Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties
Само за регистроване кориснике
2019
Аутори
Marković, Maja D.Spasojević, Pavle
Šešlija, Sanja
Popović, Ivanka G.
Veljović, Đorđe
Pjanović, Rada
Panić, Vesna
Чланак у часопису (Објављена верзија)
,
Elsevier BV
Метаподаци
Приказ свих података о документуАпстракт
The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through th...e change of one synthesis parameter was thereby demonstrated.
Кључне речи:
Casein / Hybrid polymer network / Poly(methacrylic acid) / Synthesis-structure-properties relationshipИзвор:
European Polymer Journal, 2019, 113, 276-288Издавач:
- Elsevier
Финансирање / пројекти:
- Синтеза и карактеризација нових функционалних полимера и полимерних нанокомпозита (RS-172062)
- Развој нових инкапсулационих и ензимских технологија за производњу биокатализатора и биолошки активних компонената хране у циљу повећања њене конкурентности, квалитета и безбедности (RS-46010)
DOI: 10.1016/j.eurpolymj.2019.01.065
ISSN: 00143057
WoS: 000463979200032
Scopus: 2-s2.0-85060975410
Институција/група
IHTMTY - JOUR AU - Marković, Maja D. AU - Spasojević, Pavle AU - Šešlija, Sanja AU - Popović, Ivanka G. AU - Veljović, Đorđe AU - Pjanović, Rada AU - Panić, Vesna PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2990 AB - The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated. PB - Elsevier T2 - European Polymer Journal T1 - Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties VL - 113 SP - 276 EP - 288 DO - 10.1016/j.eurpolymj.2019.01.065 ER -
@article{ author = "Marković, Maja D. and Spasojević, Pavle and Šešlija, Sanja and Popović, Ivanka G. and Veljović, Đorđe and Pjanović, Rada and Panić, Vesna", year = "2019", abstract = "The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.", publisher = "Elsevier", journal = "European Polymer Journal", title = "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties", volume = "113", pages = "276-288", doi = "10.1016/j.eurpolymj.2019.01.065" }
Marković, M. D., Spasojević, P., Šešlija, S., Popović, I. G., Veljović, Đ., Pjanović, R.,& Panić, V.. (2019). Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal Elsevier., 113, 276-288. https://doi.org/10.1016/j.eurpolymj.2019.01.065
Marković MD, Spasojević P, Šešlija S, Popović IG, Veljović Đ, Pjanović R, Panić V. Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal. 2019;113:276-288. doi:10.1016/j.eurpolymj.2019.01.065 .
Marković, Maja D., Spasojević, Pavle, Šešlija, Sanja, Popović, Ivanka G., Veljović, Đorđe, Pjanović, Rada, Panić, Vesna, "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties" in European Polymer Journal, 113 (2019):276-288, https://doi.org/10.1016/j.eurpolymj.2019.01.065 . .