Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process
Само за регистроване кориснике
1969
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The cathode process of hydrogen evolution in chlorate cells, including possible depolarization, has not been studied to date. High hydrogen polarization at graphite electrodes delayed the industrial application of bipolar cells for more than 80 years. A new method of depolarization has been developed which consists of depositing on the cathode side of a graphite electrode metallic chromium and/or an addition of small amounts of molybdate. The finely divided cathode molybdenum deposit decreases the cathode polarization for the hydrogen evolution reaction (h.e.r.). The Tafel lines obtained on metallized graphite exhibit nearly the same slopes as the ones for the parent metals, but are shifted to more positive values. This represents a further extension of the methods for depolarized hydrogen cathode evolution with metallized graphite (8,9).
Кључне речи:
Chlorate Cell Process / Depolarization of Cathodic Hydrogen Evolution / Bipolar Chlorate Cell Process / HydrogenИзвор:
Journal of Electrochemical Society, 1969, 116, 394-398Издавач:
- IOP Publishing
Институција/група
IHTMTY - JOUR AU - Jakšić, M.M. AU - Nikolić, B.Z. AU - Karanović, D.M. AU - Milovanović, C.R. PY - 1969 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4633 AB - The cathode process of hydrogen evolution in chlorate cells, including possible depolarization, has not been studied to date. High hydrogen polarization at graphite electrodes delayed the industrial application of bipolar cells for more than 80 years. A new method of depolarization has been developed which consists of depositing on the cathode side of a graphite electrode metallic chromium and/or an addition of small amounts of molybdate. The finely divided cathode molybdenum deposit decreases the cathode polarization for the hydrogen evolution reaction (h.e.r.). The Tafel lines obtained on metallized graphite exhibit nearly the same slopes as the ones for the parent metals, but are shifted to more positive values. This represents a further extension of the methods for depolarized hydrogen cathode evolution with metallized graphite (8,9). PB - IOP Publishing T2 - Journal of Electrochemical Society T1 - Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process VL - 116 SP - 394 EP - 398 DO - 10.1149/1.2411856 ER -
@article{ author = "Jakšić, M.M. and Nikolić, B.Z. and Karanović, D.M. and Milovanović, C.R.", year = "1969", abstract = "The cathode process of hydrogen evolution in chlorate cells, including possible depolarization, has not been studied to date. High hydrogen polarization at graphite electrodes delayed the industrial application of bipolar cells for more than 80 years. A new method of depolarization has been developed which consists of depositing on the cathode side of a graphite electrode metallic chromium and/or an addition of small amounts of molybdate. The finely divided cathode molybdenum deposit decreases the cathode polarization for the hydrogen evolution reaction (h.e.r.). The Tafel lines obtained on metallized graphite exhibit nearly the same slopes as the ones for the parent metals, but are shifted to more positive values. This represents a further extension of the methods for depolarized hydrogen cathode evolution with metallized graphite (8,9).", publisher = "IOP Publishing", journal = "Journal of Electrochemical Society", title = "Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process", volume = "116", pages = "394-398", doi = "10.1149/1.2411856" }
Jakšić, M.M., Nikolić, B.Z., Karanović, D.M.,& Milovanović, C.R.. (1969). Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process. in Journal of Electrochemical Society IOP Publishing., 116, 394-398. https://doi.org/10.1149/1.2411856
Jakšić M, Nikolić B, Karanović D, Milovanović C. Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process. in Journal of Electrochemical Society. 1969;116:394-398. doi:10.1149/1.2411856 .
Jakšić, M.M., Nikolić, B.Z., Karanović, D.M., Milovanović, C.R., "Studies on Chlorate Cell Process: III . Depolarization of Cathodic Hydrogen Evolution in the Bipolar Chlorate Cell Process" in Journal of Electrochemical Society, 116 (1969):394-398, https://doi.org/10.1149/1.2411856 . .