Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties
Authorized Users Only
2019
Authors
Marković, Maja D.Spasojević, Pavle
Šešlija, Sanja
Popović, Ivanka G.
Veljović, Đorđe
Pjanović, Rada
Panić, Vesna
Article (Published version)
,
Elsevier BV
Metadata
Show full item recordAbstract
The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through th...e change of one synthesis parameter was thereby demonstrated.
Keywords:
Casein / Hybrid polymer network / Poly(methacrylic acid) / Synthesis-structure-properties relationshipSource:
European Polymer Journal, 2019, 113, 276-288Publisher:
- Elsevier
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-MESTD-Basic Research (BR or ON)-172062)
- Novel encapsulation and enzyme technologies for designing of new biocatalysts and biologically active compounds targeting enhancement of food quality, safety and competitiveness (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-46010)
DOI: 10.1016/j.eurpolymj.2019.01.065
ISSN: 00143057
WoS: 000463979200032
Scopus: 2-s2.0-85060975410
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Institution/Community
IHTMTY - JOUR AU - Marković, Maja D. AU - Spasojević, Pavle AU - Šešlija, Sanja AU - Popović, Ivanka G. AU - Veljović, Đorđe AU - Pjanović, Rada AU - Panić, Vesna PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2990 AB - The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated. PB - Elsevier T2 - European Polymer Journal T1 - Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties VL - 113 SP - 276 EP - 288 DO - 10.1016/j.eurpolymj.2019.01.065 ER -
@article{ author = "Marković, Maja D. and Spasojević, Pavle and Šešlija, Sanja and Popović, Ivanka G. and Veljović, Đorđe and Pjanović, Rada and Panić, Vesna", year = "2019", abstract = "The design of complex polymeric materials with predefined task-specific properties meets challenging issues: to establish synthesis-structure-properties relationship, as well as to understand the arrangement and interactions of the involved components. Hybrid networks of protein (casein) and polyelectrolyte (poly(methacrylic acid)) were synthesized and their swelling, dynamic-mechanical and morphological properties were investigated as functions of the neutralization degree of methacrylic acid and the concentrations of caseinate and crosslinker. The domination of different interactions between components led to diverse forms of casein macromolecules- from micelles to unfold chains. That resulted in very different structures and thereby properties of derived hybrid networks: from porous unswellable to highly swellable and reinforced ones. A great opportunity to easily modulate the final characteristics of the reported hybrid system to fit the need of specific application just through the change of one synthesis parameter was thereby demonstrated.", publisher = "Elsevier", journal = "European Polymer Journal", title = "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties", volume = "113", pages = "276-288", doi = "10.1016/j.eurpolymj.2019.01.065" }
Marković, M. D., Spasojević, P., Šešlija, S., Popović, I. G., Veljović, Đ., Pjanović, R.,& Panić, V.. (2019). Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal Elsevier., 113, 276-288. https://doi.org/10.1016/j.eurpolymj.2019.01.065
Marković MD, Spasojević P, Šešlija S, Popović IG, Veljović Đ, Pjanović R, Panić V. Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties. in European Polymer Journal. 2019;113:276-288. doi:10.1016/j.eurpolymj.2019.01.065 .
Marković, Maja D., Spasojević, Pavle, Šešlija, Sanja, Popović, Ivanka G., Veljović, Đorđe, Pjanović, Rada, Panić, Vesna, "Casein-poly(methacrylic acid) hybrid soft networks with easy tunable properties" in European Polymer Journal, 113 (2019):276-288, https://doi.org/10.1016/j.eurpolymj.2019.01.065 . .