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In vitro antitumor activity, metal uptake and reactivity with ascorbic acid and BSA of some gold(III) complexes with N,N′-ethylenediamine bidentate ester ligands
(Elsevier, 2017)
Four novel gold(III) complexes of general formulae [AuCl2{(S,S)-R(2)eddl}]PF6 (R(2)eddl = O,O'-dialkyl-(S,S)-ethylenediamine-N,N'-di-2-(4-methyl)pentanoate, R= n-Pr, n-Bu, n-Pe, i-Bu; 1-4, respectively), were synthesized ...
Periodic Operation with Modulation of Inlet Concentration and Flow Rate Part I: Nonisothermal Continuous Stirred-Tank Reactor
(Wiley, 2016)
The nonlinear frequency response (NFR) method, which is an analytical, fast, and easy method for evaluating the performance of forced periodically operated chemical reactors, was used to investigate possible improvements ...
An ab initio study of SbH2 and BiH2: The Renner effect, spin-orbit coupling, local mode vibrations and rovibronic energy level clustering in SbH2
(Academic Press Inc Elsevier Science, San Diego, 2016)
We present the results of ab initio calculations for the lower electronic states of the Group 15 (pnictogen) dihydrides, SbH2 and BiH2. For each of these molecules the two lowest electronic states become degenerate at ...
Cell cycle, apoptosis, cellular uptake and whole-transcriptome microarray gene expression analysis of HeLa cells treated with a ruthenium(II)-arene complex with an isoquinoline-3-carboxylic acid ligand
(Elsevier, 2016)
Ruthenium(II)-arene complexes are promising drug candidates for the therapy of solid tumors. In previous work, seven new compounds of the general formula [Ru(eta(6)-p-cymene)(L1-7)Cl] were synthesized and characterized, ...
Influence of annealing temperature on sensitisation behaviour and corrosion properties of an Al-6.8wt% Mg alloy
(Wiley, 2016)
Influence of annealing temperature on beta-(Al3Mg2) phase precipitation and corrosion properties of sensitised Al-6.8wt% Mg alloy is investigated. Sensitisation of specimens annealed at 320 degrees C results in IGC and SCC ...
Novel 1,3,4-thiadiazole-chalcone hybrids containing catechol moiety: synthesis, antioxidant activity, cytotoxicity and DNA interaction studies
(Royal Soc Chemistry, Cambridge, 2018)
Hybrid compounds that combine the 1,3,4-thiadiazole-containing catechol moiety with a chalcone motif were synthesized and examined for their antioxidant activity, cytotoxicity, and DNA-binding activity. A series of thirteen ...
Boron-doped diamond electrode - A prestigious unmodified carbon electrode for simple and fast determination of bentazone in river water samples
(Elsevier Science Sa, Lausanne, 2018)
Bentazone (BZ) is selective contact-past herbicide with suspected reproductive toxicity potential for human due to possible contamination of ground and surface waters. This work presents simple, rapid, sensitive and accurate ...
Structural and vibrational analyses of new potential anticancer drug 2-(phenylmethyl)-2-azaspiro[5.11]heptadecane-1,3,7-trione
(Elsevier, 2017)
The establishment of the most stable structures of 2-(phenylmethyl)-2-azaspiro[5.11]heptadecane-1,3,7-trione, potential anticancer and antimicrobial drug has been investigated in this work. A detailed interpretation of ...
Tautomerism of 4-phenyl-2,4-dioxobutanoic acid. Insights from pH ramping NMR study and quantum chemical calculations
(Springer/Plenum Publishers, New York, 2018)
Aryldiketo acids (ADKs) exhibit the variety of biological activities, mainly due to large affinity toward divalent metal ions. Metal complexation ability of ADKs, as well as interactions with proteins, depend on tautomeric ...
Experimental and theoretical study on the structure-property relationship of novel 1-aryl-3-methylsuccinimides
(Elsevier, 2017)
A series of ten 1-aryl-3-methylsuccinimides was synthesized and their solvatochromic properties were studied in a set of fifteen binary solvent mixtures. The solute-solvent interactions were analyzed on the basis of the ...