dc.creator | Chung, Dong Young | |
dc.creator | Lopes, Pietro Papa | |
dc.creator | Farinazzo Bergamo Dias Martins, Pedro | |
dc.creator | He, Haiying | |
dc.creator | Kawaguchi, Tomoya | |
dc.creator | Zapol, Peter | |
dc.creator | You, Hoydoo | |
dc.creator | Tripković, Dušan | |
dc.creator | Strmcnik, Dusan | |
dc.creator | Zhu, Yisi | |
dc.creator | Seifert, Soenke | |
dc.creator | Lee, Sungsik | |
dc.creator | Stamenković, Vojislav | |
dc.creator | Marković, Nenad M. | |
dc.date.accessioned | 2020-04-16T14:50:11Z | |
dc.date.available | 2020-04-16T14:50:11Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 2058-7546 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/3485 | |
dc.description.abstract | The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H2 production. Here, by studying the activity–stability trends for the oxygen evolution reaction on conductive M1OxHy, Fe–M1OxHy and Fe–M1M2OxHy hydr(oxy)oxide clusters (M1 = Ni, Co, Fe; M2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe–M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces. | en |
dc.publisher | Springer Science and Business Media LLC | en |
dc.relation | US Department of Energy, Office of Science, Office of Basic Energy Sciences, under contract no. DE-AC02-06CH11357 | en |
dc.rights | restrictedAccess | |
dc.source | Nature Energy | en |
dc.subject | Electrocatalysis | |
dc.subject | Hydrogen fuel | |
dc.subject | Solar fuels | |
dc.title | Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Хе, Хаиyинг; Запол, Петер; Yоу, Хоyдоо; Зху, Yиси; Сеиферт, Соенке; Марковиц, Ненад М.; Стаменковић, Војислав Р.; Стрмцник, Дусан; Трипковић, Душан; Каwагуцхи, Томоyа; Лее, Сунгсик; Цхунг, Донг Yоунг; Лопес, Пиетро П.; Фариназзо Бергамо Диас Мартинс, Педро; | |
dc.rights.holder | Springer Nature | |
dc.citation.volume | 5 | |
dc.citation.issue | 3 | |
dc.citation.spage | 222 | |
dc.citation.epage | 230 | |
dc.citation.rank | aM21~ | |
dc.description.other | The peer-reviewed version: [https://cer.ihtm.bg.ac.rs/handle/123456789/3700] | |
dc.identifier.doi | 10.1038/s41560-020-0576-y | |
dc.identifier.scopus | 2-s2.0-85082113724 | |
dc.identifier.wos | 000520704000014 | |
dc.type.version | publishedVersion | |