Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides

dc.creator	Maslak, Veselin
dc.creator	Matović, Radomir
dc.creator	Saičić, Radomir N.
dc.date.accessioned	2019-04-29T07:27:53Z
dc.date.available	2019-04-29T07:27:53Z
dc.date.issued	2004
dc.identifier.issn	0040-4020
dc.identifier.uri	https://cer.ihtm.bg.ac.rs/handle/123456789/2768
dc.description.abstract	Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides, followed by acidic work-up, affords butanolides in moderate/good yields. With epihalohydrins the reaction is regioselective and occurs at the less substituted end of the epoxide; the gamma-haloalkyl-gamma-butanolides thus obtained can be further transformed into various products. (C) 2004 Elsevier Ltd. All rights reserved.	en
dc.publisher	Oxford : Pergamon-Elsevier Science Ltd
dc.rights	restrictedAccess
dc.source	Tetrahedron
dc.subject	epoxides	en
dc.subject	ketene acetals	en
dc.subject	lactones	en
dc.subject	titanium and compounds	en
dc.subject	alkylation	en
dc.title	Reaction of silyl ketene acetals with epoxides: a new method for the synthesis of gamma-butanolides	en
dc.type	article
dc.rights.license	ARR
dcterms.abstract	Матовић, Радомир; Саичић, Радомир Н.; Маслак, Веселин;
dc.citation.volume	60
dc.citation.issue	40
dc.citation.spage	8957
dc.citation.epage	8966
dc.citation.other	60(40): 8957-8966
dc.citation.rank	M21
dc.identifier.doi	10.1016/j.tet.2004.07.007
dc.identifier.scopus	2-s2.0-4444296427
dc.identifier.wos	000223935100021
dc.type.version	publishedVersion	en