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dc.creatorPetrović, Slobodan D.
dc.creatorVajs, Vlatka
dc.creatorNikolić, Aleksandar D.
dc.creatorStojanović, Nada D.
dc.date.accessioned2019-04-30T13:16:33Z
dc.date.available2019-04-30T13:16:33Z
dc.date.issued1986
dc.identifier.issn0022-2860
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2785
dc.description.abstractThe syntheses of a various N-methyl-N-substituted 2-phenylacetamides of the general formula PhCH 2 CON(CH 3 )R, wherein, R is ethyl, n-propyl, isopropyl and t-butyl group, were performed. The 1 H n.m.r. spectra of these unsymetrically N,N-disubstituted amides have been studied and the peaks have been assigned in each case to the two possible conformational isomers, arising from the lack of free rotation about the C(O)N bond. Although the cis form predominates, the percentage of cis isomer increases as the other nitrogen substituent becomes more bulky. These results are in accordance with our previous investigation of the structures of N-monosubstituted 2-phenylacetamides. © 1986.
dc.publisherElsevier
dc.rightsrestrictedAccess
dc.sourceJournal of Molecular Structure
dc.titleConfigurations in unsymmetrically N-methyl-N-substituted 2-phenylacetamides
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractНиколић, Aлександар Д.; Петровић, Слободан; Вајс, Влатка; Стојановић, Нада Д.;
dc.rights.holderElsevier
dc.citation.volume142
dc.citation.issueC
dc.citation.spage451
dc.citation.epage453
dc.identifier.doi10.1016/0022-2860(86)85154-7
dc.identifier.scopus2-s2.0-12644315841
dc.type.versionpublishedVersion


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