Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime
Само за регистроване кориснике
2011
Чланак у часопису (Објављена верзија)
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Приказ свих података о документуАпстракт
Optimization of process of formation of open and porous copper electrodes, denoted as the honeycomb-like ones, by the regime of pulsating current (PC) is considered. The square-waves PC were consisted of the same amplitude current density and pause duration of 10 ms, while the analyzed deposition pulses were: 1, 4, 7, 10 and 20 ms. Morphologies of electrodeposited copper and the quantities of evolved hydrogen during electrodeposition processes were compared with the surface morphology and the quantity of evolved hydrogen obtained by copper electrodeposition in the galvanostatic mode. In galvanostatic mode, electrodeposition of copper was performed at a current density which corresponded to the amplitude current density in the PC regimes. Honeycomb-like deposits were formed at the constant current density and by the PC regimes with deposition pulses of 7, 10 and 20 ms. The mixture of holes constructing the honeycomb-like structure and dish-like holes was obtained with a deposition pulse... of 4 ms. Finally, dish-like holes were only formed with a deposition pulse of 1 ms. The change of the shape of holes was discussed by the change of hydrodynamic conditions in the near-electrode layer caused by evolved hydrogen. The specific energy consumption in the PC regimes of electrolysis was also discussed. Analysis of the specific energy consumption showed that energy saving of about 15% can be attained in the production of honeycomb-like electrodes by the choice of the appropriate PC regime.
Кључне речи:
Microporous materials / Crystal growth / Electrochemical techniques / MicrostructureИзвор:
Materials Chemistry and Physics, 2011, 125, 3, 587-594Издавач:
- Elsevier Science Sa, Lausanne
Финансирање / пројекти:
- Електрохемијска синтеза и карактеризација наноструктурираних функционалних материјала за примену у новим технологијама (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.1016/j.matchemphys.2010.10.013
ISSN: 0254-0584
WoS: 000286904800043
Scopus: 2-s2.0-78650016924
Институција/група
IHTMTY - JOUR AU - Nikolić, Nebojša D. AU - Branković, Goran AU - Popov, Konstantin I. PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/922 AB - Optimization of process of formation of open and porous copper electrodes, denoted as the honeycomb-like ones, by the regime of pulsating current (PC) is considered. The square-waves PC were consisted of the same amplitude current density and pause duration of 10 ms, while the analyzed deposition pulses were: 1, 4, 7, 10 and 20 ms. Morphologies of electrodeposited copper and the quantities of evolved hydrogen during electrodeposition processes were compared with the surface morphology and the quantity of evolved hydrogen obtained by copper electrodeposition in the galvanostatic mode. In galvanostatic mode, electrodeposition of copper was performed at a current density which corresponded to the amplitude current density in the PC regimes. Honeycomb-like deposits were formed at the constant current density and by the PC regimes with deposition pulses of 7, 10 and 20 ms. The mixture of holes constructing the honeycomb-like structure and dish-like holes was obtained with a deposition pulse of 4 ms. Finally, dish-like holes were only formed with a deposition pulse of 1 ms. The change of the shape of holes was discussed by the change of hydrodynamic conditions in the near-electrode layer caused by evolved hydrogen. The specific energy consumption in the PC regimes of electrolysis was also discussed. Analysis of the specific energy consumption showed that energy saving of about 15% can be attained in the production of honeycomb-like electrodes by the choice of the appropriate PC regime. PB - Elsevier Science Sa, Lausanne T2 - Materials Chemistry and Physics T1 - Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime VL - 125 IS - 3 SP - 587 EP - 594 DO - 10.1016/j.matchemphys.2010.10.013 ER -
@article{ author = "Nikolić, Nebojša D. and Branković, Goran and Popov, Konstantin I.", year = "2011", abstract = "Optimization of process of formation of open and porous copper electrodes, denoted as the honeycomb-like ones, by the regime of pulsating current (PC) is considered. The square-waves PC were consisted of the same amplitude current density and pause duration of 10 ms, while the analyzed deposition pulses were: 1, 4, 7, 10 and 20 ms. Morphologies of electrodeposited copper and the quantities of evolved hydrogen during electrodeposition processes were compared with the surface morphology and the quantity of evolved hydrogen obtained by copper electrodeposition in the galvanostatic mode. In galvanostatic mode, electrodeposition of copper was performed at a current density which corresponded to the amplitude current density in the PC regimes. Honeycomb-like deposits were formed at the constant current density and by the PC regimes with deposition pulses of 7, 10 and 20 ms. The mixture of holes constructing the honeycomb-like structure and dish-like holes was obtained with a deposition pulse of 4 ms. Finally, dish-like holes were only formed with a deposition pulse of 1 ms. The change of the shape of holes was discussed by the change of hydrodynamic conditions in the near-electrode layer caused by evolved hydrogen. The specific energy consumption in the PC regimes of electrolysis was also discussed. Analysis of the specific energy consumption showed that energy saving of about 15% can be attained in the production of honeycomb-like electrodes by the choice of the appropriate PC regime.", publisher = "Elsevier Science Sa, Lausanne", journal = "Materials Chemistry and Physics", title = "Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime", volume = "125", number = "3", pages = "587-594", doi = "10.1016/j.matchemphys.2010.10.013" }
Nikolić, N. D., Branković, G.,& Popov, K. I.. (2011). Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime. in Materials Chemistry and Physics Elsevier Science Sa, Lausanne., 125(3), 587-594. https://doi.org/10.1016/j.matchemphys.2010.10.013
Nikolić ND, Branković G, Popov KI. Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime. in Materials Chemistry and Physics. 2011;125(3):587-594. doi:10.1016/j.matchemphys.2010.10.013 .
Nikolić, Nebojša D., Branković, Goran, Popov, Konstantin I., "Optimization of electrolytic process of formation of open and porous copper electrodes by the pulsating current (PC) regime" in Materials Chemistry and Physics, 125, no. 3 (2011):587-594, https://doi.org/10.1016/j.matchemphys.2010.10.013 . .