperzione atomske analize (EDS) i difrakcijom H-zraka (XRD), dok je pokrivenost površine određivana anodnim rastvaranjem u boratnom rastvoru primenom linearne voltametrije (VAD). Pokazano je da dodatak NaNO2 u rastvoru za fosfatiranje značajno povećava pokrivenost površine čelika, jer se formiraju bolje pakovani kristali, manje veličine. Duže vreme taloženja takođe povećava pokrivenost površine, kao i hrapavost prevlake i širinu kristala. Oblik kristala se tokom dužeg vremena taloženja menja od kristala u obliku većih ploča neuniformno raspoređenih na površini čelika, ka bolje pakovanim laminarnim i igličastim kristalima.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique, Određivanje pokrivenosti površine čelika gvožđe-fosfatnim prevlakama anodnim rastvaranjem primenom linearne voltametrije",
volume = "78",
number = "1",
pages = "101-114",
doi = "10.2298/JSC120706096P"
}
Popić, J. P., Jegdić, B., Bajat, J., Mitrić, M.,& Mišković-Stanković, V.. (2013). Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 78(1), 101-114.
https://doi.org/10.2298/JSC120706096P
Popić JP, Jegdić B, Bajat J, Mitrić M, Mišković-Stanković V. Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique. in Journal of the Serbian Chemical Society. 2013;78(1):101-114.
doi:10.2298/JSC120706096P .
Popić, Jovan P., Jegdić, Bore, Bajat, Jelena, Mitrić, Miodrag, Mišković-Stanković, Vesna, "Determination of surface coverage of iron-phosphate coatings on steel using the voltammetric anodic dissolution technique" in Journal of the Serbian Chemical Society, 78, no. 1 (2013):101-114,
https://doi.org/10.2298/JSC120706096P . .
8
3
5

The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline

Gavrilov, Nemanja; Pasti, Igor; Krstić, Jugoslav; Mitrić, Miodrag; Ciric-Marjanovic, Gordana; Mentus, Slavko

(Elsevier Sci Ltd, Oxford, 2013)

TY  - JOUR
AU  - Gavrilov, Nemanja
AU  - Pasti, Igor
AU  - Krstić, Jugoslav
AU  - Mitrić, Miodrag
AU  - Ciric-Marjanovic, Gordana
AU  - Mentus, Slavko
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1261
AB  - Single phase tungsten carbide nanoparticles (WC-NPs), (mean particle diameter 5.4 nm), distributed over carbonized polyaniline (C-PANT) nanotubes/nanosheets were synthesized by a solid state reaction between WO3 and nitrogen-rich carbonized polyaniline at 1000 degrees C in a reducing atmosphere. The resulting composite was characterized by X-ray diffractometry, electron microscopy, thermogravimetry in oxidizing and reduction atmospheres and elemental analysis. We suggested that the synthesis of WC as a single phase was facilitated by reactive C atoms with dangling bonds, formed upon nitrogen removal.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline
VL  - 39
IS  - 8
SP  - 8761
EP  - 8765
DO  - 10.1016/j.ceramint.2013.04.062
ER  - 
@article{
author = "Gavrilov, Nemanja and Pasti, Igor and Krstić, Jugoslav and Mitrić, Miodrag and Ciric-Marjanovic, Gordana and Mentus, Slavko",
year = "2013",
abstract = "Single phase tungsten carbide nanoparticles (WC-NPs), (mean particle diameter 5.4 nm), distributed over carbonized polyaniline (C-PANT) nanotubes/nanosheets were synthesized by a solid state reaction between WO3 and nitrogen-rich carbonized polyaniline at 1000 degrees C in a reducing atmosphere. The resulting composite was characterized by X-ray diffractometry, electron microscopy, thermogravimetry in oxidizing and reduction atmospheres and elemental analysis. We suggested that the synthesis of WC as a single phase was facilitated by reactive C atoms with dangling bonds, formed upon nitrogen removal.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline",
volume = "39",
number = "8",
pages = "8761-8765",
doi = "10.1016/j.ceramint.2013.04.062"
}
Gavrilov, N., Pasti, I., Krstić, J., Mitrić, M., Ciric-Marjanovic, G.,& Mentus, S.. (2013). The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline. in Ceramics International
Elsevier Sci Ltd, Oxford., 39(8), 8761-8765.
https://doi.org/10.1016/j.ceramint.2013.04.062
Gavrilov N, Pasti I, Krstić J, Mitrić M, Ciric-Marjanovic G, Mentus S. The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline. in Ceramics International. 2013;39(8):8761-8765.
doi:10.1016/j.ceramint.2013.04.062 .
Gavrilov, Nemanja, Pasti, Igor, Krstić, Jugoslav, Mitrić, Miodrag, Ciric-Marjanovic, Gordana, Mentus, Slavko, "The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline" in Ceramics International, 39, no. 8 (2013):8761-8765,
https://doi.org/10.1016/j.ceramint.2013.04.062 . .
9
10
11

