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dc.creatorMiladinović, Jelena
dc.creatorNinković, Rozalija
dc.creatorTodorović, Milica
dc.creatorJovanović, Vladislava
dc.date.accessioned2020-04-13T13:51:04Z
dc.date.available2020-04-13T13:51:04Z
dc.date.issued2003
dc.identifier.issn0095-9782
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/3482
dc.description.abstractThe available literature data on the osmotic coefficient of ZnSO4(aq) at 25degreesC in the molality range from 0.1 to 4.3 mol-kg(-1) and new experimental data from 1.2 to 2.9 mol-kg(-1), at the same temperature, are presented. Selected values of the osmotic coefficient from all the data are analyzed using the Clegg-Pitzer-Brimblecombe model, the extended Pitzer model, and a semiempirical equation comprising a power series in molality added to the Debye-Huckel limiting law. The extended Pitzer equation and the Clegg-Pitzer-Brimblecombe equations give the best results in fitting the osmotic coefficient data. All three models are used to calculate ZnSO4 activity coefficients at 25degreesC in dilute solutions (<0.1 mol-kg(-1)) for comparison with published values.sr
dc.language.isoensr
dc.publisherSpringersr
dc.relationThis work was supported by the Ministry for Science, Technology and Development, of the Republic of Serbia under Project No. 1891.sr
dc.rightsrestrictedAccesssr
dc.sourceJournal of Solution Chemistrysr
dc.subjectIsopiestic measurementssr
dc.subjectZinc sulfatesr
dc.subjectOsmotic coefficientsr
dc.subjectActivity coefficientsr
dc.subjectExtended Pitzer modelsr
dc.subjectClegg–Pitzer–Brimblecombe modelsr
dc.subjectSemiemprical equationsr
dc.titleCorrelation of osmotic coefficient data for ZnSO4(aq) at 25 degrees C by various thermodynamic modelssr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМиладиновић, Јелена; Јовановић, Владислава; Тодоровић, Милица; Нинковић, Розалија;
dc.rights.holderSpringersr
dc.citation.volume32
dc.citation.issue4
dc.citation.spage371
dc.citation.epage383
dc.citation.rankM23
dc.identifier.doi10.1023/A:1023710022173
dc.identifier.scopus2-s2.0-0347003388
dc.identifier.wos000182849400006
dc.type.versionpublishedVersionsr


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