Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media
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2010
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A composite mixture Ag-NaX zeolite (silver concentration 16.7% w/w) is synthesized usingimpregnation and thermal decomposition. For silver impregnation, a solution of an Ag acetylacetonate complex in acetone was used. Despite the quantity of silver applied was substantially less than it would be necessary to fill the inner pore space in the zeolite completely, some part of silver formed nanocrystallites and nanoparticles giving rise to a novel composite material. The composite powder was uniformed with soot (10% w/w) and applied onto a mirror-smooth graphite surface used as an electrode matrix. The reduction of oxygen on such a surface proceeded with activity comparable to that observed on the most active planes of the silver single crystal, Ag(100).
Izvor:
Journal of Analytical Chemistry, 2010, 65, 1, 77-81Izdavač:
- Maik Nauka/Interperiodica/Springer, New York
Finansiranje / projekti:
- Ministry for Science and Environment of Serbia - 6712
- Struktura, termodinamičke i elektrohemijske osobine materijala za konverziju energije i nove tehnologije (RS-142047)
DOI: 10.1134/S1061934810010144
ISSN: 1061-9348
WoS: 000276713700014
Scopus: 2-s2.0-73849131714
Institucija/grupa
IHTMTY - JOUR AU - Mojović, Zorica AU - Iovanovich, L. AU - Mentus, Slavko AU - Iovanovich, D. PY - 2010 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/667 AB - A composite mixture Ag-NaX zeolite (silver concentration 16.7% w/w) is synthesized usingimpregnation and thermal decomposition. For silver impregnation, a solution of an Ag acetylacetonate complex in acetone was used. Despite the quantity of silver applied was substantially less than it would be necessary to fill the inner pore space in the zeolite completely, some part of silver formed nanocrystallites and nanoparticles giving rise to a novel composite material. The composite powder was uniformed with soot (10% w/w) and applied onto a mirror-smooth graphite surface used as an electrode matrix. The reduction of oxygen on such a surface proceeded with activity comparable to that observed on the most active planes of the silver single crystal, Ag(100). PB - Maik Nauka/Interperiodica/Springer, New York T2 - Journal of Analytical Chemistry T1 - Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media VL - 65 IS - 1 SP - 77 EP - 81 DO - 10.1134/S1061934810010144 ER -
@article{ author = "Mojović, Zorica and Iovanovich, L. and Mentus, Slavko and Iovanovich, D.", year = "2010", abstract = "A composite mixture Ag-NaX zeolite (silver concentration 16.7% w/w) is synthesized usingimpregnation and thermal decomposition. For silver impregnation, a solution of an Ag acetylacetonate complex in acetone was used. Despite the quantity of silver applied was substantially less than it would be necessary to fill the inner pore space in the zeolite completely, some part of silver formed nanocrystallites and nanoparticles giving rise to a novel composite material. The composite powder was uniformed with soot (10% w/w) and applied onto a mirror-smooth graphite surface used as an electrode matrix. The reduction of oxygen on such a surface proceeded with activity comparable to that observed on the most active planes of the silver single crystal, Ag(100).", publisher = "Maik Nauka/Interperiodica/Springer, New York", journal = "Journal of Analytical Chemistry", title = "Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media", volume = "65", number = "1", pages = "77-81", doi = "10.1134/S1061934810010144" }
Mojović, Z., Iovanovich, L., Mentus, S.,& Iovanovich, D.. (2010). Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media. in Journal of Analytical Chemistry Maik Nauka/Interperiodica/Springer, New York., 65(1), 77-81. https://doi.org/10.1134/S1061934810010144
Mojović Z, Iovanovich L, Mentus S, Iovanovich D. Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media. in Journal of Analytical Chemistry. 2010;65(1):77-81. doi:10.1134/S1061934810010144 .
Mojović, Zorica, Iovanovich, L., Mentus, Slavko, Iovanovich, D., "Reduction of Oxygen at a NaX-Ag Composite Electrode and Its Application to the Determination of Oxygen in Aqueous Media" in Journal of Analytical Chemistry, 65, no. 1 (2010):77-81, https://doi.org/10.1134/S1061934810010144 . .