Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin
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The inclusion complexes of the selected, potentially biologically active, succinimides with β-cyclodextrin (βCD) and
(2-hydroxypropyl)-β-cyclodextrin (HPβCD) were prepared. the formation of the inclusion complexes of the investigated
monophenyl and diphenyl succinimide derivatives was confirmed using attenuated total reflection (ATR) study. Their
electrochemical behavior was examined by cyclic voltammetry (CV) and square wave voltammetry (SWV) in 0.05 M
NaHCO3 on a gold electrode. The stability constants for compound 1 were determined by cyclic voltammetry and calculated
as KβCD = 350.87 M–1 and KHPβCD = 250.67 M–1. The SWV measurements reveal well defined peak at potential Ep =
~ 60 mV and the higher currents at Ep for both inclusion complex of the succinimides compared to the free compounds.
The impact of chlorine atom in the phenyl moiety of succinimide derivatives on the activity in electrooxidation reaction
is presented. Among the studied succinimides, according to SWV mea...surements, the most active is the monophenyl
succinimide derivative (compound 1) in complex with βCD. The difference of peak current of compound 1 + βCD compared
to compound 1 + HPβCD and free compound is 6.3 and 35.2 μA cm–2, respectively.
Keywords:
Diphenylsuccinimide / threephenylsuccinimide / ATR analysis / inclusion complexes / voltammetrySource:
Acta Chimica Slovenica, 2019, 66, 182-189Publisher:
- Ljubljana : Slovenian Chemical Society
Funding / projects:
- Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)
- New approach in designing materials for energy conversion and energy storage systems (RS-172060)
DOI: 10.17344/acsi.2018.4767
ISSN: 1580-3155
WoS: 000459347100023
Scopus: 2-s2.0-85062351811
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IHTMTY - JOUR AU - Lović, Jelena AU - Avramov Ivić, Milka AU - Božić, Bojan AU - Lađarević, Jelena AU - Mijin, Dušan PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2874 AB - The inclusion complexes of the selected, potentially biologically active, succinimides with β-cyclodextrin (βCD) and (2-hydroxypropyl)-β-cyclodextrin (HPβCD) were prepared. the formation of the inclusion complexes of the investigated monophenyl and diphenyl succinimide derivatives was confirmed using attenuated total reflection (ATR) study. Their electrochemical behavior was examined by cyclic voltammetry (CV) and square wave voltammetry (SWV) in 0.05 M NaHCO3 on a gold electrode. The stability constants for compound 1 were determined by cyclic voltammetry and calculated as KβCD = 350.87 M–1 and KHPβCD = 250.67 M–1. The SWV measurements reveal well defined peak at potential Ep = ~ 60 mV and the higher currents at Ep for both inclusion complex of the succinimides compared to the free compounds. The impact of chlorine atom in the phenyl moiety of succinimide derivatives on the activity in electrooxidation reaction is presented. Among the studied succinimides, according to SWV measurements, the most active is the monophenyl succinimide derivative (compound 1) in complex with βCD. The difference of peak current of compound 1 + βCD compared to compound 1 + HPβCD and free compound is 6.3 and 35.2 μA cm–2, respectively. PB - Ljubljana : Slovenian Chemical Society T2 - Acta Chimica Slovenica T1 - Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin VL - 66 SP - 182 EP - 189 DO - 10.17344/acsi.2018.4767 ER -
@article{ author = "Lović, Jelena and Avramov Ivić, Milka and Božić, Bojan and Lađarević, Jelena and Mijin, Dušan", year = "2019", abstract = "The inclusion complexes of the selected, potentially biologically active, succinimides with β-cyclodextrin (βCD) and (2-hydroxypropyl)-β-cyclodextrin (HPβCD) were prepared. the formation of the inclusion complexes of the investigated monophenyl and diphenyl succinimide derivatives was confirmed using attenuated total reflection (ATR) study. Their electrochemical behavior was examined by cyclic voltammetry (CV) and square wave voltammetry (SWV) in 0.05 M NaHCO3 on a gold electrode. The stability constants for compound 1 were determined by cyclic voltammetry and calculated as KβCD = 350.87 M–1 and KHPβCD = 250.67 M–1. The SWV measurements reveal well defined peak at potential Ep = ~ 60 mV and the higher currents at Ep for both inclusion complex of the succinimides compared to the free compounds. The impact of chlorine atom in the phenyl moiety of succinimide derivatives on the activity in electrooxidation reaction is presented. Among the studied succinimides, according to SWV measurements, the most active is the monophenyl succinimide derivative (compound 1) in complex with βCD. The difference of peak current of compound 1 + βCD compared to compound 1 + HPβCD and free compound is 6.3 and 35.2 μA cm–2, respectively.", publisher = "Ljubljana : Slovenian Chemical Society", journal = "Acta Chimica Slovenica", title = "Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin", volume = "66", pages = "182-189", doi = "10.17344/acsi.2018.4767" }
Lović, J., Avramov Ivić, M., Božić, B., Lađarević, J.,& Mijin, D.. (2019). Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin. in Acta Chimica Slovenica Ljubljana : Slovenian Chemical Society., 66, 182-189. https://doi.org/10.17344/acsi.2018.4767
Lović J, Avramov Ivić M, Božić B, Lađarević J, Mijin D. Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin. in Acta Chimica Slovenica. 2019;66:182-189. doi:10.17344/acsi.2018.4767 .
Lović, Jelena, Avramov Ivić, Milka, Božić, Bojan, Lađarević, Jelena, Mijin, Dušan, "Voltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrin" in Acta Chimica Slovenica, 66 (2019):182-189, https://doi.org/10.17344/acsi.2018.4767 . .