Modification of high density polyethylene by gold implantation using different ion energies

Nenadović, Miloš; Potočnik, Jelena; Mitrić, Miodrag; Štrbac, Svetlana; Rakočević, Zlatko Lj.

(Elsevier Science Sa, Lausanne, 2013)

TY  - JOUR
AU  - Nenadović, Miloš
AU  - Potočnik, Jelena
AU  - Mitrić, Miodrag
AU  - Štrbac, Svetlana
AU  - Rakočević, Zlatko Lj.
PY  - 2013
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1262
AB  - High density polyethylene (HDPE) samples were modified by Au+ ion implantation at a dose of 5 x 10(15) ions cm(-2), using energies of 50, 100, 150 and 200 keV. The existence of implanted gold in the near-surface region of HDPE samples was confirmed by X-ray diffraction analysis. Surface roughness and Power Spectral Density analyses based on Atomic Force Microscopy (AFM) images of the surface topography revealed that the mechanism of HDPE modification during gold ion implantation depended on the energy of gold ions. Histograms obtained from phase AFM images indicated a qualitative change in the chemical composition of the surface during implantation with gold ions with different energies. Depth profiles obtained experimentally from cross-sectional Force Modulation Microscopy images and ones obtained from a theoretical simulation are in agreement for gold ions energies lower than 100 keV. The deviation that was observed for higher energies of the gold ions is explained by carbon precipitation in the near surface region of the HDPE, which prevented the penetration of gold ions further into the depth of the sample.
PB  - Elsevier Science Sa, Lausanne
T2  - Materials Chemistry and Physics
T1  - Modification of high density polyethylene by gold implantation using different ion energies
VL  - 142
IS  - 2-3
SP  - 633
EP  - 639
DO  - 10.1016/j.matchemphys.2013.08.013
ER  - 
@article{
author = "Nenadović, Miloš and Potočnik, Jelena and Mitrić, Miodrag and Štrbac, Svetlana and Rakočević, Zlatko Lj.",
year = "2013",
abstract = "High density polyethylene (HDPE) samples were modified by Au+ ion implantation at a dose of 5 x 10(15) ions cm(-2), using energies of 50, 100, 150 and 200 keV. The existence of implanted gold in the near-surface region of HDPE samples was confirmed by X-ray diffraction analysis. Surface roughness and Power Spectral Density analyses based on Atomic Force Microscopy (AFM) images of the surface topography revealed that the mechanism of HDPE modification during gold ion implantation depended on the energy of gold ions. Histograms obtained from phase AFM images indicated a qualitative change in the chemical composition of the surface during implantation with gold ions with different energies. Depth profiles obtained experimentally from cross-sectional Force Modulation Microscopy images and ones obtained from a theoretical simulation are in agreement for gold ions energies lower than 100 keV. The deviation that was observed for higher energies of the gold ions is explained by carbon precipitation in the near surface region of the HDPE, which prevented the penetration of gold ions further into the depth of the sample.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Materials Chemistry and Physics",
title = "Modification of high density polyethylene by gold implantation using different ion energies",
volume = "142",
number = "2-3",
pages = "633-639",
doi = "10.1016/j.matchemphys.2013.08.013"
}
Nenadović, M., Potočnik, J., Mitrić, M., Štrbac, S.,& Rakočević, Z. Lj.. (2013). Modification of high density polyethylene by gold implantation using different ion energies. in Materials Chemistry and Physics
Elsevier Science Sa, Lausanne., 142(2-3), 633-639.
https://doi.org/10.1016/j.matchemphys.2013.08.013
Nenadović M, Potočnik J, Mitrić M, Štrbac S, Rakočević ZL. Modification of high density polyethylene by gold implantation using different ion energies. in Materials Chemistry and Physics. 2013;142(2-3):633-639.
doi:10.1016/j.matchemphys.2013.08.013 .
Nenadović, Miloš, Potočnik, Jelena, Mitrić, Miodrag, Štrbac, Svetlana, Rakočević, Zlatko Lj., "Modification of high density polyethylene by gold implantation using different ion energies" in Materials Chemistry and Physics, 142, no. 2-3 (2013):633-639,
https://doi.org/10.1016/j.matchemphys.2013.08.013 . .
10
10
11

Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties

Janošević, Aleksandra; Pasti, Igor; Gavrilov, Nemanja; Mentus, Slavko; Krstić, Jugoslav; Mitrić, Miodrag; Travas-Sejdic, Jadranka; Ciric-Marjanovic, Gordana

(Elsevier, 2012)

TY  - JOUR
AU  - Janošević, Aleksandra
AU  - Pasti, Igor
AU  - Gavrilov, Nemanja
AU  - Mentus, Slavko
AU  - Krstić, Jugoslav
AU  - Mitrić, Miodrag
AU  - Travas-Sejdic, Jadranka
AU  - Ciric-Marjanovic, Gordana
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1001
AB  - Microporous conducting nitrogen-containing nanostructured carbon with excellent catalytic activity for the electrochemical synthesis of hydrogen peroxide was synthesized by the carbonization of self-assembled polyaniline 3,5-dinitrosalicylate nanorods. Carbonization was carried out by means of gradual heating in a nitrogen atmosphere up to 800 degrees C. Carbonized polyaniline nanorods containing 9.8 wt.% of nitrogen had a conductivity of 0.35 S cm(-1). The electrical characteristics, morphology, textural parameters, elemental composition, molecular structure and crystallinity of novel carbonized nanostructured polyaniline were investigated by conductivity measurements, scanning and transmission electron microscopies, nitrogen adsorption-desorption measurements, elemental microanalysis, XPS, FTIR and Raman spectroscopies, and XRD, respectively. The electrocatalytic activity of carbonized polyaniline nanorods towards oxygen reduction in alkaline conditions has been studied by the voltammetry with the rotating disk electrode.
PB  - Elsevier
T2  - Microporous and Mesoporous Materials
T1  - Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties
VL  - 152
SP  - 50
EP  - 57
DO  - 10.1016/j.micromeso.2011.12.002
ER  - 
@article{
author = "Janošević, Aleksandra and Pasti, Igor and Gavrilov, Nemanja and Mentus, Slavko and Krstić, Jugoslav and Mitrić, Miodrag and Travas-Sejdic, Jadranka and Ciric-Marjanovic, Gordana",
year = "2012",
abstract = "Microporous conducting nitrogen-containing nanostructured carbon with excellent catalytic activity for the electrochemical synthesis of hydrogen peroxide was synthesized by the carbonization of self-assembled polyaniline 3,5-dinitrosalicylate nanorods. Carbonization was carried out by means of gradual heating in a nitrogen atmosphere up to 800 degrees C. Carbonized polyaniline nanorods containing 9.8 wt.% of nitrogen had a conductivity of 0.35 S cm(-1). The electrical characteristics, morphology, textural parameters, elemental composition, molecular structure and crystallinity of novel carbonized nanostructured polyaniline were investigated by conductivity measurements, scanning and transmission electron microscopies, nitrogen adsorption-desorption measurements, elemental microanalysis, XPS, FTIR and Raman spectroscopies, and XRD, respectively. The electrocatalytic activity of carbonized polyaniline nanorods towards oxygen reduction in alkaline conditions has been studied by the voltammetry with the rotating disk electrode.",
publisher = "Elsevier",
journal = "Microporous and Mesoporous Materials",
title = "Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties",
volume = "152",
pages = "50-57",
doi = "10.1016/j.micromeso.2011.12.002"
}
Janošević, A., Pasti, I., Gavrilov, N., Mentus, S., Krstić, J., Mitrić, M., Travas-Sejdic, J.,& Ciric-Marjanovic, G.. (2012). Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties. in Microporous and Mesoporous Materials
Elsevier., 152, 50-57.
https://doi.org/10.1016/j.micromeso.2011.12.002
Janošević A, Pasti I, Gavrilov N, Mentus S, Krstić J, Mitrić M, Travas-Sejdic J, Ciric-Marjanovic G. Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties. in Microporous and Mesoporous Materials. 2012;152:50-57.
doi:10.1016/j.micromeso.2011.12.002 .
Janošević, Aleksandra, Pasti, Igor, Gavrilov, Nemanja, Mentus, Slavko, Krstić, Jugoslav, Mitrić, Miodrag, Travas-Sejdic, Jadranka, Ciric-Marjanovic, Gordana, "Microporous conducting carbonized polyaniline nanorods: Synthesis, characterization and electrocatalytic properties" in Microporous and Mesoporous Materials, 152 (2012):50-57,
https://doi.org/10.1016/j.micromeso.2011.12.002 . .
53
47
55

