Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose
Само за регистроване кориснике
2019
Аутори
Jugović, DraganaMitrić, Miodrag
Milović, Miloš
Ivanovski, Valentin N.
Škapin, Srečo Davor
Dojčinović, Biljana
Uskoković, Dragan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.
Кључне речи:
crystal structure / electrochemical reactions / energy storage materials / Mössbauer spectroscopy / X-ray diffractionИзвор:
Journal of Alloys and Compounds, 2019, 786, 912-919Издавач:
- Elsevier
Финансирање / пројекти:
- Молекуларно дизајнирање наночестица контролисаних морфолошких и физичко-хемијских карактеристика и функционалних материјала на њиховој основи (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
- Магнетни и радионуклидима обележени наноструктурни материјали за примене у медицини (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45015)
- Истраживање интерметалика и полупроводника и могућа примена у обновљивим изворима енергије (RS-MESTD-Basic Research (BR or ON)-171001)
Напомена:
- The peer-reviewed version: https://cer.ihtm.bg.ac.rs/handle/123456789/3330
DOI: 10.1016/j.jallcom.2019.01.392
ISSN: 0925-8388
WoS: 000461778600108
Scopus: 2-s2.0-85061204040
Институција/група
IHTMTY - JOUR AU - Jugović, Dragana AU - Mitrić, Miodrag AU - Milović, Miloš AU - Ivanovski, Valentin N. AU - Škapin, Srečo Davor AU - Dojčinović, Biljana AU - Uskoković, Dragan PY - 2019 UR - http://dais.sanu.ac.rs/123456789/4937 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2649 AB - A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V. PB - Elsevier T2 - Journal of Alloys and Compounds T1 - Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose VL - 786 SP - 912 EP - 919 DO - 10.1016/j.jallcom.2019.01.392 ER -
@article{ author = "Jugović, Dragana and Mitrić, Miodrag and Milović, Miloš and Ivanovski, Valentin N. and Škapin, Srečo Davor and Dojčinović, Biljana and Uskoković, Dragan", year = "2019", abstract = "A new method involving the homogeneous dispersion of precursor compounds inside a methylcellulose matrix is used for the synthesis of a composite powder of Li 2 FeP 2 O 7 and carbon. The properties of carbon-containing and carbon-free powders are studied by X-ray powder diffraction (XRD) including Rietveld refinement, Mössbauer spectroscopy, Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), galvanostatic cycling, and electrochemical impedance spectroscopy (EIS). The structure of both powders is refined in a monoclinic framework (space group P2 1 /c). The structural refinement and Mössbauer spectroscopy reveal different degrees of partial occupancy of mixed-occupied sites by lithium. Electrochemical measurements show that the in situ formation of carbon improves capacity (90% of 1-electron theoretical capacity) through decreased charge-transfer resistance. © 2019 Elsevier B.V.", publisher = "Elsevier", journal = "Journal of Alloys and Compounds", title = "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose", volume = "786", pages = "912-919", doi = "10.1016/j.jallcom.2019.01.392" }
Jugović, D., Mitrić, M., Milović, M., Ivanovski, V. N., Škapin, S. D., Dojčinović, B.,& Uskoković, D.. (2019). Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds Elsevier., 786, 912-919. https://doi.org/10.1016/j.jallcom.2019.01.392
Jugović D, Mitrić M, Milović M, Ivanovski VN, Škapin SD, Dojčinović B, Uskoković D. Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose. in Journal of Alloys and Compounds. 2019;786:912-919. doi:10.1016/j.jallcom.2019.01.392 .
Jugović, Dragana, Mitrić, Miodrag, Milović, Miloš, Ivanovski, Valentin N., Škapin, Srečo Davor, Dojčinović, Biljana, Uskoković, Dragan, "Structural and electrochemical properties of the Li2FeP2O7/C composite prepared using soluble methylcellulose" in Journal of Alloys and Compounds, 786 (2019):912-919, https://doi.org/10.1016/j.jallcom.2019.01.392 . .