Morphology and composition of Ni-Co electrodeposited powders
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2011
Authors
Maksimović, Vesna M.Lačnjevac, Uroš
Stoiljković, Milovan
Pavlović, Miomir
Jović, Vladimir D.
Article (Published version)
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The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centere...d cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner.
Keywords:
Ni-Co powder / Electrodeposition / MorphologySource:
Materials Characterization, 2011, 62, 12, 1173-1179Publisher:
- Elsevier Science Inc, New York
Funding / projects:
- Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
DOI: 10.1016/j.matchar.2011.09.001
ISSN: 1044-5803
WoS: 000298910800009
Scopus: 2-s2.0-80855139322
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IHTMTY - JOUR AU - Maksimović, Vesna M. AU - Lačnjevac, Uroš AU - Stoiljković, Milovan AU - Pavlović, Miomir AU - Jović, Vladimir D. PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/836 AB - The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner. PB - Elsevier Science Inc, New York T2 - Materials Characterization T1 - Morphology and composition of Ni-Co electrodeposited powders VL - 62 IS - 12 SP - 1173 EP - 1179 DO - 10.1016/j.matchar.2011.09.001 ER -
@article{ author = "Maksimović, Vesna M. and Lačnjevac, Uroš and Stoiljković, Milovan and Pavlović, Miomir and Jović, Vladimir D.", year = "2011", abstract = "The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of NVCo ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of NVCo ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic alpha-nickel phase and hexagonal close-packed alpha-cobalt phase and minor proportions of face-centered cubic alpha-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner.", publisher = "Elsevier Science Inc, New York", journal = "Materials Characterization", title = "Morphology and composition of Ni-Co electrodeposited powders", volume = "62", number = "12", pages = "1173-1179", doi = "10.1016/j.matchar.2011.09.001" }
Maksimović, V. M., Lačnjevac, U., Stoiljković, M., Pavlović, M.,& Jović, V. D.. (2011). Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization Elsevier Science Inc, New York., 62(12), 1173-1179. https://doi.org/10.1016/j.matchar.2011.09.001
Maksimović VM, Lačnjevac U, Stoiljković M, Pavlović M, Jović VD. Morphology and composition of Ni-Co electrodeposited powders. in Materials Characterization. 2011;62(12):1173-1179. doi:10.1016/j.matchar.2011.09.001 .
Maksimović, Vesna M., Lačnjevac, Uroš, Stoiljković, Milovan, Pavlović, Miomir, Jović, Vladimir D., "Morphology and composition of Ni-Co electrodeposited powders" in Materials Characterization, 62, no. 12 (2011):1173-1179, https://doi.org/10.1016/j.matchar.2011.09.001 . .