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Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey

dc.creatorJevtović, Mima
dc.creatorPevec, Andrej
dc.creatorTurel, Iztok
dc.creatorRadanović, Dušanka
dc.creatorMilčić, Miloš
dc.creatorGruden, Maja
dc.creatorZlatar, Matija
dc.creatorMitić, Dragana
dc.creatorAnđelković, Katarina
dc.creatorČobeljić, Božidar
dc.date.accessioned2023-10-18T15:08:04Z
dc.date.available2025-10-17
dc.date.issued2023
dc.identifier.issn1387-7003
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/6766
dc.description.abstractIn this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.
dc.publisherElsevieren
dc.relationinfo:eu-repo/grantAgreement/ScienceFundRS/Ideje/7750288/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS//
dc.relationSlovenian Research Agency (ARRS), grant number P1-0175
dc.relation.isversionofhttps://doi.org/10.1016/j.inoche.2023.111582
dc.relation.isversionofhttps://cer.ihtm.bg.ac.rs/handle/123456789/6788
dc.rightsembargoedAccess
dc.sourceInorganic Chemistry Communicationsen
dc.subjectSchiff base ligands
dc.subjectnickel(II)
dc.subjectnickel(III)
dc.subjectcomplexes
dc.subjectsynthesis
dc.subjectX-ray structure
dc.subjectDFT
dc.subjectsyngle crystal
dc.subjectEPR
dc.titleNickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journeyen
dc.typearticleen
dc.rights.licenseARRen
dc.citation.volume158
dc.citation.spage111582
dc.citation.rankM21~
dc.description.otherThis is the accepted version of the manuscript: M. Jevtović, A. Pevec, I. Turel, D. Radanović, M. Milčić, M. Gruden, M. Zlatar, D. Mitić, K. Anđelković, B. Čobeljić, Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey, Inorganic Chemistry Communications (2023), doi: [https://doi.org/10.1016/j.inoche.2023.111582]
dc.description.otherPublished version: [https://cer.ihtm.bg.ac.rs/handle/123456789/6788]
dc.identifier.doi10.1016/j.inoche.2023.111582
dc.identifier.scopus2-s2.0-85174714656
dc.type.versionacceptedVersion


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