Electrochemical behavior of H3PW12O40/acid-activated bentonite powders

Mojović, Zorica; Rožić, Ljiljana; Novaković, Tatjana; Vuković, Zorica; Petrović, Srđan; Randjelović, Danijela; Mitrić, Miodrag

(Association of the Chemical Engineers of Serbia, 2012)

TY  - JOUR
AU  - Mojović, Zorica
AU  - Rožić, Ljiljana
AU  - Novaković, Tatjana
AU  - Vuković, Zorica
AU  - Petrović, Srđan
AU  - Randjelović, Danijela
AU  - Mitrić, Miodrag
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/1013
AB  - Electrochemical behavior of 12-tungstophosphoric acid (HPW)/acid-activated bentonite (AAB) powders with various loadings of HPW was investigated. The physicochemical properties of the prepared powders were examined by X-ray powder diffraction, nitrogen adsorption-desorption isotherms, atomic force microscopy and cyclic voltammetry measurements. The results indicated that the prepared powders are composed mainly of oriented domains of large rock blocks, probably resulting from a preferable deposition of bentonite particles having a face-to-face interaction. The particles had a mainly disordered mesoporous structure with a pore volume that varied according to the pore size in the range of 2-50 nm. In addition, the particles had crystallite size between 4.9 and 9.0 nm. The electrocatalytic activities of prepared HPW/AAB electrodes were studied in the oxidation of NO2 and the results revealed that the electrodes possessed relatively higher nitrite oxidation currents than AAB electrode. The best electroactivity was observed for HPW3/AAB electrode (AAB + + 20 wt. % HPW) and the limit of detection (3σ) was determined as 8 μM.
AB  - U ovom radu je analizirano elektrohemijsko ponašanje prahova kiselo-aktiviranog bentonita (AAB) modifikovanogsa 5, 10 i 20 mas.% 12-volframfosforne kiseline (HPW). Fizičkohemijske osobine pripremljenih prahova su određivane na osnovu analize snimljenih difraktograma praha, adsorpciono-desoprcionih izotermi azota, skenirajuće atomske mikroskopije (atomic force microscopy - AFM) i ciklovoltamograma. Rezultati AFM-a su pokazali da se prahovi uglavnom sastoje od orijentisanih domena velikih blokova, što je verovatno posledica povoljnije orijentacije čestica bentonita koje imaju bočnu interakciju. Takođe, je ustanovljeno da čestice modifikovanih uzoraka uglavnom imaju neuređenu mezoporoznu strukturu dok zapremina pora varira u skladu sa veličinom pora. Na osnovu difraktograma praha sintetisanih uzoraka izračunate su veličine kristalita i njihove vrednosti se nalaze između 4,9 i 9,0 nm. Elektrokatalitička aktivnost pripremljenih HPW/AAB elektroda je ispitana u reakciji oksidacije NO2 i rezultati su pokazali da ove electrode pokazuju veće struje oksidacije nitritnih jona nego AAB elektroda. Najbolja elektroaktivnost je uočena za HPW3/AAB elektrodu (AAB+20 mas.% HPW). Određeni limit detekcije (3σ) je iznosio 8 μM.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Electrochemical behavior of H3PW12O40/acid-activated bentonite powders
T1  - Elektorhemijsko ponašanje praha kiselo-aktiviranog bentonita modifikovanog H3PW12O40 kiselinom
VL  - 18
IS  - 2
SP  - 329
EP  - 338
DO  - 10.2298/CICEQ110907009M
ER  - 
@article{
author = "Mojović, Zorica and Rožić, Ljiljana and Novaković, Tatjana and Vuković, Zorica and Petrović, Srđan and Randjelović, Danijela and Mitrić, Miodrag",
year = "2012",
