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dc.creatorDžambaski, Zdravko
dc.creatorTzaras, Dimitrios‐Ioannis
dc.creatorLee, Sunggi
dc.creatorKokotos, Christoforos G.
dc.creatorBondžić, Bojan
dc.date.accessioned2019-06-28T13:11:33Z
dc.date.available2020-02-01
dc.date.issued2019
dc.identifier.issn1615-4150
dc.identifier.issn1615-4169
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2954
dc.description.abstractα,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks.
dc.publisherWileyen
dc.relationCOST action CA15106: CH activation in organic synthesis (CHAOS)en
dc.relationSpecial Account for Research Grants of the National and Kapodistrian University of Athens
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS//
dc.rightsembargoedAccess
dc.sourceAdvanced Synthesis & Catalysisen
dc.subjectAsymmetric catalysis
dc.subjectCycloaddition
dc.subjectC−H oxidation
dc.subjectDiarylprolinols
dc.subjectOrganocatalysis
dc.titleEnantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reactionen
dc.typearticleen
dc.rights.licenseBY-NC-ND
dcterms.abstractКокотос, Цхристофорос Г.; Лее, Сунгги; Бондзиц, Бојан П.; Тзарас, Димитриос‐Иоаннис; Джамбаски, Здравко;
dc.citation.volume361
dc.citation.issue8
dc.citation.spage1792
dc.citation.epage1797
dc.citation.rankaM21~
dc.description.otherThis is peer-reviewed version of the article: Zdravko Dzambaski, Dimitrios Ioannis Tzaras, Sunggi Lee, Christoforos Kokotos, and Bojan Bondzic, Advanced Synthesis & Catalysis, 2019, 361, 8, 1792-1797, [http://dx.doi.org/10.1002/adsc.201900061]
dc.description.other[http://cer.ihtm.bg.ac.rs/handle/123456789/2953]
dc.identifier.doi10.1002/adsc.201900061
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/7212/10.1002_adsc.201900061.pdf
dc.identifier.scopus2-s2.0-85061776252
dc.identifier.wos000467075800011
dc.type.versionacceptedVersion


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