Unexpected Ni(III) complex with hydrazone lignad – spin state analysis
Neočekivani Ni(III) komleks sa hidrazonskim ligandom – analiza spinskih stanja
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
During synthesis of Ni(II) complex with (E)−1-(2-oxo-2-(2-(1-(pyridin-2-
yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium ligand (L) unexpected oxidation of Ni(II) to Ni(III) with atmospheric oxygen occurred at mild conditions. Unusual spin and magnetic properties of the synthesized octahedral [NiL(N3)3] complex, were further investigated with Density Functional Theory (DFT) methods.
Tokom sinteze kompleksa nikla(II) sa tridentatnim I−1-(2-okso-2-(2-(1-(piridin-2-il)etiliden)hydrazinil)etil)piridin-1-ijum ligandom (L) došlo je do neočekivane oksidacije Ni(II) u Ni(III), vazdušnim kiseonikom, pri veoma blagim uslovima. Nastali oktaedarski [NiL(N3)3] kompleks pokazuje veoma zanimljive spinske i magnetne osobine, koje su proučavane metodama teorije funkcionala gustine (DFT).
Кључне речи:
DFT / octahedral complexes / transition metal complexes / synthesis / Ni(II) / Ni(III) / spin states / magnetic properties / spin densityИзвор:
Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia, 2023, 112-112Издавач:
- Belgrade : Serbian Chemical Society / Beograd : Srpsko hemijsko društvo
Финансирање / пројекти:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
Напомена:
Повезане информације:
- Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/6230
Институција/група
IHTMTY - CONF AU - Milčić, Miloš AU - Gruden, Maja AU - Zlatar, Matija PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6210 AB - During synthesis of Ni(II) complex with (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium ligand (L) unexpected oxidation of Ni(II) to Ni(III) with atmospheric oxygen occurred at mild conditions. Unusual spin and magnetic properties of the synthesized octahedral [NiL(N3)3] complex, were further investigated with Density Functional Theory (DFT) methods. AB - Tokom sinteze kompleksa nikla(II) sa tridentatnim I−1-(2-okso-2-(2-(1-(piridin-2-il)etiliden)hydrazinil)etil)piridin-1-ijum ligandom (L) došlo je do neočekivane oksidacije Ni(II) u Ni(III), vazdušnim kiseonikom, pri veoma blagim uslovima. Nastali oktaedarski [NiL(N3)3] kompleks pokazuje veoma zanimljive spinske i magnetne osobine, koje su proučavane metodama teorije funkcionala gustine (DFT). PB - Belgrade : Serbian Chemical Society / Beograd : Srpsko hemijsko društvo C3 - Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia T1 - Unexpected Ni(III) complex with hydrazone lignad – spin state analysis T1 - Neočekivani Ni(III) komleks sa hidrazonskim ligandom – analiza spinskih stanja SP - 112 EP - 112 UR - https://hdl.handle.net/21.15107/rcub_cer_6210 ER -
@conference{ author = "Milčić, Miloš and Gruden, Maja and Zlatar, Matija", year = "2023", abstract = "During synthesis of Ni(II) complex with (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium ligand (L) unexpected oxidation of Ni(II) to Ni(III) with atmospheric oxygen occurred at mild conditions. Unusual spin and magnetic properties of the synthesized octahedral [NiL(N3)3] complex, were further investigated with Density Functional Theory (DFT) methods., Tokom sinteze kompleksa nikla(II) sa tridentatnim I−1-(2-okso-2-(2-(1-(piridin-2-il)etiliden)hydrazinil)etil)piridin-1-ijum ligandom (L) došlo je do neočekivane oksidacije Ni(II) u Ni(III), vazdušnim kiseonikom, pri veoma blagim uslovima. Nastali oktaedarski [NiL(N3)3] kompleks pokazuje veoma zanimljive spinske i magnetne osobine, koje su proučavane metodama teorije funkcionala gustine (DFT).", publisher = "Belgrade : Serbian Chemical Society / Beograd : Srpsko hemijsko društvo", journal = "Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia", title = "Unexpected Ni(III) complex with hydrazone lignad – spin state analysis, Neočekivani Ni(III) komleks sa hidrazonskim ligandom – analiza spinskih stanja", pages = "112-112", url = "https://hdl.handle.net/21.15107/rcub_cer_6210" }
Milčić, M., Gruden, M.,& Zlatar, M.. (2023). Unexpected Ni(III) complex with hydrazone lignad – spin state analysis. in Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia Belgrade : Serbian Chemical Society / Beograd : Srpsko hemijsko društvo., 112-112. https://hdl.handle.net/21.15107/rcub_cer_6210
Milčić M, Gruden M, Zlatar M. Unexpected Ni(III) complex with hydrazone lignad – spin state analysis. in Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia. 2023;:112-112. https://hdl.handle.net/21.15107/rcub_cer_6210 .
Milčić, Miloš, Gruden, Maja, Zlatar, Matija, "Unexpected Ni(III) complex with hydrazone lignad – spin state analysis" in Kratki izvodi radova, knjiga radova - 59. Savetovanje Srpskog hemijskog društva, 1. i 2. jun 2023. godine, Novi Sad / Book of Abstracts, Proceedings - 59th Meeting of the Serbian Chemical Society, June 1-2, 2023, Novi Sad, Serbia (2023):112-112, https://hdl.handle.net/21.15107/rcub_cer_6210 .