abstract = "Electrochemical behavior of 12-tungstophosphoric acid (HPW)/acid-activated bentonite (AAB) powders with various loadings of HPW was investigated. The physicochemical properties of the prepared powders were examined by X-ray powder diffraction, nitrogen adsorption-desorption isotherms, atomic force microscopy and cyclic voltammetry measurements. The results indicated that the prepared powders are composed mainly of oriented domains of large rock blocks, probably resulting from a preferable deposition of bentonite particles having a face-to-face interaction. The particles had a mainly disordered mesoporous structure with a pore volume that varied according to the pore size in the range of 2-50 nm. In addition, the particles had crystallite size between 4.9 and 9.0 nm. The electrocatalytic activities of prepared HPW/AAB electrodes were studied in the oxidation of NO2 and the results revealed that the electrodes possessed relatively higher nitrite oxidation currents than AAB electrode. The best electroactivity was observed for HPW3/AAB electrode (AAB + + 20 wt. % HPW) and the limit of detection (3σ) was determined as 8 μM., U ovom radu je analizirano elektrohemijsko ponašanje prahova kiselo-aktiviranog bentonita (AAB) modifikovanogsa 5, 10 i 20 mas.% 12-volframfosforne kiseline (HPW). Fizičkohemijske osobine pripremljenih prahova su određivane na osnovu analize snimljenih difraktograma praha, adsorpciono-desoprcionih izotermi azota, skenirajuće atomske mikroskopije (atomic force microscopy - AFM) i ciklovoltamograma. Rezultati AFM-a su pokazali da se prahovi uglavnom sastoje od orijentisanih domena velikih blokova, što je verovatno posledica povoljnije orijentacije čestica bentonita koje imaju bočnu interakciju. Takođe, je ustanovljeno da čestice modifikovanih uzoraka uglavnom imaju neuređenu mezoporoznu strukturu dok zapremina pora varira u skladu sa veličinom pora. Na osnovu difraktograma praha sintetisanih uzoraka izračunate su veličine kristalita i njihove vrednosti se nalaze između 4,9 i 9,0 nm. Elektrokatalitička aktivnost pripremljenih HPW/AAB elektroda je ispitana u reakciji oksidacije NO2 i rezultati su pokazali da ove electrode pokazuju veće struje oksidacije nitritnih jona nego AAB elektroda. Najbolja elektroaktivnost je uočena za HPW3/AAB elektrodu (AAB+20 mas.% HPW). Određeni limit detekcije (3σ) je iznosio 8 μM.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Electrochemical behavior of H3PW12O40/acid-activated bentonite powders, Elektorhemijsko ponašanje praha kiselo-aktiviranog bentonita modifikovanog H3PW12O40 kiselinom",
volume = "18",
number = "2",
pages = "329-338",
doi = "10.2298/CICEQ110907009M"
}
Mojović, Z., Rožić, L., Novaković, T., Vuković, Z., Petrović, S., Randjelović, D.,& Mitrić, M.. (2012). Electrochemical behavior of H3PW12O40/acid-activated bentonite powders. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Association of the Chemical Engineers of Serbia., 18(2), 329-338.
https://doi.org/10.2298/CICEQ110907009M
Mojović Z, Rožić L, Novaković T, Vuković Z, Petrović S, Randjelović D, Mitrić M. Electrochemical behavior of H3PW12O40/acid-activated bentonite powders. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2012;18(2):329-338.
doi:10.2298/CICEQ110907009M .
Mojović, Zorica, Rožić, Ljiljana, Novaković, Tatjana, Vuković, Zorica, Petrović, Srđan, Randjelović, Danijela, Mitrić, Miodrag, "Electrochemical behavior of H3PW12O40/acid-activated bentonite powders" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 18, no. 2 (2012):329-338,
https://doi.org/10.2298/CICEQ110907009M . .
2
1
2

