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Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity
dc.creator | Filipović, N. | |
dc.creator | Borrmann, H. | |
dc.creator | Todorović, Tamara | |
dc.creator | Borna, M. | |
dc.creator | Spasojević, Vojislav | |
dc.creator | Sladić, Dušan | |
dc.creator | Novaković, Irena | |
dc.creator | Anđelković, Katarina | |
dc.date.accessioned | 2019-01-30T17:20:56Z | |
dc.date.available | 2019-01-30T17:20:56Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/565 | |
dc.description.abstract | Three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine or 2-quinolinecarboxaldehyde with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of all three complexes were determined. Crystallographic data indicate a common basis of the structures with some major differences. Both pyridine derivatives form complexes of the type [CuCl2L] with distorted square-planar geometry around copper(II), but show a decisive difference in the side chain orientation. The quinoline derivative forms a dimeric complex of type [Cu2Cl4L2] with distorted trigonal bipyramidal geometry around copper(II), but a rather short Cu···Cu contact, which is reflected in its magnetic properties. All three complexes showed antibacterial activity. | en |
dc.publisher | Elsevier Science Sa, Lausanne | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142062/RS// | |
dc.rights | restrictedAccess | |
dc.source | Inorganica Chimica Acta | |
dc.subject | Antibacterial activity | en |
dc.subject | Copper(II) complexes | en |
dc.subject | Heteroaromatic hydrazones | en |
dc.subject | X-ray structure analysis | en |
dc.title | Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Боррманн, Х.; Спасојевић, В.; Aнђелковић, Катарина; Сладић, Д.; Филиповић, Н.; Борна, М.; Новаковић, Ирена; Тодоровић, Тамара Р.; | |
dc.citation.volume | 362 | |
dc.citation.issue | 6 | |
dc.citation.spage | 1996 | |
dc.citation.epage | 2000 | |
dc.citation.other | 362(6): 1996-2000 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1016/j.ica.2008.09.019 | |
dc.identifier.scopus | 2-s2.0-64549099782 | |
dc.identifier.wos | 000265299200049 | |
dc.type.version | publishedVersion |