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dc.creatorZarić, Milana
dc.creatorRadović, Ivona
dc.creatorKijevčanin, Mirjana
dc.date.accessioned2020-03-10T09:23:42Z
dc.date.available2020-03-10T09:23:42Z
dc.date.issued2020
dc.identifier.issn0167-7322
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3435
dc.description.abstractThermodynamic properties (density, viscosity, refractive index and speed of sound) of pure substances cis-3-hexen-1-ol, 1-hexanol and n-hexane and their binary systems cis-3-hexen-1-ol + n-hexane and 1-hexanol + n-hexane were measured. All measurements are reported in the range (288.15 to 318.15) K at seven temperatures and at atmospheric pressure. Excess molar volume (VE), viscosity deviation (Δη), refractive index deviation (ΔnD) and speed of sound deviation (Δu) were calculated based on the experimental data. Derivate properties were fitted using Redlich-Kister equation. Additionally, for analyzing the molecular interaction, the FT-IR spectroscopy and quantum chemical calculations were performed. The results show differences in viscosity deviation between cis-3-hexen-1-ol + n-hexane and 1-hexanol + n-hexane mixtures, indicating some specific role of double bonds in properties of the mixtures. The FT-IR spectra indicate change in double bond frequency between pure cis-3-hexen-1-ol and mixture of cis-3-hexen-1-ol + n-hexane, and quantum chemical calculations confirmed the possibility of double bond influence on the properties of the mixtures.en
dc.language.isoensr
dc.publisherElseviersr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172063/RS//sr
dc.rightsrestrictedAccesssr
dc.sourceJournal of Molecular Liquidssr
dc.subjectcis-3-Hexen-1-olsr
dc.subjectBinary mixturessr
dc.subjectThermophysical propertiessr
dc.subjectFT-IRsr
dc.subjectQuantum chemical calculationssr
dc.titleIntermolecular interactions of cis-3-hexen-1-ol or 1-hexanol with n-hexane: Thermodynamic study, FT-IR analysis and quantum chemical calculationsen
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractРадовић, Ивона Р.; Кијевчанин, Мирјана Љ.; Зарић, Милана М.;
dc.rights.holderElseviersr
dc.citation.volume303
dc.citation.spage112486
dc.citation.rankM21~
dc.identifier.doi10.1016/j.molliq.2020.112486
dc.identifier.scopus2-s2.0-85078990425
dc.identifier.wos000533612700037
dc.type.versionpublishedVersionsr


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Приказ основних података о документу