The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium

Djosic, M. S.; Panić, Vladimir; Stojanovic, J.; Mitrić, Miodrag; Mišković-Stanković, Vesna

(Elsevier, 2012)

TY  - JOUR
AU  - Djosic, M. S.
AU  - Panić, Vladimir
AU  - Stojanovic, J.
AU  - Mitrić, Miodrag
AU  - Mišković-Stanković, Vesna
PY  - 2012
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/950
AB  - Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite.
PB  - Elsevier
T2  - Colloids and Surfaces A-Physicochemical and Engineering Aspects
T1  - The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium
VL  - 400
SP  - 36
EP  - 43
DO  - 10.1016/j.colsurfa.2012.02.040
ER  - 
@article{
author = "Djosic, M. S. and Panić, Vladimir and Stojanovic, J. and Mitrić, Miodrag and Mišković-Stanković, Vesna",
year = "2012",
abstract = "Electrochemical deposition of calcium phosphate coatings on titanium was performed galvanostatically from the aqueous solution of Ca(NO3)(2) and NH4H2PO4 with the current densities between 5.0 and 10 mA cm(-2), for different deposition times, at room temperature. The coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results showed that dicalcium phosphate dihydrate (DCPD), brushite (CaHPO4 center dot 2H(2)O) coatings were deposited. The influence of applied current density and the deposition time on the phase composition, crystallite domain size and the morphology of brushite coatings were investigated. It was shown that brushite coating of the greatest mass was obtained for the longest deposition time, while the increase in current density over 7 mA cm(-2) does not affect significantly the mass of brushite coatings. The finest crystallites, with the smallest crystallite domain size of 15.6nm, were deposited at the current density of 9.0 mA cm(-2). Brushite coatings were fully converted to hydroxyapatite in simulated body fluid (SBF) which was confirmed by XRD and SEM. The crystallite domain size of HA coatings is controlled by applied current density for brushite coatings deposition: crystallization of HA at more porous brushite coatings, deposited at higher current density, caused the formation of smaller crystallites of hydroxyapatite.",
publisher = "Elsevier",
journal = "Colloids and Surfaces A-Physicochemical and Engineering Aspects",
title = "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium",
volume = "400",
pages = "36-43",
doi = "10.1016/j.colsurfa.2012.02.040"
}
Djosic, M. S., Panić, V., Stojanovic, J., Mitrić, M.,& Mišković-Stanković, V.. (2012). The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces A-Physicochemical and Engineering Aspects
Elsevier., 400, 36-43.
https://doi.org/10.1016/j.colsurfa.2012.02.040
Djosic MS, Panić V, Stojanovic J, Mitrić M, Mišković-Stanković V. The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium. in Colloids and Surfaces A-Physicochemical and Engineering Aspects. 2012;400:36-43.
doi:10.1016/j.colsurfa.2012.02.040 .
Djosic, M. S., Panić, Vladimir, Stojanovic, J., Mitrić, Miodrag, Mišković-Stanković, Vesna, "The effect of applied current density on the surface morphology of deposited calcium phosphate coatings on titanium" in Colloids and Surfaces A-Physicochemical and Engineering Aspects, 400 (2012):36-43,
https://doi.org/10.1016/j.colsurfa.2012.02.040 . .
46
41
49

Microstructure and Crystallinity of oriented polyolefins

Mudrinić, Tihana; Miličević, Dejan; Leskovac, Andreja; Mitrić, Miodrag; Suljovrujić, Edin

