A mathematical model of the current density distribution in electrochemical cells
Matematički model raspodele gustine struje u elektrohemijskim ćelijama
Апстракт
An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.
Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.
Кључне речи:
current distribution / edge effect / corner effectИзвор:
Journal of the Serbian Chemical Society, 2011, 76, 6, 805-822Издавач:
- Serbian Chemical Society
Финансирање / пројекти:
- Електрохемијска синтеза и карактеризација наноструктурираних функционалних материјала за примену у новим технологијама (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.2298/JSC100312079P
ISSN: 0352-5139
WoS: 000292714000001
Scopus: 2-s2.0-79959424723
Институција/група
IHTMTY - JOUR AU - Popov, Konstantin I. AU - Živković, Predrag M. AU - Nikolić, Nebojša D. PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/790 AB - An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented. AB - Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - A mathematical model of the current density distribution in electrochemical cells T1 - Matematički model raspodele gustine struje u elektrohemijskim ćelijama VL - 76 IS - 6 SP - 805 EP - 822 DO - 10.2298/JSC100312079P ER -
@article{ author = "Popov, Konstantin I. and Živković, Predrag M. and Nikolić, Nebojša D.", year = "2011", abstract = "An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented., Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "A mathematical model of the current density distribution in electrochemical cells, Matematički model raspodele gustine struje u elektrohemijskim ćelijama", volume = "76", number = "6", pages = "805-822", doi = "10.2298/JSC100312079P" }
Popov, K. I., Živković, P. M.,& Nikolić, N. D.. (2011). A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society Serbian Chemical Society., 76(6), 805-822. https://doi.org/10.2298/JSC100312079P
Popov KI, Živković PM, Nikolić ND. A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society. 2011;76(6):805-822. doi:10.2298/JSC100312079P .
Popov, Konstantin I., Živković, Predrag M., Nikolić, Nebojša D., "A mathematical model of the current density distribution in electrochemical cells" in Journal of the Serbian Chemical Society, 76, no. 6 (2011):805-822, https://doi.org/10.2298/JSC100312079P . .