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Photochemically induced oxidation of some steroidal isoxazolidines by molecular oxygen

dc.creatorLorenc, Ljubinka B.
dc.creatorJuranić, Ivan O.
dc.creatorMihailović, Milhailo Lj.
dc.date.accessioned2021-05-12T07:59:47Z
dc.date.available2021-05-12T07:59:47Z
dc.date.issued1977
dc.identifier.issn0022-4936
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4598
dc.description.abstractU.v. irradiation of the steroidal isoxazolidines 5α,10α-imino- oxy-5(10 → 1βH)abeo-5α-cholestan-3β-olacetate (1a) and the corresponding N-methyl and N-acetyl derivatives (1b) and (1c) in various solvents in the presence of oxygen, gave the nitro products (2), (3), and (4) and the azoxy products (5) and (6); a mechanism involving exciplex formation followed by proton transfer from isoxazolidine to molecular oxygen is proposed.sr
dc.language.isoensr
dc.publisherRoyal Society of Chemistrysr
dc.relationThe Research Fund of SR Serbia, Yugoslaviasr
dc.relationThe Serbian Academy of Sciences and Artssr
dc.rightsrestrictedAccesssr
dc.sourceJournal of the Chemical Society, Chemical Communicationssr
dc.subjectoxidationsr
dc.subjectsteroidal isoxazolidinessr
dc.subjectoxigensr
dc.subjectmolecular oxygensr
dc.subjectnitro productssr
dc.subjectU.V. irradiationsr
dc.subjectacetonesr
dc.subjectdiohansr
dc.subjectayoxysr
dc.subjectphoto- oxygenationsr
dc.subjectphotochemically induced oxidationsr
dc.titlePhotochemically induced oxidation of some steroidal isoxazolidines by molecular oxygensr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМихаиловић, Михаило Љ.; Лоренц, Љубинка Б.; Јуранић, Иван О.;
dc.citation.issue21
dc.citation.spage749
dc.citation.epage751
dc.identifier.doi10.1039/C39770000749
dc.identifier.scopus2-s2.0-37049110591
dc.type.versionpublishedVersionsr


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