Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries
Само за регистроване кориснике
2021
Аутори
Senćanski, JelenaNikolić, Nenad
Nedić, Zoran
Maksimović, Jelena
Blagojević, Stevan
Pagnacco, Maja
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an
examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of
lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,
and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous
solution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially used
transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”
development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)
compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the... electrochemical behavior of
purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.
Кључне речи:
Natural Pigment from Madder Plant / Eco-Friendly Cathode Material / Aqueous Li and Na-Ion BatteriesИзвор:
Journal of Electrochemical Society, 2021, 168, 10, 100535-Издавач:
- IOP Publishing
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200051 (Институт за општу и физичку хемију, Београд) (RS-MESTD-inst-2020-200051)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200053 (Универзитет у Београду, Институт за мултидисциплинарна истраживања) (RS-MESTD-inst-2020-200053)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200146 (Универзитет у Београду, Факултет за физичку хемију) (RS-MESTD-inst-2020-200146)
Напомена:
- The peer-reviewed version: https://cer.ihtm.bg.ac.rs/handle/123456789/4860
Повезане информације:
- Друга верзија
https://cer.ihtm.bg.ac.rs/handle/123456789/4860
DOI: 10.1149/1945-7111/ac3043
ISSN: 1945-7111; 0013-4651
WoS: 000711650500001
Scopus: 2-s2.0-85118880927
Институција/група
IHTMTY - JOUR AU - Senćanski, Jelena AU - Nikolić, Nenad AU - Nedić, Zoran AU - Maksimović, Jelena AU - Blagojević, Stevan AU - Pagnacco, Maja PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4839 AB - Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR, and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous solution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially used transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green” development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1) compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior of purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail. PB - IOP Publishing T2 - Journal of Electrochemical Society T1 - Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries VL - 168 IS - 10 SP - 100535 DO - 10.1149/1945-7111/ac3043 ER -
@article{ author = "Senćanski, Jelena and Nikolić, Nenad and Nedić, Zoran and Maksimović, Jelena and Blagojević, Stevan and Pagnacco, Maja", year = "2021", abstract = "Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides an examination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions of lithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR, and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueous solution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially used transition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green” development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1) compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior of purpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.", publisher = "IOP Publishing", journal = "Journal of Electrochemical Society", title = "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries", volume = "168", number = "10", pages = "100535", doi = "10.1149/1945-7111/ac3043" }
Senćanski, J., Nikolić, N., Nedić, Z., Maksimović, J., Blagojević, S.,& Pagnacco, M.. (2021). Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society IOP Publishing., 168(10), 100535. https://doi.org/10.1149/1945-7111/ac3043
Senćanski J, Nikolić N, Nedić Z, Maksimović J, Blagojević S, Pagnacco M. Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society. 2021;168(10):100535. doi:10.1149/1945-7111/ac3043 .
Senćanski, Jelena, Nikolić, Nenad, Nedić, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of Electrochemical Society, 168, no. 10 (2021):100535, https://doi.org/10.1149/1945-7111/ac3043 . .