A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method
Samo za registrovane korisnike
1990
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The oxidation of formaldehyde on gold has been studied by a rotating disc-ring method. Hydrogen evolved on the disc was possible to detect on the Pt ring electrode. The reaction scheme was proposed, and expressions for the disc and the ring current were evaluated. Experimental results fit well diagnostic criteria for a series scheme of the oxidation of formaldehyde. The partial currents associated with the oxidation of formaldehyde to formate and hydrogen to water have been calculated. The results illustrate the possibility of using the disc-ring method in elucidation of the mechanisms of oxidation of small organic molecules when a proper selection of the ring electrode and its potential is made.
Ključne reči:
oxidation / formaldehide / rotating disc-ring methodIzvor:
Electrochimica Acta, 1990, 35, 4, 725-729Izdavač:
- Elsevier
Finansiranje / projekti:
- The National Science Foundation, Washington, U.S.A.
- The Research Fund of S. R. Serbie, Yugoslavia
- The Yugoslav American Found, NSF 764
Institucija/grupa
IHTMTY - JOUR AU - Avramov Ivić, Milka AU - Anastasijević, Nikola A. AU - Adžić, Radoslav R. PY - 1990 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4731 AB - The oxidation of formaldehyde on gold has been studied by a rotating disc-ring method. Hydrogen evolved on the disc was possible to detect on the Pt ring electrode. The reaction scheme was proposed, and expressions for the disc and the ring current were evaluated. Experimental results fit well diagnostic criteria for a series scheme of the oxidation of formaldehyde. The partial currents associated with the oxidation of formaldehyde to formate and hydrogen to water have been calculated. The results illustrate the possibility of using the disc-ring method in elucidation of the mechanisms of oxidation of small organic molecules when a proper selection of the ring electrode and its potential is made. PB - Elsevier T2 - Electrochimica Acta T1 - A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method VL - 35 IS - 4 SP - 725 EP - 729 DO - 10.1016/0013-4686(90)90006-L ER -
@article{ author = "Avramov Ivić, Milka and Anastasijević, Nikola A. and Adžić, Radoslav R.", year = "1990", abstract = "The oxidation of formaldehyde on gold has been studied by a rotating disc-ring method. Hydrogen evolved on the disc was possible to detect on the Pt ring electrode. The reaction scheme was proposed, and expressions for the disc and the ring current were evaluated. Experimental results fit well diagnostic criteria for a series scheme of the oxidation of formaldehyde. The partial currents associated with the oxidation of formaldehyde to formate and hydrogen to water have been calculated. The results illustrate the possibility of using the disc-ring method in elucidation of the mechanisms of oxidation of small organic molecules when a proper selection of the ring electrode and its potential is made.", publisher = "Elsevier", journal = "Electrochimica Acta", title = "A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method", volume = "35", number = "4", pages = "725-729", doi = "10.1016/0013-4686(90)90006-L" }
Avramov Ivić, M., Anastasijević, N. A.,& Adžić, R. R.. (1990). A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method. in Electrochimica Acta Elsevier., 35(4), 725-729. https://doi.org/10.1016/0013-4686(90)90006-L
Avramov Ivić M, Anastasijević NA, Adžić RR. A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method. in Electrochimica Acta. 1990;35(4):725-729. doi:10.1016/0013-4686(90)90006-L .
Avramov Ivić, Milka, Anastasijević, Nikola A., Adžić, Radoslav R., "A study of the oxidation of formaldehyde on Au(332) by rotating disc-ring method" in Electrochimica Acta, 35, no. 4 (1990):725-729, https://doi.org/10.1016/0013-4686(90)90006-L . .