Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach
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2023
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Prikaz svih podataka o dokumentuApstrakt
In this work, a tetrafunctional epoxy resin entitled 2,3,4,5-tetraglycidyloxy pentanal (TGP) was tested and investigated as a potential corrosion inhibitor for mild steel (MS) in 0.5 M H2SO4 solution. The corrosion inhibition process for mild steel was employed alongside various techniques, such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), temperature effect (TE), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and theoretical approaches (DFT, MC, RDF and MD). Further, the corrosion efficacies obtained at the optimum concentration (10−3 M of the TGP) were 85.5% (EIS) and 88.6% (PDP), respectively. The PDP results indicated that the TGP tetrafunctional epoxy resin acted the same as an anodic inhibitor type in 0.5 M H2SO4 solution. SEM and EDS analyses found that the protective layer formed on the MS electrode surface in the presence of TGP could prevent the attack of the sulfur ions. The DFT calculation provided more... information regarding the reactivity, geometric properties and the active centers of the corrosion inhibitory efficiency of the tested epoxy resin. RDF, MC and MD simulations showed that the investigated inhibitory resin have a maximum inhibition efficiency in 0.5 M H2SO4 solution.
Ključne reči:
TGP epoxy resin / MS/0.5 M H2SO4 / corrosion inhibitor / PDP/EIS techniques / SEM/EDS analyses / DFT calculation / MC and MD simulationsIzvor:
Journal of Solid State Electrochemistry, 2023Izdavač:
- Springer
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
DOI: 10.1007/s10008-023-05433-w
ISSN: 1432-8488
WoS: 000937588900001
Scopus: 2-s2.0-85148639486
Institucija/grupa
IHTMTY - JOUR AU - Simović, Anđela AU - Stevanović, Sanja AU - Milovanović, Branislav AU - Etinski, Mihajlo AU - Bajat, Jelena B. PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6312 AB - In this work, a tetrafunctional epoxy resin entitled 2,3,4,5-tetraglycidyloxy pentanal (TGP) was tested and investigated as a potential corrosion inhibitor for mild steel (MS) in 0.5 M H2SO4 solution. The corrosion inhibition process for mild steel was employed alongside various techniques, such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), temperature effect (TE), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and theoretical approaches (DFT, MC, RDF and MD). Further, the corrosion efficacies obtained at the optimum concentration (10−3 M of the TGP) were 85.5% (EIS) and 88.6% (PDP), respectively. The PDP results indicated that the TGP tetrafunctional epoxy resin acted the same as an anodic inhibitor type in 0.5 M H2SO4 solution. SEM and EDS analyses found that the protective layer formed on the MS electrode surface in the presence of TGP could prevent the attack of the sulfur ions. The DFT calculation provided more information regarding the reactivity, geometric properties and the active centers of the corrosion inhibitory efficiency of the tested epoxy resin. RDF, MC and MD simulations showed that the investigated inhibitory resin have a maximum inhibition efficiency in 0.5 M H2SO4 solution. PB - Springer T2 - Journal of Solid State Electrochemistry T1 - Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach DO - 10.1007/s10008-023-05433-w ER -
@article{ author = "Simović, Anđela and Stevanović, Sanja and Milovanović, Branislav and Etinski, Mihajlo and Bajat, Jelena B.", year = "2023", abstract = "In this work, a tetrafunctional epoxy resin entitled 2,3,4,5-tetraglycidyloxy pentanal (TGP) was tested and investigated as a potential corrosion inhibitor for mild steel (MS) in 0.5 M H2SO4 solution. The corrosion inhibition process for mild steel was employed alongside various techniques, such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), temperature effect (TE), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and theoretical approaches (DFT, MC, RDF and MD). Further, the corrosion efficacies obtained at the optimum concentration (10−3 M of the TGP) were 85.5% (EIS) and 88.6% (PDP), respectively. The PDP results indicated that the TGP tetrafunctional epoxy resin acted the same as an anodic inhibitor type in 0.5 M H2SO4 solution. SEM and EDS analyses found that the protective layer formed on the MS electrode surface in the presence of TGP could prevent the attack of the sulfur ions. The DFT calculation provided more information regarding the reactivity, geometric properties and the active centers of the corrosion inhibitory efficiency of the tested epoxy resin. RDF, MC and MD simulations showed that the investigated inhibitory resin have a maximum inhibition efficiency in 0.5 M H2SO4 solution.", publisher = "Springer", journal = "Journal of Solid State Electrochemistry", title = "Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach", doi = "10.1007/s10008-023-05433-w" }
Simović, A., Stevanović, S., Milovanović, B., Etinski, M.,& Bajat, J. B.. (2023). Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach. in Journal of Solid State Electrochemistry Springer.. https://doi.org/10.1007/s10008-023-05433-w
Simović A, Stevanović S, Milovanović B, Etinski M, Bajat JB. Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach. in Journal of Solid State Electrochemistry. 2023;. doi:10.1007/s10008-023-05433-w .
Simović, Anđela, Stevanović, Sanja, Milovanović, Branislav, Etinski, Mihajlo, Bajat, Jelena B., "Green corrosion inhibitors of steel based on peptides and their constituents: a combination of experimental and computational approach" in Journal of Solid State Electrochemistry (2023), https://doi.org/10.1007/s10008-023-05433-w . .