Приказ основних података о документу
Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage
dc.creator | Popadić, Daliborka | |
dc.creator | Krstić, Jugoslav | |
dc.creator | Janošević-Ležaić, Aleksandra | |
dc.creator | Popović, Maja | |
dc.creator | Milojević-Rakić, Maja | |
dc.creator | Ignjatović, Ljubiša | |
dc.creator | Bajuk-Bogdanović, Danica | |
dc.creator | Gavrilov, Nemanja | |
dc.date.accessioned | 2024-01-19T10:32:17Z | |
dc.date.available | 2024-01-19T10:32:17Z | |
dc.date.issued | 2024 | |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/7399 | |
dc.description.abstract | Reuse and/or recycling of spent adsorbents is taking a central role in modern thinking and catalyzed carbonization is the way forward. Herein we explore the carbonization of adsorbed acetamiprid, in an inert atmosphere, as a way of recycling and producing nitrogen-rich carbon material for potential use in supercapacitors. Added value material and the reuse of the adsorbent were achieved by carbonization at 700 °C under argon. The formation of a nitrogen-doped carbon layer as an active material on the adsorbent, bonded through a C-Si linkage, has been conclusively verified through elemental composition quantification using XPS and EDX measurements. Two-stage catalytic decomposition and condensation of the adsorbed pesticide is followed by TGA and TPD-MS. Attained carbon-based materials give stable Faradaic capacitance with a slight dependency on the number of adsorbing cycles. Capacitance calculated with respect to the adlayer carbon material reaches values as high as 610 F g−1. Galvanostatic Charge/Discharge measurement confirmed the stability of explored materials with a slight increase in capacitance over 1000 cycles. The presented results envisage electroactive materials preparation from environmental pollutants, adding value to spent adsorbents. | |
dc.publisher | Elsevier | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200146/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200161/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS// | |
dc.rights | restrictedAccess | |
dc.source | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | |
dc.subject | Capacitance | |
dc.subject | Acetamiprid | |
dc.subject | Carbonization | |
dc.subject | Pesticide | |
dc.subject | Supercapacitor | |
dc.subject | Thin film | |
dc.title | Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage | |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.volume | 308 | |
dc.citation.spage | 123772 | |
dc.citation.rank | M21~ | |
dc.identifier.pmid | 38128326 | |
dc.identifier.doi | 10.1016/j.saa.2023.123772 | |
dc.identifier.scopus | 2-s2.0-85180540366 | |
dc.type.version | publishedVersion |