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dc.creatorLović, Jelena
dc.creatorAvramov Ivić, Milka
dc.creatorBožić, Bojan
dc.creatorLađarević, Jelena
dc.creatorMijin, Dušan
dc.date.accessioned2019-05-18T09:45:21Z
dc.date.available2019-05-18T09:45:21Z
dc.date.issued2019
dc.identifier.issn1580-3155
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2874
dc.description.abstractThe inclusion complexes of the selected, potentially biologically active, succinimides with β-cyclodextrin (βCD) and (2-hydroxypropyl)-β-cyclodextrin (HPβCD) were prepared. the formation of the inclusion complexes of the investigated monophenyl and diphenyl succinimide derivatives was confirmed using attenuated total reflection (ATR) study. Their electrochemical behavior was examined by cyclic voltammetry (CV) and square wave voltammetry (SWV) in 0.05 M NaHCO3 on a gold electrode. The stability constants for compound 1 were determined by cyclic voltammetry and calculated as KβCD = 350.87 M–1 and KHPβCD = 250.67 M–1. The SWV measurements reveal well defined peak at potential Ep = ~ 60 mV and the higher currents at Ep for both inclusion complex of the succinimides compared to the free compounds. The impact of chlorine atom in the phenyl moiety of succinimide derivatives on the activity in electrooxidation reaction is presented. Among the studied succinimides, according to SWV measurements, the most active is the monophenyl succinimide derivative (compound 1) in complex with βCD. The difference of peak current of compound 1 + βCD compared to compound 1 + HPβCD and free compound is 6.3 and 35.2 μA cm–2, respectively.sr
dc.language.isoensr
dc.publisherLjubljana : Slovenian Chemical Societysr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//sr
dc.rightsopenAccesssr
dc.sourceActa Chimica Slovenicasr
dc.subjectDiphenylsuccinimidesr
dc.subjectthreephenylsuccinimidesr
dc.subjectATR analysissr
dc.subjectinclusion complexessr
dc.subjectvoltammetrysr
dc.titleVoltammetric Investigation of Inclusion Complexes of the Selected Succinimides with β-Cyclodextrin and (2-Hydroxypropyl)-β-Cyclodextrinsr
dc.typearticlesr
dc.rights.licenseBYsr
dcterms.abstractБожић, Бојан Ђ.; Aврамов Ивић, Милка; Лађаревић, Јелена; Ловић, Јелена; Мијин, Дусан;
dc.citation.volume66
dc.citation.spage182
dc.citation.epage189
dc.citation.rankM23~
dc.identifier.doi10.17344/acsi.2018.4767
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/6917/ActaChimSlov19.pdf
dc.identifier.scopus2-s2.0-85062351811
dc.identifier.wos000459347100023
dc.type.versionpublishedVersionsr


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