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Debromination of endo-(+)-3-Bromocamphor with Primary Amines
dc.creator | Marković, Svetlana | |
dc.creator | Markovic, Violeta | |
dc.creator | Joksovic, Milan D. | |
dc.creator | Todorović, Nina | |
dc.creator | Joksovic, Ljubinka | |
dc.creator | Divjakovic, Vladimir | |
dc.creator | Trifunović, Snežana | |
dc.date.accessioned | 2019-01-30T17:35:03Z | |
dc.date.available | 2019-01-30T17:35:03Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0103-5053 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1222 | |
dc.description.abstract | Reductive debromination of endo-(+)-3-bromocamphor with different primary amines followed by imine formation was investigated. This reaction requires simple experimental procedure without any organic solvent, metal or conventional reducing agent. A strong influence of amine polarity on the efficacy of debromination process was observed, and ethanolamine and ethylene diamine having sufficiently high boiling points can debrominate 3-bromocamphor giving corresponding camphanimines in good isolated yields. The mechanisms of debromination of 3-bromocamphor with ethanolamine and n-hexylamine were investigated at the B3LYP/6-311+G(d,p) level of theory. The radical mechanism was revealed, and it was shown that the reaction with more polar ethanolamine is energetically more favorable. | en |
dc.publisher | Soc Brasileira Quimica, Sao Paulo | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172016/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Journal of the Brazilian Chemical Society | |
dc.subject | 3-bromocamphor | en |
dc.subject | primary amines | en |
dc.subject | reductive debromination | en |
dc.subject | reaction mechanism | en |
dc.subject | DFT | en |
dc.title | Debromination of endo-(+)-3-Bromocamphor with Primary Amines | en |
dc.type | article | |
dc.rights.license | BY | |
dcterms.abstract | Тодоровић, Нина; Марковиц, Виолета; Трифуновиц, Снезана; Јоксовиц, Љубинка; Марковић, Светлана; Дивјаковиц, Владимир; Јоксовиц, Милан Д.; | |
dc.citation.volume | 24 | |
dc.citation.issue | 7 | |
dc.citation.spage | 1099 | |
dc.citation.other | 24(7): 1099 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.5935/0103-5053.20130144 | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs//bitstream/id/7737/1220.pdf | |
dc.identifier.scopus | 2-s2.0-84880656725 | |
dc.identifier.wos | 000322727100003 | |
dc.type.version | publishedVersion |