Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions
Authorized Users Only
2007
Authors
Rychlewska, UrszulaWarzajtis, Beata
Cvetić, Danica
Radanović, Dušanka
Gurešić, Dejan
Đuran, Miloš
Article (Published version)
Metadata
Show full item recordAbstract
The ability of Mn(II) ion to form two distinctly different complexes with 1,3-propanediaminetetraacetate (1,3-pdta) ligand has been demonstrated by performing X-ray analyses of their crystalline Mg(II) salts. The two types of Mn(II) complexes have been obtained by different synthetic routes and their crystals constitute, respectively, the solid solution of the composition [Mg(H2O)6][Mg0.5Mn0.5(1,3-pd ta)] • 2H2O (1) and the ordered crystals of the composition [Mg(H2O)6][Mn(1,3-pdta)(H2O)] • 2H2O (2). In both, six- 1 and seven-coordinated 2 Mn(II) complexes the 1,3-pdta ligand acts as a hexadentate. As 2 makes the second example of the seven-coordinated 1,3-pdta complex with divalent transition metal ion, the other being the [Mg(H2O)6][Cd(1,3-pdta)(H2O)] • 2H2O (3) complex, the paper reports the results of X-ray investigations of both of these complexes at 130 K.
Keywords:
1,3-pdta Complexes / Isomorphism / Mixed crystals / Solid solutionsSource:
Polyhedron, 2007, 26, 8, 1717-1724Publisher:
- Elsevier
Funding / projects:
- The Polish Ministry of Education and Science Grant 4T09A18525
- Struktura novih kompleksa jona prelaznih metala i mehanizam njihovih reakcija sa biološki značajnim ligandima (RS-MESTD-MPN2006-2010-142008)
DOI: 10.1016/j.poly.2006.12.011
ISSN: 0277-5387
WoS: 000246744600022
Scopus: 2-s2.0-34247500863
Collections
Institution/Community
IHTMTY - JOUR AU - Rychlewska, Urszula AU - Warzajtis, Beata AU - Cvetić, Danica AU - Radanović, Dušanka AU - Gurešić, Dejan AU - Đuran, Miloš PY - 2007 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4254 AB - The ability of Mn(II) ion to form two distinctly different complexes with 1,3-propanediaminetetraacetate (1,3-pdta) ligand has been demonstrated by performing X-ray analyses of their crystalline Mg(II) salts. The two types of Mn(II) complexes have been obtained by different synthetic routes and their crystals constitute, respectively, the solid solution of the composition [Mg(H2O)6][Mg0.5Mn0.5(1,3-pd ta)] • 2H2O (1) and the ordered crystals of the composition [Mg(H2O)6][Mn(1,3-pdta)(H2O)] • 2H2O (2). In both, six- 1 and seven-coordinated 2 Mn(II) complexes the 1,3-pdta ligand acts as a hexadentate. As 2 makes the second example of the seven-coordinated 1,3-pdta complex with divalent transition metal ion, the other being the [Mg(H2O)6][Cd(1,3-pdta)(H2O)] • 2H2O (3) complex, the paper reports the results of X-ray investigations of both of these complexes at 130 K. PB - Elsevier T2 - Polyhedron T1 - Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions VL - 26 IS - 8 SP - 1717 EP - 1724 DO - 10.1016/j.poly.2006.12.011 ER -
@article{ author = "Rychlewska, Urszula and Warzajtis, Beata and Cvetić, Danica and Radanović, Dušanka and Gurešić, Dejan and Đuran, Miloš", year = "2007", abstract = "The ability of Mn(II) ion to form two distinctly different complexes with 1,3-propanediaminetetraacetate (1,3-pdta) ligand has been demonstrated by performing X-ray analyses of their crystalline Mg(II) salts. The two types of Mn(II) complexes have been obtained by different synthetic routes and their crystals constitute, respectively, the solid solution of the composition [Mg(H2O)6][Mg0.5Mn0.5(1,3-pd ta)] • 2H2O (1) and the ordered crystals of the composition [Mg(H2O)6][Mn(1,3-pdta)(H2O)] • 2H2O (2). In both, six- 1 and seven-coordinated 2 Mn(II) complexes the 1,3-pdta ligand acts as a hexadentate. As 2 makes the second example of the seven-coordinated 1,3-pdta complex with divalent transition metal ion, the other being the [Mg(H2O)6][Cd(1,3-pdta)(H2O)] • 2H2O (3) complex, the paper reports the results of X-ray investigations of both of these complexes at 130 K.", publisher = "Elsevier", journal = "Polyhedron", title = "Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions", volume = "26", number = "8", pages = "1717-1724", doi = "10.1016/j.poly.2006.12.011" }
Rychlewska, U., Warzajtis, B., Cvetić, D., Radanović, D., Gurešić, D.,& Đuran, M.. (2007). Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions. in Polyhedron Elsevier., 26(8), 1717-1724. https://doi.org/10.1016/j.poly.2006.12.011
Rychlewska U, Warzajtis B, Cvetić D, Radanović D, Gurešić D, Đuran M. Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions. in Polyhedron. 2007;26(8):1717-1724. doi:10.1016/j.poly.2006.12.011 .
Rychlewska, Urszula, Warzajtis, Beata, Cvetić, Danica, Radanović, Dušanka, Gurešić, Dejan, Đuran, Miloš, "Two distinct manganese(II) complexes with hexadentate 1,3-propanediaminetetraacetate ligand: The ability of metal(II) complexes with 1,3-pdta ligand to form solid solutions" in Polyhedron, 26, no. 8 (2007):1717-1724, https://doi.org/10.1016/j.poly.2006.12.011 . .