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Phase-structure analysis of brass by anodic linear-sweep voltammetry
dc.creator | Stevanović, Jasmina | |
dc.creator | Skibina, LJ. | |
dc.creator | Stefanović, M. | |
dc.creator | Despić, Aleksandar | |
dc.creator | Jović, Vladimir D. | |
dc.date.accessioned | 2023-11-08T13:59:12Z | |
dc.date.available | 2023-11-08T13:59:12Z | |
dc.date.issued | 1992 | |
dc.identifier.issn | 0021-891X | |
dc.identifier.issn | 1572-8838 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/6832 | |
dc.description.abstract | Anodic linear-sweep voltammetry (ALSV) was applied to electrodeposited alloy layers and to metallurgically obtained Cu−Zn alloys of different composition and structure. Metallurgically obtained samples covered the range of composition in which α, (α+β), β and (β+γ) intermediate phases were detected by X-ray. The ALSV of samples containing less than 30 wt % Zn exhibited a single peak at −0.08 to −0.1 V/SCE before massive dissolution, starting at about −0.05 V/SCE. The presence of the γ-phase gave another peak at a significantly more negative potential (−0.25 to −0.35 V/SCE). The ALSV of electrodeposited alloys were significantly more complex than the former, depending on the deposition potentials, with peaks attributable to pure Zn, to the ε-phase, to the η-phase as well as to the α-phase, present in most cases and dissolving at potentials similar to that of pure Cu. ALSV was shown to be a reliable and practical method for a fast determination of both the composition and the phase structure of electrodeposited brass. | |
dc.publisher | Springer | en |
dc.rights | restrictedAccess | |
dc.source | Journal of Applied Electrochemistry | en |
dc.subject | anodic linear-sweep voltammetry | |
dc.subject | Phase-structure | |
dc.subject | alloys | |
dc.subject | electrodeposition | |
dc.title | Phase-structure analysis of brass by anodic linear-sweep voltammetry | en |
dc.type | article | en |
dc.rights.license | ARR | |
dc.citation.volume | 22 | |
dc.citation.issue | 2 | |
dc.citation.spage | 172 | |
dc.citation.epage | 178 | |
dc.identifier.doi | 10.1007/BF01023820 | |
dc.identifier.scopus | 2-s2.0-0026817837 | |
dc.type.version | publishedVersion |