IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination
Apstrakt
The only stable isomer of the higher fullerene C-76 of D-2 symmetry was isolated from carbon soot by the new and advanced extraction and chromatographic methods and processes. Characterization of the isolated C-76-D-2 was performed by the IR(KBr) and UV/VIS method in the absorption mode. All of the experimentally observed infrared and electronic absorption bands are in excellent agreement with the theoretical calculations for this fullerene. The molar absorptivity epsilon and the integrated molar absorptivity psi of the observed entire new series of various characteristic, both deconvoluted and convoluted IR absorption bands of the C-76-D-2 isomer, in different integration ranges were determined. In addition, the molar extinction coefficients of its UV/VIS absorption bands were determined. The obtained novel IR and UV/VIS spectroscopic parameters are significant for the quantitative assessment of C-76-D-2. All the presented data are important both for its qualitative and quantitative d...etermination, either in natural resources on Earth and in space or in artificially synthesized materials, electronic and optical devices, optical limiters, sensors, polymers, solar cells, nanophotonic lenses, diagnostic and therapeutic agents, pharmaceutical substances, for targeted drug delivery, incorporation of metal atoms, in biomedical engineering, industry, applied optical science, batteries, catalysts and so forth.
Ključne reči:
Electronic absorption bands / Fullerenes / Integrated molar absorptivity / Theoretical calculations / Spectroscopic parameters / Molar extinction coefficient / Quantitative assessments / Spectroscopic characterization / Chromatographic analysisIzvor:
Journal of Nanomaterials, 2018, 6862710-Izdavač:
- Hindawi Limited
Finansiranje / projekti:
DOI: 10.1155/2018/6862710
ISSN: 1687-4110
WoS: 000446811100001
Scopus: 2-s2.0-85062476554
Institucija/grupa
IHTMTY - JOUR AU - Jovanovic, Tamara AU - Koruga, Djuro AU - Mitrović, Aleksandra D. AU - Stamenkovic, Dragomir AU - Dević, Gordana PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2371 AB - The only stable isomer of the higher fullerene C-76 of D-2 symmetry was isolated from carbon soot by the new and advanced extraction and chromatographic methods and processes. Characterization of the isolated C-76-D-2 was performed by the IR(KBr) and UV/VIS method in the absorption mode. All of the experimentally observed infrared and electronic absorption bands are in excellent agreement with the theoretical calculations for this fullerene. The molar absorptivity epsilon and the integrated molar absorptivity psi of the observed entire new series of various characteristic, both deconvoluted and convoluted IR absorption bands of the C-76-D-2 isomer, in different integration ranges were determined. In addition, the molar extinction coefficients of its UV/VIS absorption bands were determined. The obtained novel IR and UV/VIS spectroscopic parameters are significant for the quantitative assessment of C-76-D-2. All the presented data are important both for its qualitative and quantitative determination, either in natural resources on Earth and in space or in artificially synthesized materials, electronic and optical devices, optical limiters, sensors, polymers, solar cells, nanophotonic lenses, diagnostic and therapeutic agents, pharmaceutical substances, for targeted drug delivery, incorporation of metal atoms, in biomedical engineering, industry, applied optical science, batteries, catalysts and so forth. PB - Hindawi Limited T2 - Journal of Nanomaterials T1 - IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination SP - 6862710 DO - 10.1155/2018/6862710 ER -
@article{ author = "Jovanovic, Tamara and Koruga, Djuro and Mitrović, Aleksandra D. and Stamenkovic, Dragomir and Dević, Gordana", year = "2018", abstract = "The only stable isomer of the higher fullerene C-76 of D-2 symmetry was isolated from carbon soot by the new and advanced extraction and chromatographic methods and processes. Characterization of the isolated C-76-D-2 was performed by the IR(KBr) and UV/VIS method in the absorption mode. All of the experimentally observed infrared and electronic absorption bands are in excellent agreement with the theoretical calculations for this fullerene. The molar absorptivity epsilon and the integrated molar absorptivity psi of the observed entire new series of various characteristic, both deconvoluted and convoluted IR absorption bands of the C-76-D-2 isomer, in different integration ranges were determined. In addition, the molar extinction coefficients of its UV/VIS absorption bands were determined. The obtained novel IR and UV/VIS spectroscopic parameters are significant for the quantitative assessment of C-76-D-2. All the presented data are important both for its qualitative and quantitative determination, either in natural resources on Earth and in space or in artificially synthesized materials, electronic and optical devices, optical limiters, sensors, polymers, solar cells, nanophotonic lenses, diagnostic and therapeutic agents, pharmaceutical substances, for targeted drug delivery, incorporation of metal atoms, in biomedical engineering, industry, applied optical science, batteries, catalysts and so forth.", publisher = "Hindawi Limited", journal = "Journal of Nanomaterials", title = "IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination", pages = "6862710", doi = "10.1155/2018/6862710" }
Jovanovic, T., Koruga, D., Mitrović, A. D., Stamenkovic, D.,& Dević, G.. (2018). IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination. in Journal of Nanomaterials Hindawi Limited., 6862710. https://doi.org/10.1155/2018/6862710
Jovanovic T, Koruga D, Mitrović AD, Stamenkovic D, Dević G. IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination. in Journal of Nanomaterials. 2018;:6862710. doi:10.1155/2018/6862710 .
Jovanovic, Tamara, Koruga, Djuro, Mitrović, Aleksandra D., Stamenkovic, Dragomir, Dević, Gordana, "IR and UV/VIS Spectroscopic Characterization of the Higher Fullerene C-76-D-2 for Its Quantitative and Qualitative Determination" in Journal of Nanomaterials (2018):6862710, https://doi.org/10.1155/2018/6862710 . .