Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands
Abstract
The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography.
Keywords:
Chelates / Coordination chemistry / Crystal structure / EDTA ligands / Palladium complexes / X-ray diffractionSource:
Collection of Czechoslovak Chemical Communications, 2007, 72, 4, 560-568Publisher:
- Ceska Republika : Akademie Ved Ceske Republiky
DOI: 10.1135/cccc20070560
ISSN: 0010-0765; 1212-6950
WoS: 000246602000009
Scopus: 2-s2.0-34347334355
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IHTMTY - JOUR AU - Kaluđerović, Goran N. AU - Schmidt, Harry AU - Wagner, Christoph AU - Merzweiler, Kurt AU - Steinborn, Dirk PY - 2007 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4304 AB - The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography. PB - Ceska Republika : Akademie Ved Ceske Republiky T2 - Collection of Czechoslovak Chemical Communications T1 - Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands VL - 72 IS - 4 SP - 560 EP - 568 DO - 10.1135/cccc20070560 ER -
@article{ author = "Kaluđerović, Goran N. and Schmidt, Harry and Wagner, Christoph and Merzweiler, Kurt and Steinborn, Dirk", year = "2007", abstract = "The reaction of solutions of tetraalkyl ethylenediamine-N,N,N′, N′-tetraacetate esters (alkyl = Me, 1a; Et, 1b) with H 2[PdCl4] led to the complexes [PdCl2(R 4EDTA)] (R = Me, 2a; Et, 2b). The coordination of R4EDTA ligands to palladium(II) ions occurs through the two nitrogen donor atoms, as confirmed by IR, 1H and 13C NMR spectroscopies and X-ray crystallography.", publisher = "Ceska Republika : Akademie Ved Ceske Republiky", journal = "Collection of Czechoslovak Chemical Communications", title = "Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands", volume = "72", number = "4", pages = "560-568", doi = "10.1135/cccc20070560" }
Kaluđerović, G. N., Schmidt, H., Wagner, C., Merzweiler, K.,& Steinborn, D.. (2007). Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands. in Collection of Czechoslovak Chemical Communications Ceska Republika : Akademie Ved Ceske Republiky., 72(4), 560-568. https://doi.org/10.1135/cccc20070560
Kaluđerović GN, Schmidt H, Wagner C, Merzweiler K, Steinborn D. Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands. in Collection of Czechoslovak Chemical Communications. 2007;72(4):560-568. doi:10.1135/cccc20070560 .
Kaluđerović, Goran N., Schmidt, Harry, Wagner, Christoph, Merzweiler, Kurt, Steinborn, Dirk, "Synthesis, characterization and crystal structure of palladium(II) complexes containing edta tetraalkyl ester ligands" in Collection of Czechoslovak Chemical Communications, 72, no. 4 (2007):560-568, https://doi.org/10.1135/cccc20070560 . .