Show simple item record

dc.creatorVukićević, Nataša
dc.creatorCvetković, Vesna S.
dc.creatorNikolić, Nebojša
dc.creatorBrankovic, Goran
dc.creatorBarudzija, Tanja S.
dc.creatorJovićević, Jovan N.
dc.date.accessioned2019-01-30T17:59:19Z
dc.date.available2019-01-30T17:59:19Z
dc.date.issued2018
dc.identifier.issn0352-5139
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2382
dc.description.abstractSynthesis of the honeycomb-like MgO/Mg(OH)(2) structures, with controlled shape and size of holes, by the electrolysis from magnesium nitrate hexahydrate melt onto glassy carbon is presented. The honeycomb-like structures were made up of holes, formed from detached hydrogen bubbles, surrounded by walls, built up of thin intertwined needles. For the first time, it was shown that the honeycomb-like structures can be obtained by molten salt electrolysis and not exclusively by electrolysis from aqueous electrolytes. Analogies with the processes of the honeycomb-like metal structures formation from aqueous electrolytes are presented and discussed. Rules established for the formation of these structures from aqueous electrolytes, such as the increase of number of holes, the decrease of holes size and coalescence of neighbouring hydrogen bubbles observed with increasing cathodic potential, appeared to be valid for the electrolysis of the molten salt used.en
dc.publisherSerbian Chemical Society
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectelectrolysisen
dc.subjectmagnesium nitrate melten
dc.subjecthoneycomb-like structureen
dc.subjecthydrogen evolutionen
dc.subjectscanning electron microscope (SEM)en
dc.titleFormation of the honeycomb-like MgO/Mg(OH)(2) structures with controlled shape and size of holes by molten salt electrolysisen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractЈовицевиц, Јован Н.; Николић, Небојша; Бранковиц, Горан; Барудзија, Тања С.; Цветковић, Весна С.; Вукићевић, Наташа;
dc.citation.volume83
dc.citation.issue12
dc.citation.spage1351
dc.citation.epage1362
dc.citation.other83(12): 1351-1362
dc.citation.rankM23
dc.identifier.doi10.2298/JSC180913084V
dc.identifier.rcubConv_4041
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8765/2380.pdf
dc.identifier.scopus2-s2.0-85059301033
dc.identifier.wos000454508900006
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record