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Asymmetric Epoxidation of α-Substituted Acroleins Catalyzed by Diphenylprolinol Silyl Ether
dc.creator | Bondžić, Bojan | |
dc.creator | Urushima, Tatsuya | |
dc.creator | Ishikawa, Hayato | |
dc.creator | Hayashi, Yujiro | |
dc.date.accessioned | 2023-11-06T06:55:10Z | |
dc.date.available | 2023-11-06T06:55:10Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/6812 | |
dc.description.abstract | Asymmetric epoxidation of α-substituted acroleins with hydrogen peroxide has been catalyzed by diphenylprolinol diphenylmethylsilyl ether to afford α-substituted-β,β-unsubstituted-α,β-epoxy aldehyde with excellent enantioselectivity and the generation of a chiral quaternary carbon center. The method was applied to a short synthesis of (R)-methyl palmoxirate. | sr |
dc.language.iso | en | sr |
dc.publisher | American Chemical Society (ACS) | sr |
dc.rights | restrictedAccess | sr |
dc.source | Organic Letters | sr |
dc.subject | epoxidation | sr |
dc.subject | Asymmetric epoxidation | sr |
dc.subject | (R)-methyl palmoxirate | sr |
dc.title | Asymmetric Epoxidation of α-Substituted Acroleins Catalyzed by Diphenylprolinol Silyl Ether | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dc.citation.volume | 12 | |
dc.citation.issue | 23 | |
dc.citation.spage | 5434 | |
dc.citation.epage | 5437 | |
dc.citation.rank | aM21 | |
dc.identifier.pmid | 21049980 | |
dc.identifier.doi | 10.1021/ol102269s | |
dc.identifier.scopus | 2-s2.0-78650339798 | |
dc.type.version | publishedVersion | sr |