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dc.creatorWang, Lianke
dc.creatorZlatar, Matija
dc.creatorVlahović, Filip
dc.creatorDemeshko, Serhiy
dc.creatorPhilouze, Christian
dc.creatorMolton, Florian
dc.creatorGennari, Marcello
dc.creatorMeyer, Franc
dc.creatorDuboc, Carole
dc.creatorGruden, Maja
dc.date.accessioned2019-01-30T17:58:21Z
dc.date.available2019-01-30T17:58:21Z
dc.date.issued2018
dc.identifier.issn0947-6539
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2335
dc.description.abstractThe complexes [(FeLX)-X-N2S2] [in which L-N2S2 = 2,2'-(2,2'-bipryridine-6,6'-diyl)bis(1,1'-diphenylethanethiolate) and X = Cl, Br and I], characterized crystallographically earlier and here (Fe(L)Br), reveal a square pyramidal coordinated Fe-III ion. Unusually, all three complexes have intermediate spin ground states. Susceptibility measurements, powder cw X- and Q-band EPR spectra, and zero-field powder Mossbauer spectra show that all complexes display distinct magnetic anisotropy, which has been rationalized by DFT calculations.en
dc.publisherWiley-V C H Verlag Gmbh, Weinheim
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.relationCOST Action ECOSTBio (Explicit Control Over Spin-States in Technology and Biochemistry) including a STSM grant [CM1305, COST-STSM-CM1305-25068]
dc.relationChina Scholarship Council
dc.relationDeutsche Forschungsgemeinschaft (collaborative DFG/ANR project) [Me1313/14-1]
dc.relationSerbian-French collaboration project [451-03-39/2016-09/06, 36224WB, ANR-11-LABX-003]
dc.rightsopenAccess
dc.sourceChemistry-A European Journal
dc.subjectdensity functional calculationsen
dc.subjectelectronic structureen
dc.subjectintermediate spin stateen
dc.subjectiron(III)en
dc.subjectmagnetic propertiesen
dc.titleExperimental and Theoretical Identification of the Origin of Magnetic Anisotropy in Intermediate Spin Iron(III) Complexesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМолтон, Флориан; Геннари, Марцелло; Дубоц, Цароле; Груден, Маја; Меyер, Франц; Влаховиц, Филип; Демесхко, Серхиy; Wанг, Лианке; Златар, Матија; Пхилоузе, Цхристиан;
dc.citation.volume24
dc.citation.issue20
dc.citation.spage5091
dc.citation.epage5094
dc.citation.other24(20): 5091-5094
dc.citation.rankM21
dc.identifier.pmid29447424
dc.identifier.doi10.1002/chem.201705989
dc.identifier.rcubConv_3919
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/8724/2333.pdf
dc.identifier.scopus2-s2.0-85042682197
dc.identifier.wos000429703700018
dc.type.versionpublishedVersion


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