Electrocatalytic behavior of nickel impregnated zeolite electrode
Samo za registrovane korisnike
2011
Autori
Mojović, ZoricaBanković, Predrag
Jović-Jovičić, Nataša
Milutinović Nikolić, Aleksandra
Abu Rabi-Stanković, Andjela S.
Jovanović, Dušan M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright
Ključne reči:
Nickel loaded zeolite / Nitrogen adsorption isotherms / Zeolite electrodes / Methanol oxidationIzvor:
International Journal of Hydrogen Energy, 2011, 36, 21, 13343-13351Izdavač:
- Oxford : Pergamon-Elsevier Science Ltd
Finansiranje / projekti:
- Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
DOI: 10.1016/j.ijhydene.2011.07.097
ISSN: 0360-3199
WoS: 000296208800001
Scopus: 2-s2.0-83055194575
Institucija/grupa
IHTMTY - JOUR AU - Mojović, Zorica AU - Banković, Predrag AU - Jović-Jovičić, Nataša AU - Milutinović Nikolić, Aleksandra AU - Abu Rabi-Stanković, Andjela S. AU - Jovanović, Dušan M. PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/810 AB - In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright PB - Oxford : Pergamon-Elsevier Science Ltd T2 - International Journal of Hydrogen Energy T1 - Electrocatalytic behavior of nickel impregnated zeolite electrode VL - 36 IS - 21 SP - 13343 EP - 13351 DO - 10.1016/j.ijhydene.2011.07.097 ER -
@article{ author = "Mojović, Zorica and Banković, Predrag and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Abu Rabi-Stanković, Andjela S. and Jovanović, Dušan M.", year = "2011", abstract = "In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "International Journal of Hydrogen Energy", title = "Electrocatalytic behavior of nickel impregnated zeolite electrode", volume = "36", number = "21", pages = "13343-13351", doi = "10.1016/j.ijhydene.2011.07.097" }
Mojović, Z., Banković, P., Jović-Jovičić, N., Milutinović Nikolić, A., Abu Rabi-Stanković, A. S.,& Jovanović, D. M.. (2011). Electrocatalytic behavior of nickel impregnated zeolite electrode. in International Journal of Hydrogen Energy Oxford : Pergamon-Elsevier Science Ltd., 36(21), 13343-13351. https://doi.org/10.1016/j.ijhydene.2011.07.097
Mojović Z, Banković P, Jović-Jovičić N, Milutinović Nikolić A, Abu Rabi-Stanković AS, Jovanović DM. Electrocatalytic behavior of nickel impregnated zeolite electrode. in International Journal of Hydrogen Energy. 2011;36(21):13343-13351. doi:10.1016/j.ijhydene.2011.07.097 .
Mojović, Zorica, Banković, Predrag, Jović-Jovičić, Nataša, Milutinović Nikolić, Aleksandra, Abu Rabi-Stanković, Andjela S., Jovanović, Dušan M., "Electrocatalytic behavior of nickel impregnated zeolite electrode" in International Journal of Hydrogen Energy, 36, no. 21 (2011):13343-13351, https://doi.org/10.1016/j.ijhydene.2011.07.097 . .