(Institute of Technical Sciences of the Serbian Academy of Sciences and Arts, 2010)

TY  - CONF
AU  - Mudrinić, Tihana
AU  - Miličević, Dejan
AU  - Leskovac, Andreja
AU  - Mitrić, Miodrag
AU  - Suljovrujić, Edin
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/7004
AB  - The influence of orientation on polyolefins was studied in accordance with Peterlin’s molecular model of drawing. Isotactic polypropylene and low density, linear low density and high density polyethylenes were oriented via solid-state stretching at an elevated temperature. Orientation induced changes in the morphology were analyzed by optical and scanning electron microscopy. Differential scanning calorimetry and wide-angle X-ray diffraction were used to determine changes in the crystallinity where a two-stage evolution was revealed. The first stage is characterized by a significant increase in crystallinity while the following saturation occurs with a further draw ratio increase at the second one. The value of the critical draw ratio, which separates these two stages and corresponds to the transformation from the initial to the fully developed fibrillar structure, was influenced by the structural peculiarities of each polyolefin.
PB  - Institute of Technical Sciences of the Serbian Academy of Sciences and Arts
C3  - Program and the book of abstracts - IX Ninth Young Researchers’ Conference Materials Science and Engineering, December 20-22 2010, Belgrade, Serbia
T1  - Microstructure and Crystallinity of oriented polyolefins
SP  - 22
EP  - 22
UR  - https://hdl.handle.net/21.15107/rcub_cer_7004
ER  - 
@conference{
author = "Mudrinić, Tihana and Miličević, Dejan and Leskovac, Andreja and Mitrić, Miodrag and Suljovrujić, Edin",
year = "2010",
abstract = "The influence of orientation on polyolefins was studied in accordance with Peterlin’s molecular model of drawing. Isotactic polypropylene and low density, linear low density and high density polyethylenes were oriented via solid-state stretching at an elevated temperature. Orientation induced changes in the morphology were analyzed by optical and scanning electron microscopy. Differential scanning calorimetry and wide-angle X-ray diffraction were used to determine changes in the crystallinity where a two-stage evolution was revealed. The first stage is characterized by a significant increase in crystallinity while the following saturation occurs with a further draw ratio increase at the second one. The value of the critical draw ratio, which separates these two stages and corresponds to the transformation from the initial to the fully developed fibrillar structure, was influenced by the structural peculiarities of each polyolefin.",
publisher = "Institute of Technical Sciences of the Serbian Academy of Sciences and Arts",
journal = "Program and the book of abstracts - IX Ninth Young Researchers’ Conference Materials Science and Engineering, December 20-22 2010, Belgrade, Serbia",
title = "Microstructure and Crystallinity of oriented polyolefins",
pages = "22-22",
url = "https://hdl.handle.net/21.15107/rcub_cer_7004"
}
Mudrinić, T., Miličević, D., Leskovac, A., Mitrić, M.,& Suljovrujić, E.. (2010). Microstructure and Crystallinity of oriented polyolefins. in Program and the book of abstracts - IX Ninth Young Researchers’ Conference Materials Science and Engineering, December 20-22 2010, Belgrade, Serbia
Institute of Technical Sciences of the Serbian Academy of Sciences and Arts., 22-22.
https://hdl.handle.net/21.15107/rcub_cer_7004
Mudrinić T, Miličević D, Leskovac A, Mitrić M, Suljovrujić E. Microstructure and Crystallinity of oriented polyolefins. in Program and the book of abstracts - IX Ninth Young Researchers’ Conference Materials Science and Engineering, December 20-22 2010, Belgrade, Serbia. 2010;:22-22.
https://hdl.handle.net/21.15107/rcub_cer_7004 .
Mudrinić, Tihana, Miličević, Dejan, Leskovac, Andreja, Mitrić, Miodrag, Suljovrujić, Edin, "Microstructure and Crystallinity of oriented polyolefins" in Program and the book of abstracts - IX Ninth Young Researchers’ Conference Materials Science and Engineering, December 20-22 2010, Belgrade, Serbia (2010):22-22,
https://hdl.handle.net/21.15107/rcub_cer_7004 .