Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode
Samo za registrovane korisnike
2011
Autori
Stanković, DaliborManojlović, Dragan
Roglić, Goran
Kostić Rajačić, Slađana
Anđelković, Ivan
Dojčinović, Biljana
Mutić, Jelena
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The determination of Pb and Cd with a Nafion-modified glassy carbon electrode and Cu-DPABA complex (Cu-DPABA NA/GCE; DPABA is methyl 3,5-bis{bis-[(pyridin-2-yl)methyl]amino}methyl-benzoate) as an alternative electrode for anodic stripping voltammetry was described. Pb and Cd were accumulated in acetate buffer pH 4 at a potential of -1.4 V (vs. Ag/AgCl electrode) for 120 s followed by a DPASV scan from -1.2 to -0.2 V. Under optimum conditions the calibration curves were linear in the range of 4.8 x 10(-9)-5.0 x 10(-5) and 5.0 x 10(-9)-5 x 10(-5) molL(-1) for Pb and Cd, respectively. Detection limits were 1.8 x 10(-9) and 1.2 x 10(-9) mol L(-1) for Pb and Cd, respectively. Different parameters and conditions, such as membrane ingredients, accumulation time, potential and pH value were optimized. A study of interfering substances was also performed. A significant increase in current was achieved at the modified electrode in comparison with the bare glassy carbon electrode. The validation ...of the proposed method was made by Pb and Cd determination in the certified reference material Groundwater CRM 610 (BCR, Community Bureau of Reference, Brussels, Belgium). The electrode was successfully applied for determination of Pb and Cd in river water with a high content of organic contaminants without any pretreatment.
Ključne reči:
Modified electrode / Anodic stripping voltammetry / Lead / Cadmium / NafionIzvor:
Electroanalysis, 2011, 23, 8, 1928-1933Izdavač:
- Wiley-Blackwell, Malden
Finansiranje / projekti:
- Primena unapređenih oksidacionih procesa i nanostrukturisanih oksidnih materijala za uklanjanje zagađivača iz životne sredine, razvoj i optimizacija instrumentalnih tehnika za praćenje efikasnosti (RS-MESTD-Basic Research (BR or ON)-172030)
DOI: 10.1002/elan.201100189
ISSN: 1040-0397
WoS: 000294037300022
Scopus: 2-s2.0-79961078136
Institucija/grupa
IHTMTY - JOUR AU - Stanković, Dalibor AU - Manojlović, Dragan AU - Roglić, Goran AU - Kostić Rajačić, Slađana AU - Anđelković, Ivan AU - Dojčinović, Biljana AU - Mutić, Jelena PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/765 AB - The determination of Pb and Cd with a Nafion-modified glassy carbon electrode and Cu-DPABA complex (Cu-DPABA NA/GCE; DPABA is methyl 3,5-bis{bis-[(pyridin-2-yl)methyl]amino}methyl-benzoate) as an alternative electrode for anodic stripping voltammetry was described. Pb and Cd were accumulated in acetate buffer pH 4 at a potential of -1.4 V (vs. Ag/AgCl electrode) for 120 s followed by a DPASV scan from -1.2 to -0.2 V. Under optimum conditions the calibration curves were linear in the range of 4.8 x 10(-9)-5.0 x 10(-5) and 5.0 x 10(-9)-5 x 10(-5) molL(-1) for Pb and Cd, respectively. Detection limits were 1.8 x 10(-9) and 1.2 x 10(-9) mol L(-1) for Pb and Cd, respectively. Different parameters and conditions, such as membrane ingredients, accumulation time, potential and pH value were optimized. A study of interfering substances was also performed. A significant increase in current was achieved at the modified electrode in comparison with the bare glassy carbon electrode. The validation of the proposed method was made by Pb and Cd determination in the certified reference material Groundwater CRM 610 (BCR, Community Bureau of Reference, Brussels, Belgium). The electrode was successfully applied for determination of Pb and Cd in river water with a high content of organic contaminants without any pretreatment. PB - Wiley-Blackwell, Malden T2 - Electroanalysis T1 - Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode VL - 23 IS - 8 SP - 1928 EP - 1933 DO - 10.1002/elan.201100189 ER -
@article{ author = "Stanković, Dalibor and Manojlović, Dragan and Roglić, Goran and Kostić Rajačić, Slađana and Anđelković, Ivan and Dojčinović, Biljana and Mutić, Jelena", year = "2011", abstract = "The determination of Pb and Cd with a Nafion-modified glassy carbon electrode and Cu-DPABA complex (Cu-DPABA NA/GCE; DPABA is methyl 3,5-bis{bis-[(pyridin-2-yl)methyl]amino}methyl-benzoate) as an alternative electrode for anodic stripping voltammetry was described. Pb and Cd were accumulated in acetate buffer pH 4 at a potential of -1.4 V (vs. Ag/AgCl electrode) for 120 s followed by a DPASV scan from -1.2 to -0.2 V. Under optimum conditions the calibration curves were linear in the range of 4.8 x 10(-9)-5.0 x 10(-5) and 5.0 x 10(-9)-5 x 10(-5) molL(-1) for Pb and Cd, respectively. Detection limits were 1.8 x 10(-9) and 1.2 x 10(-9) mol L(-1) for Pb and Cd, respectively. Different parameters and conditions, such as membrane ingredients, accumulation time, potential and pH value were optimized. A study of interfering substances was also performed. A significant increase in current was achieved at the modified electrode in comparison with the bare glassy carbon electrode. The validation of the proposed method was made by Pb and Cd determination in the certified reference material Groundwater CRM 610 (BCR, Community Bureau of Reference, Brussels, Belgium). The electrode was successfully applied for determination of Pb and Cd in river water with a high content of organic contaminants without any pretreatment.", publisher = "Wiley-Blackwell, Malden", journal = "Electroanalysis", title = "Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode", volume = "23", number = "8", pages = "1928-1933", doi = "10.1002/elan.201100189" }
Stanković, D., Manojlović, D., Roglić, G., Kostić Rajačić, S., Anđelković, I., Dojčinović, B.,& Mutić, J.. (2011). Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode. in Electroanalysis Wiley-Blackwell, Malden., 23(8), 1928-1933. https://doi.org/10.1002/elan.201100189
Stanković D, Manojlović D, Roglić G, Kostić Rajačić S, Anđelković I, Dojčinović B, Mutić J. Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode. in Electroanalysis. 2011;23(8):1928-1933. doi:10.1002/elan.201100189 .
Stanković, Dalibor, Manojlović, Dragan, Roglić, Goran, Kostić Rajačić, Slađana, Anđelković, Ivan, Dojčinović, Biljana, Mutić, Jelena, "Simultaneous Determination of Pb and Cd Traces in Water Samples by Anodic Stripping Voltammetry Using a Modified GC Electrode" in Electroanalysis, 23, no. 8 (2011):1928-1933, https://doi.org/10.1002/elan.201100189 . .