ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
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1991
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Metapodaci
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Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.
Ključne reči:
phase composition / Cu + Sn alloys / graphite / voltammograms / electrochemistry / alloyIzvor:
Journal of Electroanalytical Chemistry, 1991, 310, 1-2, 391-401Izdavač:
- Elsevier
Finansiranje / projekti:
- The Research Fund of Serbia
Institucija/grupa
IHTMTY - JOUR AU - Skibina, Lj M. AU - Stevanović, Jasmina S. AU - Despić, Aleksandar R. PY - 1991 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4389 AB - Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - ALSV investigation of the phase composition of electrolytic Cu + Sn alloys VL - 310 IS - 1-2 SP - 391 EP - 401 DO - 10.1016/0022-0728(91)85274-S ER -
@article{ author = "Skibina, Lj M. and Stevanović, Jasmina S. and Despić, Aleksandar R.", year = "1991", abstract = "Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, appearing in the ALSVs of all samples, could be ascribed both to pure Cu (in the deposit obtained at low cathodic polarization) and to the η-Cu6Sn5 phase, while one of the other two peaks appearing only in the samples obtained at low cathodic polarization should reflect the presence of the ε{lunate}-Cu3Sn phase. The other peak, appearing only in the samples obtained at high cathodic polarization, is likely to reflect the presence of the tin-rich β-solid solution. The phase composition, in terms of the content of different phases, was determined as a function of the thickness of the alloy as well as of the deposition potential.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys", volume = "310", number = "1-2", pages = "391-401", doi = "10.1016/0022-0728(91)85274-S" }
Skibina, L. M., Stevanović, J. S.,& Despić, A. R.. (1991). ALSV investigation of the phase composition of electrolytic Cu + Sn alloys. in Journal of Electroanalytical Chemistry Elsevier., 310(1-2), 391-401. https://doi.org/10.1016/0022-0728(91)85274-S
Skibina LM, Stevanović JS, Despić AR. ALSV investigation of the phase composition of electrolytic Cu + Sn alloys. in Journal of Electroanalytical Chemistry. 1991;310(1-2):391-401. doi:10.1016/0022-0728(91)85274-S .
Skibina, Lj M., Stevanović, Jasmina S., Despić, Aleksandar R., "ALSV investigation of the phase composition of electrolytic Cu + Sn alloys" in Journal of Electroanalytical Chemistry, 310, no. 1-2 (1991):391-401, https://doi.org/10.1016/0022-0728(91)85274-S . .