Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Аутори
Romanović, MimaČobeljić, Božidar
Pevec, Andrej
Turel, Iztok
Spasojević, Vojislav
Tsaturyan, Arshak A.
Shcherbakov, Igor N.
Anđelković, Katarina
Milenković, Marina
Radanović, Dušanka
Milenković, Milica R.
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документуАпстракт
A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.
Кључне речи:
Ni(II) complex / Hydrazones / DFT / Magnetic properties / Crystal structureИзвор:
Polyhedron, 2017, 128, 30-37Издавач:
- Oxford : Pergamon-Elsevier Science Ltd
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
- COST Action
- Slovenian Research Agency [P-0175]
- SFedU [213.01-07-2014/03PChVG]
Напомена:
- This is per-reviewed version of the article: Polyhedron, 2017, 128, 30-37, https://doi.org/10.1016/j.poly.2017.02.039
- http://cer.ihtm.bg.ac.rs/handle/123456789/2065
DOI: 10.1016/j.poly.2017.02.039
ISSN: 0277-5387
WoS: 000401047100005
Scopus: 2-s2.0-85015629397
Институција/група
IHTMTY - JOUR AU - Romanović, Mima AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Turel, Iztok AU - Spasojević, Vojislav AU - Tsaturyan, Arshak A. AU - Shcherbakov, Igor N. AU - Anđelković, Katarina AU - Milenković, Marina AU - Radanović, Dušanka AU - Milenković, Milica R. PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3013 AB - A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Polyhedron T1 - Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent VL - 128 SP - 30 EP - 37 DO - 10.1016/j.poly.2017.02.039 ER -
@article{ author = "Romanović, Mima and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Tsaturyan, Arshak A. and Shcherbakov, Igor N. and Anđelković, Katarina and Milenković, Marina and Radanović, Dušanka and Milenković, Milica R.", year = "2017", abstract = "A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Polyhedron", title = "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent", volume = "128", pages = "30-37", doi = "10.1016/j.poly.2017.02.039" }
Romanović, M., Čobeljić, B., Pevec, A., Turel, I., Spasojević, V., Tsaturyan, A. A., Shcherbakov, I. N., Anđelković, K., Milenković, M., Radanović, D.,& Milenković, M. R.. (2017). Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron Oxford : Pergamon-Elsevier Science Ltd., 128, 30-37. https://doi.org/10.1016/j.poly.2017.02.039
Romanović M, Čobeljić B, Pevec A, Turel I, Spasojević V, Tsaturyan AA, Shcherbakov IN, Anđelković K, Milenković M, Radanović D, Milenković MR. Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron. 2017;128:30-37. doi:10.1016/j.poly.2017.02.039 .
Romanović, Mima, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Tsaturyan, Arshak A., Shcherbakov, Igor N., Anđelković, Katarina, Milenković, Marina, Radanović, Dušanka, Milenković, Milica R., "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Polyhedron, 128 (2017):30-37, https://doi.org/10.1016/j.poly.2017.02.039 . .