Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Fullerene is one of carbon allotropes with extremely low solubility in aqueous solvents and most organic solvents, but high potential of application in various areas, such as medicine, photovoltaics and materials. To overcome this obstacle, fullerene needs to be functionalized. The Prato reaction is decent synthetic method that provides N- and C-substituted fulleropyrrolidines. We optimized the conditions of the Prato reaction in order to obtain fulleropyrrolidines containing phenol (3d) and protected phenol subunits (3a, 3b). (Figure 1) The desired products were purified by dry-flash chromatography and obtained in satisfactory yields.
Кључне речи:
fullerene / synthesis / reaction conditionsИзвор:
9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia, 2023, 75-75Издавач:
- Belgrade : Serbian Chemical Society
- Belgrade : Serbian Young Chemists’ Club
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
Институција/група
IHTMTY - CONF AU - Kotlaja, Katarina AU - Trifković, Željko AU - Kop, Tatjana AU - Milić, Dragana PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/7012 AB - Fullerene is one of carbon allotropes with extremely low solubility in aqueous solvents and most organic solvents, but high potential of application in various areas, such as medicine, photovoltaics and materials. To overcome this obstacle, fullerene needs to be functionalized. The Prato reaction is decent synthetic method that provides N- and C-substituted fulleropyrrolidines. We optimized the conditions of the Prato reaction in order to obtain fulleropyrrolidines containing phenol (3d) and protected phenol subunits (3a, 3b). (Figure 1) The desired products were purified by dry-flash chromatography and obtained in satisfactory yields. PB - Belgrade : Serbian Chemical Society PB - Belgrade : Serbian Young Chemists’ Club C3 - 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia T1 - Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions SP - 75 EP - 75 UR - https://hdl.handle.net/21.15107/rcub_cer_7012 ER -
@conference{ author = "Kotlaja, Katarina and Trifković, Željko and Kop, Tatjana and Milić, Dragana", year = "2023", abstract = "Fullerene is one of carbon allotropes with extremely low solubility in aqueous solvents and most organic solvents, but high potential of application in various areas, such as medicine, photovoltaics and materials. To overcome this obstacle, fullerene needs to be functionalized. The Prato reaction is decent synthetic method that provides N- and C-substituted fulleropyrrolidines. We optimized the conditions of the Prato reaction in order to obtain fulleropyrrolidines containing phenol (3d) and protected phenol subunits (3a, 3b). (Figure 1) The desired products were purified by dry-flash chromatography and obtained in satisfactory yields.", publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists’ Club", journal = "9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia", title = "Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions", pages = "75-75", url = "https://hdl.handle.net/21.15107/rcub_cer_7012" }
Kotlaja, K., Trifković, Ž., Kop, T.,& Milić, D.. (2023). Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia Belgrade : Serbian Chemical Society., 75-75. https://hdl.handle.net/21.15107/rcub_cer_7012
Kotlaja K, Trifković Ž, Kop T, Milić D. Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia. 2023;:75-75. https://hdl.handle.net/21.15107/rcub_cer_7012 .
Kotlaja, Katarina, Trifković, Željko, Kop, Tatjana, Milić, Dragana, "Mono- and disubstituted fulleropyrrolidines: synthesis and optimization of reaction conditions" in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia (2023):75-75, https://hdl.handle.net/21.15107/rcub_cer_7012 .