Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent
Аутори
Tadić, TamaraSandić, Zvjezdana
Bulatović, Sandra
Marković, Bojana
Nastasović, Aleksandra
Onjia, Antonije
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Silver as one of the most known precious metal is used on a large scale in various industrial
branches and the release of silver ions from such industrial activities potentially can cause
serious environmental problems. Therefore, the removal of this metal from wastewater is a great
challenge, and it is crucial for the quality improvement of the environment. Porous polymer
materials with high specific surface areas and other specific physical and chemical
characteristics have gained much attention as sorbents in the field of environmental protection.
In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
copolymer synthesized by suspension copolymerization and functionalized with
diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjusted
pH and room temperature. The sorption kinetics and isotherms were studied to establish the
mechanisms of sorption process. The kinetic data were modeled with pseudo-first-ord...er (PFO),
pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle
diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized using
Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions such as
coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square
statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error
(RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average
relative error (ARE) were used to estimate the error deviations between theoretically predicted
and experimental values of sorption capacities. The best kinetic and isotherm models were
determined by normalizing eight error functions and finding the sum of normalized error value
(SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous
amino-functionalized sorbent obeys the PSO kinetic model. In addition, the results indicate that
sorption was governed by intraparticle diffusion with the evident influence of liquid film
diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted
to the Redlich-Peterson isotherm model.
Кључне речи:
silver / macroporous sorbent / error functions / glycidyl methacrylate / sorptionИзвор:
Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina, 2023, 244-252Издавач:
- University of East Sarajevo, Faculty of Technology
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
Напомена:
Повезане информације:
- Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/6767
Институција/група
IHTMTY - CONF AU - Tadić, Tamara AU - Sandić, Zvjezdana AU - Bulatović, Sandra AU - Marković, Bojana AU - Nastasović, Aleksandra AU - Onjia, Antonije PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6769 AB - Silver as one of the most known precious metal is used on a large scale in various industrial branches and the release of silver ions from such industrial activities potentially can cause serious environmental problems. Therefore, the removal of this metal from wastewater is a great challenge, and it is crucial for the quality improvement of the environment. Porous polymer materials with high specific surface areas and other specific physical and chemical characteristics have gained much attention as sorbents in the field of environmental protection. In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) copolymer synthesized by suspension copolymerization and functionalized with diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjusted pH and room temperature. The sorption kinetics and isotherms were studied to establish the mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO), pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized using Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions such as coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error (RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average relative error (ARE) were used to estimate the error deviations between theoretically predicted and experimental values of sorption capacities. The best kinetic and isotherm models were determined by normalizing eight error functions and finding the sum of normalized error value (SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous amino-functionalized sorbent obeys the PSO kinetic model. In addition, the results indicate that sorption was governed by intraparticle diffusion with the evident influence of liquid film diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted to the Redlich-Peterson isotherm model. PB - University of East Sarajevo, Faculty of Technology C3 - Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina T1 - Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent SP - 244 EP - 252 UR - https://hdl.handle.net/21.15107/rcub_cer_6769 ER -
@conference{ author = "Tadić, Tamara and Sandić, Zvjezdana and Bulatović, Sandra and Marković, Bojana and Nastasović, Aleksandra and Onjia, Antonije", year = "2023", abstract = "Silver as one of the most known precious metal is used on a large scale in various industrial branches and the release of silver ions from such industrial activities potentially can cause serious environmental problems. Therefore, the removal of this metal from wastewater is a great challenge, and it is crucial for the quality improvement of the environment. Porous polymer materials with high specific surface areas and other specific physical and chemical characteristics have gained much attention as sorbents in the field of environmental protection. In this paper, macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) copolymer synthesized by suspension copolymerization and functionalized with diethylenetriamine was employed for silver ions sorption from aqueous solution at unadjusted pH and room temperature. The sorption kinetics and isotherms were studied to establish the mechanisms of sorption process. The kinetic data were modeled with pseudo-first-order (PFO), pseudo-second-order (PSO), Elovich and fractional power (FP) models as well as intraparticle diffusion (IPD) and liquid diffusion model (LFD), while the equilibrium data were analized using Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Eight error functions such as coefficient of determination (R2), Marquardt’s percent standard deviation (MPSD), Chi-square statistic test (χ2), hybrid fractional error function (HYBRID), the root mean square error (RMSE), the sum of the errors squared (SSE), sum of the absolute errors (SAE), and average relative error (ARE) were used to estimate the error deviations between theoretically predicted and experimental values of sorption capacities. The best kinetic and isotherm models were determined by normalizing eight error functions and finding the sum of normalized error value (SNE). The sorption kinetic studies revealed that the sorption of silver by macroporous amino-functionalized sorbent obeys the PSO kinetic model. In addition, the results indicate that sorption was governed by intraparticle diffusion with the evident influence of liquid film diffusion. The obtained results showed that the sorption isotherm data were satisfactorily fitted to the Redlich-Peterson isotherm model.", publisher = "University of East Sarajevo, Faculty of Technology", journal = "Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina", title = "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent", pages = "244-252", url = "https://hdl.handle.net/21.15107/rcub_cer_6769" }
Tadić, T., Sandić, Z., Bulatović, S., Marković, B., Nastasović, A.,& Onjia, A.. (2023). Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina University of East Sarajevo, Faculty of Technology., 244-252. https://hdl.handle.net/21.15107/rcub_cer_6769
Tadić T, Sandić Z, Bulatović S, Marković B, Nastasović A, Onjia A. Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent. in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina. 2023;:244-252. https://hdl.handle.net/21.15107/rcub_cer_6769 .
Tadić, Tamara, Sandić, Zvjezdana, Bulatović, Sandra, Marković, Bojana, Nastasović, Aleksandra, Onjia, Antonije, "Kinetics and isotherms modeling of silver removal onto macroporous amino sorbent" in Proceedings - VIII International Congress “Engineering, Environment and Materials in Process Industry," March 20-23, 2023, Jahorina, Republic of Srpska, Bosnia and Herzegovina (2023):244-252, https://hdl.handle.net/21.15107/rcub_cer_6769 .