Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys
Аутори
Radojković, Bojana M.Marunkić, Dunja D.
Pejić, Jovanka N.
Milošević, Milena D.
Jegdić, Bore
Marinković, Aleksandar D.
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The corrosion protective properties of environmentally friendly Ce-citrate were analyzed on AISI 4130 low alloy carbon steel and AA7075 aluminum alloy in 0.05 M NaCl solution. For this purpose different concentrations of corrosion inhibitor were analyzed in the range of 0.1-0.5 mM. Electrochemical impedance spectroscopy and potentiodynamic polarization test were used for measurements of resistance to general corrosion. Pitting potential Epit value was used for the determination of resistance to pitting corrosion. Additionally, corrosion resistance measurements and determination of pitting potential value were performed in Ce-chloride solution with the aim of comparation. SEM microscopy was used for the determination of changes on the surface of the specimens after corrosion testing. The XPS method was used for the analyses of the formed inhibitory layer on the steel specimen surface. It has been shown that significant amounts of cerium, as well as the citrate anions, are present in the... inhibitory layer. Ce-citrates have proved to be an effective corrosion inhibitor for AISI 4130 steel as well as an effective pitting corrosion inhibitor for AA7075 aluminum alloy. The mechanism of action of Ce-citrate on AISI 4130 steel and AA7075 aluminum alloy has been proposed.
Кључне речи:
Low alloy steel / aluminium alloys / corrosion / green corrosion inhibitor / electrochemical methods / XPSИзвор:
Proceeding - XXIII YuCorr International Conference, 2022, 23, 43-51Издавач:
- Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (Uiskozam)
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-200135)
Напомена:
- XXIII YUCORR International Conference, 116th-19th May 2022, Divčibare, Serbia, invited talk (Bojana Radojković)
Институција/група
IHTMTY - CONF AU - Radojković, Bojana M. AU - Marunkić, Dunja D. AU - Pejić, Jovanka N. AU - Milošević, Milena D. AU - Jegdić, Bore AU - Marinković, Aleksandar D. PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5436 AB - The corrosion protective properties of environmentally friendly Ce-citrate were analyzed on AISI 4130 low alloy carbon steel and AA7075 aluminum alloy in 0.05 M NaCl solution. For this purpose different concentrations of corrosion inhibitor were analyzed in the range of 0.1-0.5 mM. Electrochemical impedance spectroscopy and potentiodynamic polarization test were used for measurements of resistance to general corrosion. Pitting potential Epit value was used for the determination of resistance to pitting corrosion. Additionally, corrosion resistance measurements and determination of pitting potential value were performed in Ce-chloride solution with the aim of comparation. SEM microscopy was used for the determination of changes on the surface of the specimens after corrosion testing. The XPS method was used for the analyses of the formed inhibitory layer on the steel specimen surface. It has been shown that significant amounts of cerium, as well as the citrate anions, are present in the inhibitory layer. Ce-citrates have proved to be an effective corrosion inhibitor for AISI 4130 steel as well as an effective pitting corrosion inhibitor for AA7075 aluminum alloy. The mechanism of action of Ce-citrate on AISI 4130 steel and AA7075 aluminum alloy has been proposed. PB - Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (Uiskozam) C3 - Proceeding - XXIII YuCorr International Conference T1 - Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys VL - 23 SP - 43 EP - 51 UR - https://hdl.handle.net/21.15107/rcub_cer_5436 ER -
@conference{ author = "Radojković, Bojana M. and Marunkić, Dunja D. and Pejić, Jovanka N. and Milošević, Milena D. and Jegdić, Bore and Marinković, Aleksandar D.", year = "2022", abstract = "The corrosion protective properties of environmentally friendly Ce-citrate were analyzed on AISI 4130 low alloy carbon steel and AA7075 aluminum alloy in 0.05 M NaCl solution. For this purpose different concentrations of corrosion inhibitor were analyzed in the range of 0.1-0.5 mM. Electrochemical impedance spectroscopy and potentiodynamic polarization test were used for measurements of resistance to general corrosion. Pitting potential Epit value was used for the determination of resistance to pitting corrosion. Additionally, corrosion resistance measurements and determination of pitting potential value were performed in Ce-chloride solution with the aim of comparation. SEM microscopy was used for the determination of changes on the surface of the specimens after corrosion testing. The XPS method was used for the analyses of the formed inhibitory layer on the steel specimen surface. It has been shown that significant amounts of cerium, as well as the citrate anions, are present in the inhibitory layer. Ce-citrates have proved to be an effective corrosion inhibitor for AISI 4130 steel as well as an effective pitting corrosion inhibitor for AA7075 aluminum alloy. The mechanism of action of Ce-citrate on AISI 4130 steel and AA7075 aluminum alloy has been proposed.", publisher = "Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (Uiskozam)", journal = "Proceeding - XXIII YuCorr International Conference", title = "Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys", volume = "23", pages = "43-51", url = "https://hdl.handle.net/21.15107/rcub_cer_5436" }
Radojković, B. M., Marunkić, D. D., Pejić, J. N., Milošević, M. D., Jegdić, B.,& Marinković, A. D.. (2022). Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys. in Proceeding - XXIII YuCorr International Conference Belgrade, Serbia : Serbian Society of Corrosion and Materials Protection (Uiskozam)., 23, 43-51. https://hdl.handle.net/21.15107/rcub_cer_5436
Radojković BM, Marunkić DD, Pejić JN, Milošević MD, Jegdić B, Marinković AD. Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys. in Proceeding - XXIII YuCorr International Conference. 2022;23:43-51. https://hdl.handle.net/21.15107/rcub_cer_5436 .
Radojković, Bojana M., Marunkić, Dunja D., Pejić, Jovanka N., Milošević, Milena D., Jegdić, Bore, Marinković, Aleksandar D., "Ecologically friendly corrosion inhibitor for low alloy steels and aluminium alloys" in Proceeding - XXIII YuCorr International Conference, 23 (2022):43-51, https://hdl.handle.net/21.15107/rcub_cer_5436 .