A Conductometric Study of the Bi-HgI2 System
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The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms.
Ključne reči:
electric conductivity / homogeneous liquid Bi-HgI2 / bismuth / free metal atomsIzvor:
Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 1976, 31, 7, 777-780Izdavač:
- De Gruyter
Institucija/grupa
IHTMTY - JOUR AU - Šušić, Milenko V. AU - Mentus, Slavko PY - 1976 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4708 AB - The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms. PB - De Gruyter T2 - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences T1 - A Conductometric Study of the Bi-HgI2 System VL - 31 IS - 7 SP - 777 EP - 780 DO - 10.1515/zna-1976-0716 ER -
@article{ author = "Šušić, Milenko V. and Mentus, Slavko", year = "1976", abstract = "The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms.", publisher = "De Gruyter", journal = "Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences", title = "A Conductometric Study of the Bi-HgI2 System", volume = "31", number = "7", pages = "777-780", doi = "10.1515/zna-1976-0716" }
Šušić, M. V.,& Mentus, S.. (1976). A Conductometric Study of the Bi-HgI2 System. in Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences De Gruyter., 31(7), 777-780. https://doi.org/10.1515/zna-1976-0716
Šušić MV, Mentus S. A Conductometric Study of the Bi-HgI2 System. in Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1976;31(7):777-780. doi:10.1515/zna-1976-0716 .
Šušić, Milenko V., Mentus, Slavko, "A Conductometric Study of the Bi-HgI2 System" in Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 31, no. 7 (1976):777-780, https://doi.org/10.1515/zna-1976-0716 . .