Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent
Autori
Savić, MilicaJevtović, Mima
Zlatar, Matija
Gruden, Maja
Mitić, Dragana
Čobeljić, Božidar
Anđelković, Katarina
Konferencijski prilog (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand
with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water
mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The
tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion
through NNO set of donor atoms forming two five-membered chelate rings and the other three
coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was
characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was
defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis.
DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.
Ključne reči:
synthesis / characterization / 2-acetylpyridine / Girard’s P reagent / Ni(III) / DFTIzvor:
Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro, 2023, 114-114Izdavač:
- Belgrade, Serbia : Materials Research Society of Serbia
Finansiranje / projekti:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
Napomena:
- Poster: P.S.40
- Poster: https://cer.ihtm.bg.ac.rs/handle/123456789/6609
Povezane informacije:
- Povezani sadržaj
https://cer.ihtm.bg.ac.rs/handle/123456789/6609
Institucija/grupa
IHTMTY - CONF AU - Savić, Milica AU - Jevtović, Mima AU - Zlatar, Matija AU - Gruden, Maja AU - Mitić, Dragana AU - Čobeljić, Božidar AU - Anđelković, Katarina PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6608 AB - The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex. PB - Belgrade, Serbia : Materials Research Society of Serbia C3 - Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro T1 - Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent SP - 114 EP - 114 UR - https://hdl.handle.net/21.15107/rcub_cer_6608 ER -
@conference{ author = "Savić, Milica and Jevtović, Mima and Zlatar, Matija and Gruden, Maja and Mitić, Dragana and Čobeljić, Božidar and Anđelković, Katarina", year = "2023", abstract = "The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.", publisher = "Belgrade, Serbia : Materials Research Society of Serbia", journal = "Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro", title = "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent", pages = "114-114", url = "https://hdl.handle.net/21.15107/rcub_cer_6608" }
Savić, M., Jevtović, M., Zlatar, M., Gruden, M., Mitić, D., Čobeljić, B.,& Anđelković, K.. (2023). Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro Belgrade, Serbia : Materials Research Society of Serbia., 114-114. https://hdl.handle.net/21.15107/rcub_cer_6608
Savić M, Jevtović M, Zlatar M, Gruden M, Mitić D, Čobeljić B, Anđelković K. Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro. 2023;:114-114. https://hdl.handle.net/21.15107/rcub_cer_6608 .
Savić, Milica, Jevtović, Mima, Zlatar, Matija, Gruden, Maja, Mitić, Dragana, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent" in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro (2023):114-114, https://hdl.handle.net/21.15107/rcub_cer_6608 .