Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage
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2024
Authors
Popadić, DaliborkaKrstić, Jugoslav
Janošević-Ležaić, Aleksandra
Popović, Maja
Milojević-Rakić, Maja
Ignjatović, Ljubiša
Bajuk-Bogdanović, Danica
Gavrilov, Nemanja
Article (Published version)
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Reuse and/or recycling of spent adsorbents is taking a central role in modern thinking and catalyzed carbonization is the way forward. Herein we explore the carbonization of adsorbed acetamiprid, in an inert atmosphere, as a way of recycling and producing nitrogen-rich carbon material for potential use in supercapacitors. Added value material and the reuse of the adsorbent were achieved by carbonization at 700 °C under argon. The formation of a nitrogen-doped carbon layer as an active material on the adsorbent, bonded through a C-Si linkage, has been conclusively verified through elemental composition quantification using XPS and EDX measurements. Two-stage catalytic decomposition and condensation of the adsorbed pesticide is followed by TGA and TPD-MS. Attained carbon-based materials give stable Faradaic capacitance with a slight dependency on the number of adsorbing cycles. Capacitance calculated with respect to the adlayer carbon material reaches values as high as 610 F g−1. Galvano...static Charge/Discharge measurement confirmed the stability of explored materials with a slight increase in capacitance over 1000 cycles. The presented results envisage electroactive materials preparation from environmental pollutants, adding value to spent adsorbents.
Keywords:
Capacitance / Acetamiprid / Carbonization / Pesticide / Supercapacitor / Thin filmSource:
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2024, 308, 123772-Publisher:
- Elsevier
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-MESTD-inst-2020-200146)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200161 (University of Belgrade, Faculty of Pharmacy) (RS-MESTD-inst-2020-200161)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-MESTD-inst-2020-200017)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
DOI: 10.1016/j.saa.2023.123772
ISSN: 1386-1425
PubMed: 38128326
Scopus: 2-s2.0-85180540366
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IHTMTY - JOUR AU - Popadić, Daliborka AU - Krstić, Jugoslav AU - Janošević-Ležaić, Aleksandra AU - Popović, Maja AU - Milojević-Rakić, Maja AU - Ignjatović, Ljubiša AU - Bajuk-Bogdanović, Danica AU - Gavrilov, Nemanja PY - 2024 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/7399 AB - Reuse and/or recycling of spent adsorbents is taking a central role in modern thinking and catalyzed carbonization is the way forward. Herein we explore the carbonization of adsorbed acetamiprid, in an inert atmosphere, as a way of recycling and producing nitrogen-rich carbon material for potential use in supercapacitors. Added value material and the reuse of the adsorbent were achieved by carbonization at 700 °C under argon. The formation of a nitrogen-doped carbon layer as an active material on the adsorbent, bonded through a C-Si linkage, has been conclusively verified through elemental composition quantification using XPS and EDX measurements. Two-stage catalytic decomposition and condensation of the adsorbed pesticide is followed by TGA and TPD-MS. Attained carbon-based materials give stable Faradaic capacitance with a slight dependency on the number of adsorbing cycles. Capacitance calculated with respect to the adlayer carbon material reaches values as high as 610 F g−1. Galvanostatic Charge/Discharge measurement confirmed the stability of explored materials with a slight increase in capacitance over 1000 cycles. The presented results envisage electroactive materials preparation from environmental pollutants, adding value to spent adsorbents. PB - Elsevier T2 - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy T1 - Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage VL - 308 SP - 123772 DO - 10.1016/j.saa.2023.123772 ER -
@article{ author = "Popadić, Daliborka and Krstić, Jugoslav and Janošević-Ležaić, Aleksandra and Popović, Maja and Milojević-Rakić, Maja and Ignjatović, Ljubiša and Bajuk-Bogdanović, Danica and Gavrilov, Nemanja", year = "2024", abstract = "Reuse and/or recycling of spent adsorbents is taking a central role in modern thinking and catalyzed carbonization is the way forward. Herein we explore the carbonization of adsorbed acetamiprid, in an inert atmosphere, as a way of recycling and producing nitrogen-rich carbon material for potential use in supercapacitors. Added value material and the reuse of the adsorbent were achieved by carbonization at 700 °C under argon. The formation of a nitrogen-doped carbon layer as an active material on the adsorbent, bonded through a C-Si linkage, has been conclusively verified through elemental composition quantification using XPS and EDX measurements. Two-stage catalytic decomposition and condensation of the adsorbed pesticide is followed by TGA and TPD-MS. Attained carbon-based materials give stable Faradaic capacitance with a slight dependency on the number of adsorbing cycles. Capacitance calculated with respect to the adlayer carbon material reaches values as high as 610 F g−1. Galvanostatic Charge/Discharge measurement confirmed the stability of explored materials with a slight increase in capacitance over 1000 cycles. The presented results envisage electroactive materials preparation from environmental pollutants, adding value to spent adsorbents.", publisher = "Elsevier", journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy", title = "Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage", volume = "308", pages = "123772", doi = "10.1016/j.saa.2023.123772" }
Popadić, D., Krstić, J., Janošević-Ležaić, A., Popović, M., Milojević-Rakić, M., Ignjatović, L., Bajuk-Bogdanović, D.,& Gavrilov, N.. (2024). Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage. in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy Elsevier., 308, 123772. https://doi.org/10.1016/j.saa.2023.123772
Popadić D, Krstić J, Janošević-Ležaić A, Popović M, Milojević-Rakić M, Ignjatović L, Bajuk-Bogdanović D, Gavrilov N. Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage. in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy. 2024;308:123772. doi:10.1016/j.saa.2023.123772 .
Popadić, Daliborka, Krstić, Jugoslav, Janošević-Ležaić, Aleksandra, Popović, Maja, Milojević-Rakić, Maja, Ignjatović, Ljubiša, Bajuk-Bogdanović, Danica, Gavrilov, Nemanja, "Acetamiprid's degradation products and mechanism: Part II – Inert atmosphere and charge storage" in Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 308 (2024):123772, https://doi.org/10.1016/j.saa.2023.123772 . .